No 1 (2023)

Cover Page

The study of the influence of micro-arc oxidation modes on the morphology and parameters of an oxide coating on the D16AT aluminum alloy

Bao F., Bashkov O.V., Zhang D., Lyu L., Bashkova T.I.

Abstract

An effective way to protect valve metals and their alloys is the micro-arc oxidation method (MAO), which is currently used in various industries. However, to achieve the desired characteristics and properties of oxide coatings, a large number of experiments are required to determine an optimal oxidation mode, which makes the MAO method labor-intensive and resource-consuming. One of the ways to solve this problem is the search for an informative parameter or several parameters, the use of which during the oxidation process monitoring allows identifying a relationship between the MAO modes and the specified characteristics of oxide coatings. This paper studies the influence of the specified technological MAO modes (current density, oxidation time, amplitude of acoustic emission (AE) signals recorded during MAO) on the morphology and parameters of oxide coatings (thickness δ and surface roughness Ra) deposited on the D16AT aluminum alloy clad with pure aluminum. Multivariate planning of an experiment and the performed regression analysis allowed establishing a relationship between two oxidation factors (current density and oxidation time) and the parameters of the produced coatings. The authors proposed an additional factor, which is determined in the monitoring mode during the oxidation process as the time from the moment when the maximum or minimum of the acoustic emission (AE) amplitude recorded in the MAO process is reached until the end of the oxidation process. The study established that the introduction of an additional factor allows increasing significantly the reliability of the dependence between the coating parameters obtained experimentally and by the computational method based on the regression analysis. The authors note that when performing MAO, with the additional use of the MAO process monitoring by recording the AE amplitude, it is possible to achieve a high reliability between the calculated and actual values of the parameters of oxide coatings.

Frontier Materials & Technologies. 2023;(1):7-21
pages 7-21 views

Numerical modeling of temperature fields during friction stir welding of the AA5083 aluminum alloy

Zybin I.N., Antokhin M.S.

Abstract

One of the important parameters ensuring the production of a welded joint without continuity defects during friction stir welding is the provision of the required temperature in the metal bonding zone. Significant difficulties arise when determining experimentally the temperature directly in the stir zone of metals using thermocouples. In this regard, the application of numerical methods describing the distribution of temperature fields during friction stir welding is relevant. In the work, numerical modeling of temperature fields during friction stir welding was used, which was based on the finite element method using Abaqus/Explicit software. Modeling was carried out taking into account the coupled Euler – Lagrange approach, the Johnson – Cook plasticity model, and the Coulomb friction law. Using the finite element method, the models of a part, substrate, and tool were constructed taking into account their thermophysical properties. To reduce the computation time, an approach based on the metal mass scaling by recalculating the density of the metal and its thermal properties was used. The authors matched coefficients of scaling of the material mass and heat capacity for the selected welding mode parameters. To evaluate the validity of the results of numerical modeling of temperature fields during friction stir welding, the experimental research of the temperature fields using thermocouples was carried out. The paper shows the possibility of numerical modeling of temperature fields during friction stir welding with the help of the coupled Euler – Lagrange approach and Abaqus/Explicit software. Due to the application of the approach associated with material mass scaling, the calculation time is reduced by more than 10 times.

Frontier Materials & Technologies. 2023;(1):23-32
pages 23-32 views

Characteristic properties of the microstructure and microtexture of medium-carbon steel subjected to sulfide stress cracking

Malinin A.V., Sitdikov V.V., Tkacheva V.E., Makatrov A.K., Valekzhanin I.V., Markin A.N.

