No 1 (2020)

Full Issue

TWO APPROACHES TO STUDY THE EFFECT OF SURFACE STRESSES IN AN ELASTIC BODY WITH A NEARLY CIRCULAR NANODEFECT

Vakaeva A.B., Shuvalov G.M., Kostyrko S.A., Sedova O.S.

Abstract

Most of the advanced construction and functional materials are elastically nonuniform, moreover, for many of them, the elongated holes and inclusions are typical, which are similar to a cylinder in form. The strength and physicochemical properties of a material, to a great extent, depend on the peculiarities of the strain-stress state of the near-surface and boundary layers of the materials in the heterogeneous systems. The development of the processes of elastic deformation and fracture in these areas, to a large extent, determines the mechanical behavior of a material in general and arouses much interest. The authors study the influence of interfacial stresses on the strain-stress state of elastic bimaterial with smooth waveform interface; consider the 2-D solid mechanics problem of an elastic body with nanoscale boundary surface texture, which appears between the nearly circular inclusion and the matrix. It is expected that a body is situated within a uniform stress field. To solve the problem, the authors used the simplified Gurtin-Murdoch’s surface/interface elasticity model, where the interfacial boundary is the negligibly thin layer exactly bordered on the bulk phases. It is acknowledged that there are no displacement discontinuities on the interfacial boundary, and the stress jump is determined by the effect of surface/interfacial stress according to the generalized Laplace-Young law. Using the boundary perturbation method, the problem solution for each approximation is limited to a singular integrodifferential equation against the unknown surface/interfacial stress. The paper gives the numerical results for the problem to a first approximation. As a result, the authors carry out the comparative analysis of the strain-stress state using the finite-element method and analytical boundary perturbation method.
Frontier Materials & Technologies. 2020;(1):7-14
pages 7-14 views

THE INFLUENCE OF SR(CA)2NB2O7 ON THE PHASE FORMATION AND THE STRUCTURE OF SOLID SOLUTIONS BASED ON THE SODIUM-KALIUM NIOBATE

Glazunova E.V.

Abstract

(1- x )KNbO3 - x NaNbO3 system is one of the most learned among lead-free ceramics. This system is promising for potential use in piezoelectric technology and the replacement of lead-containing elements in such devices. However, despite many works aimed at the solution of this problem, at the moment, no lead-free materials with the properties comparable to the lead-containing piezo-ceramics were produced. It is caused by various technological difficulties of creating solid solutions (SS) based on the lead-free compositions such as alkaline components volatility and the strongest dependence of the observed properties on the production conditions (thermodynamic history). One of the techniques applied to improve processability and SS stability as well as to improve electrophysical properties is modifying. The paper deals with the study of the influence of calcium and strontium pyroniobates additives on the structure and properties of (1- x )KNbO3 - x NaNbO3 system. The conditions of synthesis and sintering for each solid solution of (1- x-у )KNbO3 - y NaNbO3 - x (Sr/Са)2Nb2O7 systems are optimized. The author carried out the X-ray diffraction and radiographic analysis of the produced items, analyzed the dependence of the parameters, cell volume, and the ceramics densities on the concentration of added (Sr/Са)2Nb2O7 component. The study determined that the increase in the content of calcium and strontium pyroniobates in the interval of 0≤х≤10 % leads to the appearance of several phase transitions caused by the structural transformation in the (1- x-у )KNbO3 - y NaNbO3 - x (Sr/Са)2Nb2O7 systems. The symmetry of the abovementioned systems changes in different ways. The doping with strontium pyroniobate causes the tetragonal structure distortion and the doping with calcium pyroniobate leads to the formation of the cubic lattice. The study showed as well that the adding of (Sr/Са)2Nb2O7 pyroniobates to the (1- x )KNbO3 - x NaNbO3 system above 2.5 % significantly reduces the density of the produced ceramics.
Frontier Materials & Technologies. 2020;(1):15-22
pages 15-22 views

THE STUDY OF THE STRUCTURE AND PROPERTIES OF SPECIMENS OF INCONEL 738 HEAT-RESISTING ALLOY OBTAINED BY THE SELECTIVE LASER MELTING TECHNIQUE (SLM)

Dmitrieva M.O., Melnikov A.A., Golovach A.M., Bondareva O.S., Smelov V.G., Sotov A.V., Agapovichev A.V.

