No 3 (2025)

Cover Page

Features of arc surfacing of intermetallic alloys of the Fe–Al system on the surface of low-carbon steels

Bochkarev A.G.

Abstract

The durability of industrial components is largely determined by the materials they are made of. Often, the materials used must be resistant to wear, corrosion, and high temperatures. Advanced materials, such as high-strength alloy steels, are expensive and have limited weldability, which complicates the restoration of worn components. Fe–Al alloys having high corrosion resistance, wear resistance, and heat resistance at a lower cost are considered as an alternative. The objective of this study is to increase the wear resistance and heat resistance of low-carbon steel components by studying the processes of arc surfacing of iron aluminides and their properties. The study methodology included single-arc and double-arc surfacing using aluminium and steel electrode wires, analysis of the chemical composition of the deposited coatings, their hardness, wear resistance, and heat resistance. The results showed that single-arc surfacing forms alloys based on FeAl3 and α-Al phases with Fe2Al5 and FeAl3 inclusions, while double-arc surfacing produces alloys more saturated with iron with an α-Fe matrix phase and a Fe3AlCx carbide phase. The resulting alloys demonstrate a hardness of up to 58 HRC, a relative wear resistance of up to 2.5 units, and a weight loss of no more than 5 % with an aluminium content of up to 20 %, which indicates their potential for use under high loading conditions. The results confirm the feasibility of using iron aluminides as an inexpensive alternative to expensive coatings, which expands the possibilities for increasing the wear resistance and heat resistance of components in industry.

Frontier Materials & Technologies. 2025;(3):11-25
pages 11-25 views

Scheme for producing composite material based on structural aluminum alloy by the direct extrusion method

Bushueva N.I.

Abstract

The work covers the development of a technology for producing a bimetallic rod from high-strength 7075 alloy with a cladding layer of 1100 aluminum, which is aimed at improving corrosion resistance while maintaining mechanical properties. A special feature of the proposed technology is the use of an additional front pure aluminum workpiece for the process of direct extrusion of a rod from 7075 alloy. The direct extrusion process for a composite workpiece was simulated with the DEFORM software package’s finite element method. The influence of process temperature and speed on the formation of the cladding layer was analyzed. For this purpose, four problems were formulated with varying heating modes of workpieces and tools. It was found that it is possible to produce a thin cladding layer at a heating temperature of the base 7075 alloy equal to 360 °C and a cladding layer temperature equal to 20 °C, which ensures a uniform distribution of the coating along the length of the rod without signs of delamination. Stress-strain analysis during extrusion showed that a cold additional workpiece ensures continuity for cladding coating formation. However, heating above 300 °C leads to rupture from deformation localization. The developed approach can be used to reduce the cost of products by reducing the consumption of expensive 7075 alloy while simultaneously increasing corrosion resistance due to the use of pure aluminum cladding. Prospects for the development of further research are associated with the optimization of extrusion modes for various rod sizes.

Frontier Materials & Technologies. 2025;(3):27-37
pages 27-37 views

Study of rigidity and frequency response of an end mill on a vertical milling center

Voronov R.D.

Abstract

The study covers the problem of early elimination of tool resonant vibrations through preliminary mathematical modelling. In particular, the problem is considered for the case of milling with an end mill on a vertical milling centre. The paper presents processed experimental data and results of mathematical modelling containing information on the rigidity of the FKC 4257 mill, its natural frequencies on the spectrum and vibration modes. The constructed finite element mathematical model covers the mill itself, the gripping collet and the collet chuck attachment. The model describes the static rigidity of the mill with an error of 2.2 %, and the position of its natural frequencies on the spectrum – with an error of about 7 % relative to the experimental results. By constructing the amplitude-frequency characteristic and conducting a modal analysis, it is shown that the first two vibration modes (80 and 112 Hz) are the most critical for the mill, both in terms of the amplitude of vibrations and in terms of their shape. The vibration shapes in the first modes are bending. During the modal analysis, the vibration shapes in the remaining modes are considered and estimated. To improve the convergence of the frequency analysis results, it is proposed to introduce the coefficient Kk1=0.9, which takes into account the lower rigidity of a real mill in comparison with an idealized mathematical model, when applying which the convergence is improved to 2.5 %. Thanks to the applied technique, it is possible to obtain reliable data on the frequency zones of instability used in practice to avoid resonance phenomena. In the future, based on such data, taking into account the correction factors, it is possible to train neural network models predicting the tool response under specific processing conditions and solving the inverse problem of selecting rational tool geometry for specific tasks.

