The influence of boron carbide additive on the structure and hardness of a nickel-based coating

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Abstract

Laser cladding is increasingly frequently used in various branches of mechanical engineering since it has such advantages over traditional methods of depositing coatings as high heating and cooling rates and minimal mixing of base and melting materials. Laser-clad coatings are usually characterized by a fine-grained structure and a minimal heat-affected zone. Coatings formed from the Ni–Cr–B–Si powders are also very common in industrial applications, as they have good resistance to wear, corrosion, erosion, etc. Various strengthening particles can be added to this group of powders to improve the properties of the deposited coating. Boron carbides can act as such particles since they have high hardness, thermodynamic stability, and wear resistance. In this regard, the paper investigated the influence of the 7 wt. % of boron carbide B4C addition on the structure and hardness of the NiCrBSi coating formed by laser cladding of PG-SR2 powder on the surface of 30HRA steel. Using the scanning electron microscope, the authors carried out microscopic studies of the structure of NiCrBSi and NiCrBSi–B4C coatings and presented the results of X-ray spectral microanalysis. The study shows that the structures of both coatings in the deposited state are characterized by uniformity and fine-grain structure. The investigation revealed that the samples with NiCrBSi and NiCrBSi–B4C coatings have a narrow transition zone from the deposit to the base metal. The paper presents the results of measuring the microhardness of coatings indicating a decrease in the microhardness of laser-clad nickel-based coatings with the boron carbide addition. 

About the authors

Uliana S. Starikova

M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg (Russia)

Author for correspondence.
Email: ulstar97@mail.ru
ORCID iD: 0000-0001-6960-0619

junior researcher

Россия

Natalia N. Soboleva

Institute of Engineering Science of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg (Russia)

Email: fake@neicon.ru
ORCID iD: 0000-0002-7598-2980

PhD (Engineering), senior researcher

Россия

Aleksey V. Makarov

M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg (Russia)

Email: fake@neicon.ru
ORCID iD: 0000-0002-2228-0643

Corresponding member of RAS, Doctor of Sciences (Engineering), Head of Department of Materials Science and the Laboratory of Mechanical Properties

Россия

Evgeny V. Kharanzhevsky

Udmurt State University, Izhevsk (Russia)