Abstract

Currently, the selective laser melting technique (SLM) with the use of powder metallic materials is a promising area in the aircraft and engine technology. Due to this technique, it is possible to produce parts with any complexity configuration at fewer expenses for tooling and mechanical processing and the prototyping of goods becomes simpler as well. The issue of application of powder materials of heat-resisting alloys in the additive production is particularly topical, which is due to the problems caused by their complex chemical composition, insufficient thermal conductivity, and shrinkage tendency. The paper studies the influence of laser output power on the microstructure and properties of specimens of Inconel 738 heat-resisting nickel alloy produced with the help of a commercial 3-D printer using the SLM printing technology. Moreover, the authors considered the way of improvement of the specimens’ mechanical properties through the improvement of microstructure after SLM and further heat treatment. The authors carried out the metallographic and electron microscopic study of the initial material and the specimens grown using the SLM technology at the laser output power of 75, 100, 125, and 325 W; analyzed the microstructure evolution in the result of heating caused by the growth of supply energy. Further heat treatment made it possible to study the influence of step quenching on the microstructure and mechanical properties of specimens. Further heat treatment made it possible to study the influence of step quenching on the microstructure and mechanical properties of specimens. The authors determined the optimum technological parameters of laser emission to produce parts from Inconel 738 heat-resisting alloy using the SLM technique and produced parts with the minimum quantity of the defects. The study identified that heat treatment, including step quenching, improves the mechanical properties - ultimate resistance, yield limit, and percent elongation - through the “healing” and the defects’ size reduction.
Frontier Materials & Technologies. 2020;(1):23-31
pages 23-31 views

THE INVESTIGATION OF STRENGTH AND PLASTICITY CHARACTERISTICS OF COMPOSITE LAYERS IN AUSTENITIC STAINLESS STEEL SUBJECTED TO ION-PLASMA TREATMENT USING THE NANOINDENTATION METHOD

Zagibalova E.A., Moskvina V.A., Astafurov S.V., Maier G.G., Melnikov E.V., Panchenko M.Y., Ramazanov K.N., Astafurova E.G.

Abstract

One of the main issues of austenitic stainless steel is low strength properties and low wear-resistance. It can be partially or fully eliminated by the product surface modification and the creation of hardened surface layers. The ion-plasma saturation of alloys with interstitials, which is carried out in a mixture of gases with different compositions is an available and effective method of surface hardening of complex structural parts. At the same time, the mechanical and plastic characteristics of the processed materials are determined by the complex of properties of the base alloy and the hardened surface, and it is not always possible to identify their influence on the mechanical and plastic properties of each component of the composite material. The nanoindentation method allows determining local mechanical and plastic characteristics in certain areas of hardened materials (base alloy and surface) by the dynamic loading of the local microscopic areas. In this paper, using the nanoindentation method, the authors identified the mechanical and plastic characteristics of hardened layers produced by the ion-plasma treatment of austenitic 01H17N13M3 stainless steel with the grain-subgrain and coarse-grain structures. The ion-plasma treatment of steel specimens facilitates surface hardening and the formation of a composite surface layer of ≈20-25 μm in thickness. High values of nano-hardness in a composite layer are caused by the complex hardening of specimens: solid-solution hardening of austenite with nitrogen and carbon, the dispersion hardening and the formation of different nitrides and carbonitrides and the ferrite low fraction. The experimental results show that the strength properties and plasticity characteristics of such a layer strongly depend on the base material initial microstructure - the formation of a highly-defective grain-subgrain structure promotes the formation of a more enforced surface layer compared to the coarse-grained specimens.
Frontier Materials & Technologies. 2020;(1):32-40
pages 32-40 views

SIMULATION OF ALTERNATING DEFORMATION OF THE TINI ALLOY SAMPLE IN ISOTHERMAL AND ADIABATIC REGIMES

Lapina T.A., Belyaev F.S., Evard M.E.

Abstract

Shape memory alloys belong to the class of functional materials with unique properties that make them useful in many engineering applications. Since in the austenitic state, due to the pseudoelasticity effect, such alloys have a significant damping capacity, and one of the possible applications is vibro-protection devices. Working elements of damping devices made of shape memory alloys are used in the conditions of cyclically varying stresses and/or temperature. The theoretical models adequately describing such behavior make it possible to advance the efficiency of damping devices. The paper aims at the microstructural modeling of alternating deformation of the sample of TiNi shape memory alloy. Phase transformations in the materials with the martensite channel of inelasticity take place with the release and absorption of heat, which can lead to a shift in the working temperatures of the element and the change in its functional properties. Consequently, when theoretically describing the mechanical behavior of the material, the authors considered heat release at the direct transformation and heat absorption at the reverse transformation. Within this study, the authors implemented such consideration for the adiabatic regime of alternating deformation and compared the obtained data with the results of modeling of isothermal alternating deformation. When calculating, the authors took into account the irreversible strain accumulation at cycling, which, in the real device, can cause the change in its working characteristics and operational life loss. The study showed that taking into account the latent transformation heat during cycling in the strain-controlled regime increases the maximum stresses in the cycle and reduces the volume fraction of the resulting martensite. When taking into account the microplastic strain, the deformation loop evolves. In this case, in the adiabatic regime in the first cycles, the temperature increases, later on, about by the seventh cycle, the temperature increase slows down, and the average temperature ceases to change markedly.
Frontier Materials & Technologies. 2020;(1):41-48
pages 41-48 views

ON THE HYDROGEN STATE IN MAGNESIUM ALLOYS AFTER CORROSIVE EFFECT

Myagkikh P.N., Merson E.D., Poluyanov V.A., Merson D.L., Vinogradov A.Y.