Frontier Materials & Technologies. 2025;(3):39-49
pages 39-49 views

Microstructure, properties and strengthening mechanisms of low-carbon steel subjected to equal-channel angular pressing

Malinin A.V.

Abstract

In the work, an ultrafine-grained (UFG) state was formed in a low-carbon steel by equal-channel angular pressing (ECAP) (8 passes, 200 °С), demonstrating high mechanical properties (yield strength is 1021 MPa, tensile strength is 1072 MPa, ductility is 10.7 %) along with satisfactory corrosion resistance (0.345 mm/year). To explain the reasons for improvement of strength properties and changes in corrosion properties, UFG steel microstructure was analysed using electron microscopy and X-ray scattering methods. Specifically, electron microscopy methods revealed structural refinement of ECAP-processed steel, resulting in the formation of equiaxed grains averaged ~240 nm in size. Modified Williamson–Hall and Warren–Averbach X-ray procedures were applied to find the patterns of changes in coherent scattering domains size, density ρ and fraction fs of screw-type dislocations, effective outer cut-off radius Re of dislocations and some other parameters of low-carbon steel depending on a number of ECAP passes (degree of deformation). X-ray diffraction analysis and small-angle X-ray scattering methods were used to determine evolution trends of mass fraction, size and morphology of various precipitates depending on the number of ECAP passes. Based on the obtained data, a model of microstructure transformation during UFG state formation in steel was proposed. Furthermore, strengthening mechanisms of both coarse-grained and UFG steels were discussed. It was found that in initial state, steel strength was primarily ensured by grain-boundary strengthening and precipitation of small Ме23С6 and Ме3С2 precipitates. It was shown that during UFG structure formation, steel strength increases due to grain-boundary strengthening and dislocation density increase. The contribution of precipitates in the UFG state to the strengthening decreases and this is due to their growth during ECAP processing. It was found that an increase in corrosion rate of UFG steel results from a decrease in ferrite grain size, an increase in grain-boundary dislocations density and a cellular structure formation.

Frontier Materials & Technologies. 2025;(3):51-65
pages 51-65 views

Special aspects of microstructure formation in Cu–Cr–Zr–Y bronze under low-temperature friction stir processing

Nikitin I.S.

Abstract

The use of friction stir treatment (FST) to modify the physical and mechanical properties of age-hardenable low-alloyed bronzes is a promising and at the same time complex task due to the wide temperature range of its implementation. The difficulty is that friction stir treatment of bronzes can result in the formation of fundamentally different types of microstructures with a wide range of grain sizes and various combinations of types of strengthening phases and their various morphologies. Moreover, options are possible when friction stir treatment leads to degradation of properties of bronzes. A favorable combination of properties can be achieved by low-temperature friction stir treatment. In this work, the main microstructural changes in promising Cu–Cr–Zr–Y bronze were analyzed during low-temperature friction stir treatment with a tool rotation speed of 1000 rpm and a feed rate of 25 mm/min (ensuring a temperature in the stir zone of ≈350 °C). Scanning electron microscopy and EBSD analysis revealed the mechanisms of formation of an ultrafine-grained structure with predominantly high-angle boundaries, as well as the development of two types of simple shear crystallographic textures. It is shown that the Cux(Y,Zr) phase observed in the initial structure can undergo mechanical destruction or retain its geometric parameters depending on its initial morphology and location. It is shown for the first time that excess Cr particles (the equilibrium fraction at the heating temperature for quenching) may not be destroyed, but plastically deformed with a strong change in their morphology. During friction stir treatment of the bronze under study, particles of a new Y-containing phase are released. The paper considered the relationship of the distribution of microhardness and electrical conductivity and the observed changes in the microstructure of a new promising material.