Email: fake@neicon.ru
ORCID iD: 0000-0002-1525-2169

Doctor of Sciences (Engineering), Professor, Head of Laboratory

Россия

References

  1. Zemlyakov E., Babkin K., Korsmik R., Sklyar M., Kuznetsov M. Prospects of use of laser cladding technology for restoration of compressor blades of gas turbine engines. Fotonika, 2016, no. 4, pp. 10–25. doi: 10.22184/1993-7296.2016.58.4.10.22.
  2. Golubovskiy E.N., Parkin A.A., Zhatkin S.S. Repair of cracks on sectors of gas-turbine engine shovels by method of cutting and laser pulse cladding. Izvestiya Samarskogo nauchnogo tsentra Rossiyskoy akademii nauk, 2020, vol. 22, no. 2, pp. 107–112.
  3. Soboleva N.N., Makarov A.V., Malygina I.Yu. Technological aspects of friction treatment of PG-SR2 coating formed by laser cladding. Vektor nauki Tolyattinskogo gosudarstvennogo universiteta, 2019, no. 3, pp. 47–53. doi: 10.18323/2073-5073-2019-3-47-53.
  4. Gibzun M.S., Makarov A.V., Soboleva N.N., Malygina I.Yu. Increasing frictional thermal resistance of Ni-Cr coating using combined laser-heat treatment. Master’s journal, 2017, no. 1, pp. 11–16.
  5. Shi B.W., Li T., Wang D., Zhang X.R., Zhang H.C. Investigation on crack behavior of Ni60A alloy coating produced by coaxial laser cladding. Journal of Materials Science, 2021, vol. 56, no. 23, pp. 13323–13336. doi: 10.1007/s10853-021-06108-5.
  6. Miguel J.M., Guilemany J.M., Vizcaino S. Tribological study of NiCrBSi coating obtained by different processes. Tribology International, 2003, vol. 36, no. 3, pp. 181–187. doi: 10.1016/S0301-679X(02)00144-5.
  7. Niranatlumpong P., Koiprasert H. Phase transformation of NiCrBSi–WC and NiBSi–WC arc sprayed coatings. Surface and Coatings Technology, 2011, vol. 206, no. 2-3, pp. 440–445. doi: 10.1016/j.surfcoat.2011.07.057.
  8. Sha J., Chen L.-Y., Liu Y.-T., Yao Z.-J., Lu S., Wang Z.-X., Zang Q.-H., Mao S.-H., Zhang L.-C. Phase transformation-induced improvement in hardness and high-temperature wear resistance of plasma-sprayed and remelted NiCrBSi/WC coatings. Metals, 2020, vol. 10, no. 12, article number 1688. doi: 10.3390/met10121688.
  9. Soboleva N.N., Nikolaeva E.P., Makarov A.V., Malygina I.Yu. The influence of chromium carbide additive on the structure and abrasive wear resistance of the NiCrBSi coating formed by laser cladding. Vektor nauki Tolyattinskogo gosudarstvennogo universiteta, 2020, no. 1, pp. 68–76. doi: 10.18323/2073-5073-2020-1-68-76.
  10. Makarov A.V., Soboleva N.N., Malygina I.Yu., Osintseva A.L. The formation of NiCrBSi–TiC composite coating with increased abrasive wear resistance by gas powder laser cladding. Uprochnyayushchie tekhnologii i pokrytiya, 2013, no. 11, pp. 38–44.
  11. Fals H.C., Aguiar D., Fanton L., Belém M.J.X., Lima C.R.C. A new approach of abrasive wear performance of flame sprayed NiCrSiBFeC/SiC composite coating. Wear, 2021, vol. 477, no. SI, article number 203887. doi: 10.1016/j.wear.2021.203887.
  12. Senapati P., Sutar H. Surface erosion behaviour over NiCrBSi-Al2O3 composite coatings. Materials Research Express, 2020, vol. 7, no. 7, article number 076512. doi: 10.1088/2053-1591/aba396.
  13. Li H.J., He Y., Luo P.Y., Fan Y., Yu H., Wang Y.Q., He T., Li Z.J., Zhang H.L. Influence of pulse frequency on corrosion resistance and mechanical properties of Ni-W/B4C composite coatings. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, vol. 629, article number 127436. doi: 10.1016/j.colsurfa.2021.127436.
  14. Krivizhenko D.S., Drobyaz E.A., Zimoglyadova T.A. Structure formation features of boron-containing coatings obtained by highspeed treatment. Aktualnye problemy v mashinostroenii, 2014, no. 1, pp. 489–492.
  15. Golyshev A.A., Filippov A.A. Comparative investigation of nickel-based metal-ceramic structures with ceramic particles of tungsten and carbides made by the selective laser melting method. Nanoscience and Technology, 2020, vol. 11, no. 3, pp. 247–257. doi: 10.1615/NanoSciTechnolIntJ.2020033784.
  16. Fan X.H., Geng L., Xu B., Li J. Laser Cladding NiCrBSi+2%B4C Coating on Ti-6Al-4V. Advanced Materials Research, 2009, vol. 79-82, pp. 473–476. doi: 10.4028/ href='www.scientific.net/AMR.79-82.473' target='_blank'>www.scientific.net/AMR.79-82.473.
  17. Meng Q.W., Geng L., Zhang B.Y. Laser cladding of Ni-base composite coatings onto Ti–6Al–4V substrates with pre-placed B4C+NiCrBSi powders. Surface and Coatings Technology, 2006, vol. 200, no. 16-17, pp. 4923–4928. doi: 10.1016/j.surfcoat.2005.04.059.
  18. Geng L., Meng Q.W., Chen Y.B. In-situ Synthesis of Metal Matrix Composite Coating with Laser Melting-Solidifying Processes. Composite materials IV. Key Engineering Materials, 2006, vol. 313, pp. 139–144. doi: 10.4028/ href='www.scientific.net/KEM.313.139' target='_blank'>www.scientific.net/KEM.313.139.
  19. Golubev V.S., Vegera I.I., Chernasheyus O., Chaevskiy V.V. Laser treatment of materials with change of chemical composition of the surface layer. Vestnik Baranovichskogo gosudarstvennogo universiteta. Seriya: Tekhnicheskie nauki, 2019, no. 7, pp. 34–42.
  20. Drobyaz E.A., Krivizhenko D.S., Polyakov I.A., Nagavkin S.Yu., Ivantsivskiy V.V. Structure and properties of boron-containing coatings, deposited by non-vacuum electron beam. Obrabotka metallov (tekhnologiya, oborudovanie, instrumenty), 2012, no. 4, pp. 83–85.
  21. Zusin V.Ya. Investigation of metal modification, deposited with powder wire with aluminums shell. Vestnik Priazovskogo gosudarstvennogo universiteta. Seriya: Tekhnicheskie nauki, 2011, no. 23, pp. 180–183.
  22. Eremin E.N. Application of nanoparticles of refractory compounds for improving the quality of welding joints made of heat-resistant alloys. Omskiy nauchnyy vestnik, 2009, no. 3, pp. 63–67.
  23. Zernin E.A., Kuznetsov M.A. Method of modifying the weld metal nanostructured powders for increasing the mechanical properties of welded joints. Sovremennye problemy nauki i obrazovaniya, 2014, no. 5, pp. 206–212.

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