Abstract

Low resistance to corrosion and stress corrosion cracking (SCC) hinders the widespread introduction of the magnesium alloys as the construction materials. Considered, that the SCC of the magnesium alloys may be related to the hydrogen fragility. Nevertheless, at the moment, the role of hydrogen in the SCC mechanism of magnesium alloys is not fully evident. In the previous papers, the authors identified that the role of diffusion-active hydrogen in the SCC process of magnesium alloys is highly doubtful: the results both of mechanical tests and gas analysis show that the concentration of diffusion-active hydrogen in tested materials is negligibly small; normally, hydrogen locates in the corrosion products. However, these studies have not identified the influence of external strains on the concentration and state of hydrogen, therefore, it is not clear if the results obtained are typical for SCC only or valid for the corrosion without external load. In this context, the authors set the goal to identify the concentration and the state of hydrogen in magnesium alloys after corrosive action without external strains. Samples of MA14 and MA2-1 alloys and pure magnesium were exposed in a corrosive medium, after which, each sample was divided into two parts: the corrosion products were removed from the first part and left untouched in the second part. Next, the authors studied the samples by gas analysis; and obtained extraction curves and hydrogen concentration values for each of them. The results of the study showed that the removal of corrosion products leads to a strong decline of hydrogen concentration, and at temperatures below 300 °C, it practically ceases. This indicates that most of the hydrogen is in the corrosion products and not in the diffusion-active form in the matrix metal, which is similar to the results obtained when studying the SCC.
Frontier Materials & Technologies. 2020;(1):49-56
pages 49-56 views

THE EFFECT OF HYDROGEN CHARGING ON THE MECHANICAL PROPERTIES AND FRACTURE MECHANISMS OF HIGH-NITROGEN CHROMIUM-MANGANESE STEELS AFTER AGE-HARDENING

Panchenko M.Y., Mikhno A.S., Tumbusova I.A., Maier G.G., Moskvina V.A., Melnikov E.V., Astafurov S.V., Astafurova E.G.

Abstract

Currently, many technical problems require a comprehensive study of the properties of materials operating in hydrogen-containing environments. The authors investigated the effect of age-hardening on the hydrogen embrittlement and fracture micromechanisms of high-nitrogen austenitic Fe-23Cr-17Mn-0.1C-0.6N (wt. %) steel. For this purpose, using heat treatments, the authors formed in specimens of Fe-23Cr-17Mn-0.1C-0.6N steel the structural phase states characterized by different distribution and content of dispersed phases. The experiment determined that the accumulation of hydrogen atoms occurs predominantly in the grains in solution-treated specimens without dispersed phases. This causes the effects of solid solution hardening and leads to a change in the micromechanism of steel fracture from a ductile dimple fracture in the absence of hydrogen to a transgranular fracture by the quasi-cleavage mechanism in hydrogen-charged specimens. It was established that the discontinuous decomposition of austenite with the formation of Cr2N cells and austenite depleted in nitrogen, predominantly along the grain boundaries causes the formation of a large fraction of interphase (austenite/Cr2N particles) boundaries. Cells of discontinuous decomposition promote hydrogen accumulation along the grain boundaries and cause brittle intergranular fracture of hydrogen-charged specimens during plastic deformation. The study showed that in specimens with the discontinuous decomposition of austenite both along the grain boundaries and spreading into the grain body, plenty of intragranular interphase boundaries (Cr2N plates in austenite) are formed, which causes the formation of a transgranular brittle fracture in the hydrogen-charged specimens.
Frontier Materials & Technologies. 2020;(1):57-67
pages 57-67 views

THE INFLUENCE OF CHROMIUM CARBIDE ADDITIVE ON THE STRUCTURE AND ABRASIVE WEAR RESISTANCE OF THE NICRBSI COATING FORMED BY LASER CLADDING

Soboleva N.N., Nikolaeva E.P., Makarov A.V., Malygina I.Y.

