Email this article The dependence of the biodegradable ZX10 alloy corrosion process on the structural factors and local pH level
- Authors: Myagkikh P.N.1, Merson E.D.1, Poluyanov V.A.1, Merson D.L.1
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Affiliations:
- Togliatti State University, Togliatti
- Issue: No 2 (2023)
- Pages: 59-76
- Section: Articles
- URL: https://vektornaukitech.ru/jour/article/view/841
- DOI: https://doi.org/10.18323/2782-4039-2023-2-64-3
- ID: 841
Cite item
Abstract
Magnesium biodegradable alloys are a promising material for self-dissolving surgical implants. Magnesium is known to be sensitive to electrochemical corrosion due to the galvanic effect between the matrix and particles of secondary phases and inclusions. Another important factor is the pH level. The behavior of certain chemical reactions depends on the pH level, so one can assume that the pH level of a corrosive medium at the material surface is a factor determining what chemical reactions can occur there. Finally, there is evidence that variability of the crystallographic orientation of the grains may be a cause of anisotropy of corrosion properties. The purpose of this work is to reveal the influence of the electrode potential of the microstructural elements, the crystallographic orientation of the grains, and the pH level of the near-surface volume of the corrosion solution on the corrosion process. In the study, sections of 2×1.5 mm were marked on the ZX10 alloy samples, for which maps of the distribution of crystallographic orientations and chemical composition were drawn. To assess the influence of the electrode potential of the particles, the authors carried out a Kelvin probe mapping in the 90×90 µm area. Next, corrosion tests were carried out with video filming of the surface on the marked area. To determine the pH level influence, the solution circulation in the cell was varied. Upon completion of the tests, corrosion products and corrosion damage were examined in detail. According to the results, the pH level in the liquid near-surface micro-volumes has a greater influence than the electrode potential of the particles as it provokes the formation of corrosion products of a different composition, which leads to passivation of the surface areas around the particles. The authors identified two different types of filiform corrosion. For filiform corrosion, a correlation between the corrosion direction and the crystallographic orientation of the grains was established.
About the authors
Pavel N. Myagkikh
Togliatti State University, Togliatti
Author for correspondence.
Email: feanorhao@gmail.com
ORCID iD: 0000-0002-7530-9518
junior researcher of the Research Institute of Advanced Technologies
Russian FederationEvgeny D. Merson
Togliatti State University, Togliatti
Email: mersoned@gmail.com
ORCID iD: 0000-0002-7063-088X
PhD (Physics and Mathematics), senior researcher of the Research Institute of Advanced Technologies
Russian FederationVitaly A. Poluyanov
Togliatti State University, Togliatti
Email: vitaliy.poluyanov@gmail.com
ORCID iD: 0000-0002-0570-2584
PhD (Engineering), junior researcher of the Research Institute of Advanced Technologies
Russian FederationDmitry L. Merson
Togliatti State University, Togliatti
Email: D.Merson@tltsu.ru
ORCID iD: 0000-0001-5006-4115
Doctor of Sciences (Physics and Mathematics), Professor, Director of the Research Institute of Advanced Technologies
Russian FederationReferences
- Chen J., Tan L., Yu X., Etim I.P., Ibrahim M., Yang K. Mechanical properties of magnesium alloys for medical application: A review. Journal of the Mechanical Behavior Biomedical Materials, 2018, vol. 87, pp. 68–79. doi: 10.1016/j.jmbbm.2018.07.022.
- Vinogradov A., Merson E., Myagkikh P., Linderov M., Brilevsky A., Merson D. Attaining High Functional Performance in Biodegradable Mg-Alloys: An Overview of Challenges and Prospects for the Mg-Zn-Ca System. Materials, 2023, vol. 16, no. 3, article number 1324. doi: 10.3390/ma16031324.
- McCall C.R., Hill M.A., Lillard R.S. Crystallographic pitting in magnesium single crystals. Corrosion Engineering Science and Technology, 2005, vol. 40, no. 4, pp. 337–343. doi: 10.1179/174327805X66326.
- Shin K.S., Bian M.Z., Nam N.D. Effects of crystallographic orientation on corrosion behavior of magnesium single crystals. JOM, 2012, vol. 64, no. 6, pp. 664–670. doi: 10.1007/s11837-012-0334-0.
- Liu M., Qiu D., Zhao M.-C., Song G., Atrens A. The effect of crystallographic orientation on the active corrosion of pure magnesium. Scripta Materialia, 2008, vol. 58, no. 5, pp. 421–424. doi: 10.1016/j.scriptamat.2007.10.027.