Frontier Materials & Technologies. 2025;(3):67-80
pages 67-80 views

Study of the influence of deformation temperature on the mechanical behaviour and fracturing behaviour of the cast TNM-B1 alloy

Sokolovskiy V.S.

Abstract

The paper covers the study of β-solidifying TiAl-based alloys, which are extremely promising materials for the aviation industry with an operating temperature of up to 850 °C, have high specific strength characteristics. The authors studied the influence of tensile deformation temperature in the range of T=25–1000 °C on the mechanical properties, phase composition and crack formation in the cast β-solidifying TNM-B1 alloy. It is found that the cast TNM-B1 alloy is characterised by a complex microstructure, including (α2+γ) lamellar colonies and interlayers of β(B2)+ω phases, the evolution of which at elevated deformation temperatures determines the material behaviour. It is shown that the ω-phase dissolution and the precipitation of dispersed secondary β-phase particles at T>950 °C have a significant influence on the mechanical characteristics. A pronounced temperature dependence of strength and ductility is identified: the maximum strength is observed at 800 °C, while the greatest relative elongation in the studied temperature range is achieved at 1000 °C. The transition from brittle to viscous fracture occurs in the temperature range of about 950 °C. Moreover, a dependence of the crack propagation mechanism on the orientation of lamellar colonies relative to the deformation axis is revealed: with an increase in temperature, the differences are leveled, and at 1000 °C, complete suppression of crack formation with the formation of pores along the boundaries of colonies and clusters of secondary β-phase particles is observed. The obtained results demonstrate the important role of microstructural transformations in the formation of deformation behaviour and mechanical properties of the TNM-B1 alloy based on gamma-titanium aluminide, which is of practical importance for the development of technologies for its thermomechanical processing.

Frontier Materials & Technologies. 2025;(3):81-89
pages 81-89 views

Study of the temperature field formed in the process of milling with the use of ultrasonic vibrations under various processing modes

Unyanin A.N.

Abstract

Study of the temperature field of the milling process with the imposition of ultrasonic vibrations (USV), under various ratios of the vibration amplitude to the depth of tooth penetration into the blank, will allow predicting the efficiency of the milling process with USV under various processing modes. The purpose of this study is to develop physical and mathematical models of the milling process with the imposition of USV, allowing identifying the influence of ultrasonic vibrations on the efficiency of the milling process under various ratios of the vibration amplitude to the depth of tooth penetration. Three sources of heat generation are considered: in the deformation (chip formation) area and in the zones of contact of the chip with the cutting plate (cutter tooth) and the plate with the blank. The authors have developed heat transfer models that take into account, in particular, the change in boundary conditions on the surfaces of the cutting plate and the blank under the USV imposition. When the plate is in contact with the blank, heat flows are directed to the blank, chips and cutter tooth, and the conditions of thermal interaction within the zones of contact of the plate with the chips and the blank are described by boundary conditions of the 2nd type. When the plate leaves the contact with the blank during the ultrasonic imposition and the chip formation process stops, then on all surfaces of the tooth (plate) and the blank that are in contact with the environment (cutting fluid or air), the convective heat transfer is described by the Newton–Richmann law (boundary conditions of the 3rd type). The results of numerical modelling are presented, confirming the assumption that the effect of using ultrasonic vibrations is higher at high values of the ratio of the ultrasonic vibration amplitude to the depth of tooth penetration into the blank.

Frontier Materials & Technologies. 2025;(3):91-100
pages 91-100 views

Influence of heat treatment on the structure and corrosion properties of microalloyed pipe steels with a chromium content of up to 1 %

Chistopoltseva E.A.