Abstract

Laser cladding allows obtaining hardening and restorative coatings and is widely used in various branches of engineering. Self-fluxing Ni-Cr-B-Si alloys proved to be wear-resistant alloys for deposition. The relatively low melting point of NiCrBSi powders allows adding hard particles in the matrix material and, thereby, creating composite coatings with particles not dissolved during the deposition. WC/W2C, Cr3C2, SiC, TaC, NiC, VC, and TiC additives are used as reinforcing carbide particles when creating composite coatings based on NiCrBSi. The study of wear patterns of the NiCrBSi-Cr3C2 composite coating characterized by the increased resistance to corrosion and oxidation at high temperatures is of particular scientific and practical interest. When studying, the authors added 15 wt. % of Cr3C2 powder with the particle size of 50-150 μm to PG-SR2 powder (chemical composition, wt. %: 0.48 % C; 14.8 % Cr; 2.6 % Fe; 2.9 % Si; 2.1 % B; the rest is Ni) with the particle size of 40-160 µm during gas powder laser cladding. Using scanning electron microscopy, the authors identified that such addition of chromium carbide to NiCrBSi powder caused the formation of a composite coating during laser cladding since the structure contains the initial nondissolved Cr3C2 chromium carbides. NiCrBSi - Cr3C2 coating has improved microhardness. The authors carried out abrasion tests for fixed abrasive material - corundum, determined abrasive wear intensity, friction coefficient, and specific work of abrasive wear, and studied the wear surfaces of NiCrBSi and NiCrBSi-Cr3C2 coatings. The study identified a significant increase in abrasive wear resistance of the composite coating in response to the change of the main wear mechanism (from micro-cutting for NiCrBSi coating to scratching for NiCrBSi-Cr3C2 coating).
Frontier Materials & Technologies. 2020;(1):68-76
pages 68-76 views

THE EFFECT OF MEGAPLASTIC DEFORMATION IN THE BRIDGMAN CHAMBER ON THE PHASE TRANSFORMATIONS, CORROSION BEHAVIOR, AND MICROHARDNESS OF PURE VT1-00 AND VT1-0 TITANIUM

Cheretaeva A.O., Shurygina N.A., Glezer A.M.

Abstract

Due to the combination of lightness, high specific strength and corrosion resistance, titanium and its alloys are highly interesting for applying in many areas of industry (mechanical engineering, shipbuilding, and aircraft manufacturing). Technically pure titanium is the first choice to be used in medicine because of its high biocompatibility and lack of toxic elements. Pure titanium has high ductility and corrosion resistance but it is inferior to titanium alloys in other mechanical characteristics, such as tensile strength, yield strength, and hardness. Megaplastic deformation (MPD) is a promising method for increasing the strength of titanium to the level of highly alloyed alloys. The paper deals with the study of the influence of MPD in the Bridgman chamber on the structure (phase transformations occurring in technically pure VT1-00 and VT1-0 titanium), corrosion resistance, and microhardness. Using the high-pressure torsion (HPT), the authors obtained samples with different degrees of deformation: from 0.25 to 4 revolutions of the movable anvil. The authors carried out the X-ray diffraction analysis and electrochemical tests of samples and studied the phase composition of titanium samples of two grades containing 0.1 and 0.3 % of impurities before and after MPD. The study identified that the HPT led to the formation of a two-phase mixture a+ɷ. The results showed the positive effect of MPD on the mechanical properties of titanium. The microhardness of the deformed material increases in comparison with the initial state, while there is no deterioration in the corrosion resistance in the studied environment. Under all deformation modes, titanium stays in a passive state. For the VT1-0 alloy, the stationary corrosion potentials of samples after HPT have a more positive value compared to the original undeformed material.
Frontier Materials & Technologies. 2020;(1):77-85
pages 77-85 views

ON THE MECHANOCHEMICAL CORROSION OF A PIPE WITH A THICKNESS DEVIATION UNDER THE ACTION OF EXTERNAL AND INTERNAL PRESSURE

Zhao S.

Abstract

The paper deals with the computer modeling of internal mechanochemical corrosion of a long pipe line section under the internal and external corrosion pressure. The outer boundary of the pipe cross-section is circular, while the inner surface is elliptical. The author studied the task in a two-dimensional installation. Many decisions related to the irregular mechanochemical wear are based on the hypothesis suppositions about the retention of a definite shape of a corroding product. However, mentioned analytical solution gives a significantly overestimated lifetime if the pipe has the initial deviation in the wall thickness even within the permissible tolerance. In this way, computer modeling is a good approach to solve such problems of defective pipes. Using the finite elements technique (FET) in MATLAB environment, the author carried out the numerical experiment for a certain example for studying the influence of pipe thickness deviation on its service life. The study showed that even a slight thickness deviation of a pipe wall causes the stress concentration and the existence of the mechanochemical corrosion causes larger variation in thickness. Moreover, both thinning and thickening of the pipe wall lead to a reduction in its durability. In this way, the more the internal and external pressure difference, the stronger the mechanochemical effect and the shorter the service life of a pipe. The greatest increase in the absolute values of stresses is observed at the vertices of the inner elliptical boundary of a pipe where its thickness has minimum values.
Frontier Materials & Technologies. 2020;(1):86-91
pages 86-91 views

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