- Bahl S., Suwas S., Chatterjee K. The control of crystallographic texture in the use of magnesium as a resorbable biomaterial. RSC Advances, 2014, vol. 4, no. 99, pp. 55677–55684. doi: 10.1039/c4ra08484e.
- Ma Y., Wang D., Li H., Yuan F., Yang C., Zhang J. Microstructure, mechanical and corrosion properties of novel quaternary biodegradable extruded Mg-1Zn-0.2Ca-xAg alloys. Materials Research Express, 2020, vol. 7, no. 1, article number 015414. doi: 10.1088/2053-1591/ab6a52.
- Parfenov E.V., Kulyasova O.B., Mukaeva V.R., Mingo B., Farrakhov R.G., Cherneikina Y.V., Erokhin A., Zheng Y.F., Valiev R.Z. Influence of ultra-fine grain structure on corrosion behaviour of biodegradable Mg-1Ca alloy. Corrosion Science, 2020, vol. 163, article number 108303. doi: 10.1016/j.corsci.2019.108303.
- Thekkepat K., Han J.-S., Choi J.-W., Lee S.-Ch., Yoon E.S., Li G., Seok H.-H., Kim Y.-Ch., Kim J.-H., Cha P.-R. Computational design of Mg alloys with minimal galvanic corrosion. Journal of Magnesium and Alloys, 2022, vol. 10, no. 7, pp. 1972–1980. doi: 10.1016/j.jma.2021.06.019.
- Song G.-L. Corrosion electrochemistry of magnesium (Mg) and its alloys. Corrosion of Magnesium Alloys, 2011, pp. 3–65. doi: 10.1533/9780857091413.1.3.
- Salahshoor M., Guo Y. Biodegradable orthopedic magnesium-calcium (MgCa) alloys, processing, and corrosion performance. Materials, 2012, vol. 5, no. 1, pp. 135–155. doi: 10.3390/ma5010135.
- Urwongse L., Sorrell C.A. The System MgO-MgCl2-H2O at 23°C. Journal of American Ceramic Society, 1980, vol. 63, no. 9-10, pp. 501–504. doi: 10.1111/J.1151-2916.1980.TB10752.X.
- Merson D., Brilevsky A., Myagkikh P., Tarkova A., Prokhorikhin A., Kretov E., Frolova T., Vinogradov A. The functional properties of Mg-Zn-X biodegradable magnesium alloys. Materials, 2020, vol. 13, no. 3, article number 544. doi: 10.3390/ma13030544.
- Merson D.L., Brilevsky A.I., Myagkikh P.N., Markushev M.V., Vinogradov A. Effect of deformation processing of the dilute Mg-1Zn-0.2Ca alloy on the mechanical properties and corrosion rate in a simulated body fluid. Letters on Materials, 2020, vol. 10, no. 2, pp. 217–222. doi: 10.22226/2410-3535-2020-2-217-222.
- Myagkikh P.N., Merson E.D., Poluyanov V.A., Merson D.L. Structure effect on the kinetics and staging of the corrosion process of biodegradable ZX10 and WZ31 magnesium alloys. Frontier Materials & Technologies, 2022, no. 2, pp. 63–73. doi: 10.18323/2782-4039-2022-2-63-73.
- McCall C.R., Hill M.A., Lillard R.S. Crystallographic pitting in magnesium single crystals. Corrosion Engineering, Science and Technology, 2005, vol. 40, no. 4, pp. 337–343. doi: 10.1179/174327805X66326.
- Zhang X., Wang Z., Yuan G., Xue Y. Improvement of mechanical properties and corrosion resistance of biodegradable Mg-Nd-Zn-Zr alloys by double extrusion. Materials Science and Engineering: B, 2012, vol. 177, no. 13, pp. 1113–1119. doi: 10.1016/j.mseb.2012.05.020.
- Ding Y., Wen C., Hodgson P., Li Y. Effects of alloying elements on the corrosion behavior and biocompatibility of biodegradable magnesium alloys: A review. Journal of Materials Chemistry B, 2014, vol. 2, no. 14, pp. 1912–1933. doi: 10.1039/c3tb21746a.
- Yang Y., He C., Dianyu E., Yang W., Qi F., Xie D., Shen L., Peng S., Shuai C. Mg bone implant: Features, developments and perspectives. Materials and Design, 2020, vol. 185, article number 108259. doi: 10.1016/j.matdes.2019.108259.
- Esmaily M., Svensson J.E., Fajardo S., Birbilis N., Frankel G.S., Virtanen S., Arrabal R., Thomas S., Johansson L.G. Fundamentals and advances in magnesium alloy corrosion. Progress in Materials Science, 2017, vol. 89, pp. 92–193. doi: 10.1016/j.pmatsci.2017.04.011.
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