Abstract

The service life of oil pipelines has recently decreased significantly due to severe operating conditions and the increased aggressiveness of the environment, caused by the simultaneous presence of dissolved hydrogen sulfide, carbon dioxide, chlorides, and a high water phase content. Conventional corrosion mitigation methods typically address only one of these factors and therefore fail to provide adequate protection under such combined conditions. This limitation necessitates the use of multiple complementary approaches for corrosion control. This paper proposes microalloying systems for low-carbon steels of grades 10KhB, 10F, 10B, and 15KhF (with chromium content up to 1 %) for seamless pipes, along with optimized heat treatment regimes that provide increased strength, cold resistance, and corrosion resistance in CO2- and H2S-containing environments. Mechanical testing after heat treatment demonstrated that the proposed chemical compositions ensure strength classes K52–K56, while also providing high low-temperature toughness. The morphology of carbides in the microstructure depends on the chemical composition and determines the steel’s strength, though it does not affect corrosion resistance. The investigated steels showed high resistance to hydrogen-induced cracking (HIC) and sulfide stress cracking (SSC). After exposure to CO2–H2S media, a protective iron sulfide film formed on the surface, indicating uniform sulfide corrosion. The corrosion rate and mechanism were found to be governed by the medium composition and the kinetics of iron sulfide film formation. The obtained results allow expanding the scope of application of the proposed steels in multicomponent aggressive environments regardless of the type of microalloying.

Frontier Materials & Technologies. 2025;(3):101-111
pages 101-111 views

The influence of rotary swaging and subsequent annealing on the structure and mechanical properties of L68 single-phase brass

Chistyukhina E.I.

Abstract

Copper alloys based on the Cu–Zn system, in particular L68 brass, are promising structural materials. However, to improve their reliability and expand the scope of application, it is necessary to enhance their strength characteristics. In this work, the influence of a combination of rotary swaging (RS) and subsequent annealing on the structure, strength and ductility of L68 brass was studied. For this purpose, the alloy microstructure was studied in the quenched and deformed states, mechanical tests for uniaxial tension, a Brinell hardness study, and an assessment of structural and phase transitions using differential scanning calorimetry were carried out. It was found that during rotary swaging, both α-phase grains elongated along the deformation direction and an ultrafine-grained structure inside them consisting of subgrains, deformation twins and shear bands are formed. Subsequent annealing at 450 °C leads to an increase in the grain size to 3–5 μm due to static recrystallization. After rotary swaging, an increase in the offset yield strength (σ0.2) and ultimate tensile stress limit (σB) by ~10 and ~3.5 times, respectively, is observed with a decrease in the relative elongation value by more than 6 times. Subsequent annealing at 450 °C, which caused the formation of a recrystallised structure, led to a decrease in the strength characteristics of L68 brass relative to the deformed state with a simultaneous increase in the relative elongation value compared to both the deformed and the initial state of the alloy. However, it is worth noting that σ0.2 and σB of L68 brass after rotary swaging and subsequent annealing at 450 °C exceed the values for the quenched alloy by an average of ~2.5 and ~1.7 times, respectively, and exceed the values regulated by GOST 494-90, GOST 1066-2015, GOST 931-90, and GOST 5362-78.

Frontier Materials & Technologies. 2025;(3):113-124
pages 113-124 views

Strength of joints produced by ultrasonic spot welding of copper plates using tools with different tooth heights

Shayakhmetova E.R.

Abstract

Ultrasonic welding of metals is an energy-efficient, environmentally friendly technology that allows producing solid-state joints between thin blanks. The widespread use of this technology is hampered by the low strength of the resulting joints and the instability of their properties. One of the ways to improve strength characteristics is to develop a welding tool that ensures stable transmission of ultrasonic vibration energy to the joint zone. For this purpose, a relief with teeth or pyramids of different shapes and heights is applied to the surface of the welding tip and anvil. This paper presents data on the fracture load and fracture energy of lap joints produced by ultrasonic spot welding of copper plates using tools with a tooth height of 0.1 and 0.4 mm. Ultrasonic welding was carried out with a frequency of 20 kHz and a vibration amplitude of 18–20 μm, the welding duration was 2 and 3 s, the clamping force was 2.5 kN. The paper considers the features of the fracture of the produced joints and the distribution of normal strains in the weld spot, and results of calculation of stress intensity factors in its vicinity. It is shown that after ultrasonic welding for 3 s, the strength characteristics of the joints produced with different tools reach the highest values, they are close in magnitude, but the experimental data scatter is half as much after welding with a tool with small teeth. The joints produced with such a tool fractured along the interface of the joint, and after welding with a tool with large teeth, the fracture developed with nugget pull-out, which is explained by an increase in the stress intensity factor at the tip of the concentrator surrounding the weld spot.

Frontier Materials & Technologies. 2025;(3):125-136
pages 125-136 views

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