CUPRUM-ZINC COATING WITH HIGH SPECIFIC SURFACE PRODUCED BY METAL ELECTRODEPOSITION METHOD


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Abstract

The improvement of chemical and petrochemical plants’ efficiency and the environmental management are impossible without the development of new technologies and materials. All this is directly concerned with the introduction of new catalysts. Each chemical reaction requires its own catalysts. Currently, solid metal catalysts with the multicomponent composition are determined as the prospective ones. They show mechanical strength and high thermal conductivity but, in some cases, they have low specific surface. That is why the development of the multicomponent material with high specific surface spread on metal micronet that could be used in future as the advanced catalyst is the critical task.   

As opposed to the methods of producing multicomponent materials and methods of creation of developed surface of metal oxide coatings presented in the paper survey, this paper covers the producing the developed surface coating on micronet consisting of nanosized cuprum and zinc particles. The author suggests the creation of two-component (cuprum-zinc) coating with the high specific surface by means of electrodeposition from the complex electrolyte. Two series of experiments were carried out during the study. At the first stage, the electrodeposition was carried out in the stationary layer of complex cuprum-zinc electrolyte; at the second stage of experiments, the electrodeposition was carried out in the same electrolyte at the same deposition parameters but with the electrolyte mixing at various stages of electrolysis.       

During each series of experiments, the author determined the technological modes of the coating producing, its composition and specific surface. It is shown that it is possible to change zinc concentration in the coating and its specific surface at various technological modes of deposition (with the electrolyte mixing and without it). The study allowed making the conclusion on the most optimal technological conditions of electrodeposition with the purpose of producing certain cuprum and zinc concentration in the coating. Preliminary tests showed that such cuprum-zinc coating can be used for wastewater aftertreatment from ethylene glycol.    

About the authors

Alena Gennadyevna Denisova

Togliatti State University, Togliatti

Author for correspondence.
Email: aliona.denisova.tlt@gmail.com

postgraduate student of “Nanotechnologies, material engineering and mechanics”

Россия

References

  1. Merson D.L., ed. Perspektivnye materialy [Perspective materials]. Togliatti, TGU Publ., 2013. Vol. 5, 421 p.
  2. Vikarchuk A.A., Romanov A.E. Principal physics of getting fundamentally new cuprum-based catalysts. Fundamentalnye problemy sovremennogo materialovedeniya, 2014, no. 11, pp. 87–98.
  3. Aleksandrova Ju.V., Vlasov E.A. Copper-containing oxidation catalysts properties study. Izvestiya Sankt-Peterburgskogo gosudarstvennogo tekhnologicheskogo instituta (tekhnicheskogo universiteta), 2013, no. 22, pp. 15–20.
  4. Yuranov I., Dunand N., Kiwi-Minsker L., Renken A. Metal grids with high-porous surface as structured catalysts: preparation, characterization and activity in propane total oxidation. Applied Catalysis B: Environmental, 2002, no. 36, pp. 183–185.
  5. Kruglova M.A., Yaroshenko M.P., Antonyuk S.N., Golosman E.Z. Catalysts for the process of hydrogen fuel producing. Tonkie khimicheskie tekhnologii, 2008, vol. 3, no. 6, pp. 22–25.
  6. Vedyagin A.A., Tsyrulnikov P.G., Struikhina N.O., Dashuk T.A., Bubnov A.V. Methanol dehydrogenation over copper-containing catalysts modified by zinc oxide. Kataliz v promyshlennosti, 2006, no. 3, pp. 29–33.
  7. Vinogradova E.N. Study of nickel oxide, cuprum and cobalt-based catalysts in the process of methane oxidation. Uspekhi v khimii i khimicheskoy tekhnologii, 2009, vol. 23, no. 2, pp. 43–47.
  8. Ovsienko O.L. Effect of supplementation of nitrate and cesium formiate on properties of CO conversion Cu-Zn-Al catalyst. Kataliz v promyshlennosti, 2011, no. 6, pp. 60а–66.
  9. Gryzunova N.N., Vikarchuk A.A., Shafeev M.R., Gryzunov A.M. Creation of the developed surface of mesh metal carriers made of stainless steel. Vektor nauki Tolyattinskogo gosudarstvennogo universiteta, 2014, no. 4, pp. 25–29.
  10. Gryzunova N.N., Vikarchuk A.A., Shafeev M.R. Creating high surface in the metal mesh carrier. Pisma o materialakh, 2015, vol. 5, no. 2, pp. 211–214.
  11. Gryzunova N.N., Denisova A.G., Yasnikov I.S., Vikarchuk A.A. Preparation of materials with a developed surface by thermal treatment and chemical etching of electrodeposited icosahedral small copper particles. Russian Journal of Electrochemistry, 2015, vol. 51, no. 12, pp. 1176–1179.
  12. Gryzunova N.N., Denisova A.G., Yasnikov I.S., Vikarchuk A.A. Preparation of materials with a developed surface by thermal treatment and chemical etching of electrodeposited icosahedral small copper particles. Elektrokhimiya, 2015, vol. 51, no. 12, pp. 1317–1320.
  13. Denisova A.G., Gryzunova N.N. An alternative method of producing whisker structures copper. Nauchniy almanakh, 2015, no. 6, pp. 120–124.
  14. Gryzunova N.N., Vikarchuk A.A., Tyurkov M.N. Production and investigation of electrolytic energy-intensive materials with defect structure and developed surface. Deformatsiya i razrushenie materialov, 2016, no. 2, pp. 13–19.
  15. Vikarchuk A.A., Vlasenkova E.Yu., Gryzunova N.N. Fabrication of nanosized metallic objects by thermal processing of pentagonal particles and nanotubes. Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy akademii nauk, 2008, no. S6, pp. 44–49.
  16. Gryzunova N.N., Vikarchuk A.A. On the extend of specific surface of metal catalysts and carriers for them. Novosti materialovedeniya. Nauka i tekhnika, 2015, no. 1, pp. 6–11.
  17. Yasnikov I.S., Vikarchuk A.A. Thermodynamics of cavity formation in pentagonal crystals during electrodeposition of copper. Izvestiya Rossiyskoy akademii nauk. Seriya fizicheskaya, 2005, vol. 69, no. 9, pp. 1378–1382.
  18. Vikarchuk A.A., Dorogov M.V. Special aspects of evolution of the structure and morphology of surface of cuprum icosahedral particles in the annealing process. Pisma v zhurnal eksperimentalnoy i teoreticheskoy fiziki, 2013, vol. 97, no. 9-10, pp. 682–686.
  19. Gryzunova N.N., Vikarchuk A.A., Shafeev M.R., Romanov A.E. Morphological and phase transformations in nickel coatings on stainless steel in temperature fields. Materials Physics and Mechanics, 2014, vol. 21, no. 2, pp. 119–125.
  20. Gryzunova N.N., Vikarchuk A.A., Bekin V.V., Romanov A.E. Creating a developed surface of copper electrolytic coatings via mechanical activation of the cathode with subsequent thermal treatment. Izvestiya Rossiyskoy akademii nauk. Seriya fizicheskaya, 2015, vol. 79, no. 9, pp. 1238–1242.

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