Abstract

Increasing the resistance of steel products to sulfide stress cracking (SSC) is one of the topical issues of the oil and gas industry. Among various factors determining the SSC resistance of a material is the structure-phase state of the material itself and the crystallographic texture associated with it. This paper analyzes these features using the scanning electron microscopy (SEM), transmission electron microscopy (TEM), and microroentgen electron backscattered diffraction (EBSD) techniques. As the research material, a production string (PS) coupling made of medium-carbon steel was selected, which collapsed by the mechanism of hydrogen embrittlement and subsequent SSC. For the first time, by the SEM method, using the location and mutual orientation of cementite (Fe3C) particles, at high magnifications, the authors demonstrated the possibilities of identifying the components of upper bainite, lower bainite, and tempered martensite in steels. The presence of the detected structural components of steel was confirmed by transmission electron microscopy (TEM). Using the EBSD method, the detailed studies of microtexture were conducted to identify the type and nature of the microcrack propagation. It is established that the processes of hydrogen embrittlement and subsequent SSC lead to the formation of {101} <0 0>, {100} <001>, {122} <2 0>, {013} <211>, {111} < 00>, {133} < 1>, {3 } <201> grain orientations. It is shown that the strengthening of orientations of {001} <110>, {100} <001>, {112} <111>, and {133} < 1> types worsens the SSC resistance of the material. Using the EBSD analysis method, the influence of coincident site lattice (CSL) grain boundaries on the nature of microcrack propagation is estimated. It is found that the Σ 3 CSL grain boundaries between the {122} <2 0> and {111} < 00>, {012} < 0>, {100} <001> plates of the upper bainite inhibit the microcrack development, and the Σ 13b, Σ 29a, and Σ 39a CSL grain boundaries, contribute to the accelerated propagation of microcracks. For comparative analysis, similar studies were carried out in an unbroken (original) coupling before operation.

Frontier Materials & Technologies. 2023;(1):33-44
pages 33-44 views

Strain rate sensitivity of mechanical properties of the ZK60 alloy with the high degree of corrosion damage

Merson E.D., Poluyanov V.A., Myagkikh P.N., Merson D.L.

Abstract

There is a strong belief that hydrogen absorbed by magnesium alloys during corrosion can cause their stress corrosion cracking. One of the characteristic markers indicating the involvement of diffusible hydrogen into the fracture mechanism of metals is the negative strain rate dependence of the embrittlement degree. Recent studies show that the loss of ductility of the ZK60 alloy specimens subjected to a short-term (1.5 h) pre-exposure in a corrosive medium actually decreases with the increasing strain rate. However, after the removal of corrosion products from the surface of the specimens, the strain rate dependence of the ductility loss becomes positive, which indicates the absence of hydrogen in the bulk of the metal. At short-term exposure in a corrosive environment, the deep penetration of hydrogen into a metal could be limited due to the insufficient time for hydrogen diffusion. The paper studies the mechanical behavior of the ZK60 alloy subjected to a longer (12 h) pre-exposure in a corrosive medium followed by tensile testing in air at various strain rates. The authors consider the effect of strain rate, long-term pre-exposure in a corrosive medium, and subsequent removal of corrosion products on the strength, ductility, stages of work hardening, and localized deformation, as well as on the state of the side and fracture surfaces of specimens. It is established that the ductility loss of the specimens pre-exposed in a corrosive medium for 12 h decreases with the increasing strain rate, regardless of whether the corrosion products have been removed from their surface or not. It is shown that in this case, the negative strain rate dependence of the ductility loss is associated not with hydrogen dissolved in the bulk of a metal but with the presence of severe corrosion damage of the specimens’ surface. An explanation for the effect of corrosion damage on the mechanical properties and their strain rate sensitivity is proposed. 

Frontier Materials & Technologies. 2023;(1):45-55
pages 45-55 views

Statistical dependences of influence of ultrasonic exposure time on the strength and other parameters of a polypropylene welded joint

Murashkin S.V., Selivanov A.S., Spiridonov N.G., Savina E.B.

Abstract

Polypropylene is one of the most popular thermoplastic materials used in industry. To produce goods from this material, the ultrasonic welding method is often used. However, despite a large number of scientific papers, the influence of some parameters of the ultrasonic welding mode on the strength characteristics of polypropylene joints remains unstudied. The paper presents the results of experimental studies of contact spot ultrasonic welding of plates 3 mm thick made of 01003-26 grade polypropylene. The authors considered the process of gradual penetration of the ultrasonic tool working face into polypropylene to a depth equal to the total thickness of the welded plates. Statistical dependences of the depth of the tool face penetration into the material and the force of material separation on the ultrasound exposure time are obtained. The influence of the depth of the ultrasonic tool working face penetration on the tearing force of welded specimens is determined. A significant increase in the tearing force from 150 to 400 N was found at the tool penetration depth of more than 3.5 mm due to an increase in the nominal area of mutual mixing of the material between the welded plates caused by the flow of molten material into the gap. The authors proposed a hypothesis about the flow of the molten material in the direction opposite to the direction of penetration of the working tool by forming traveling Rayleigh waves. However, its confirmation requires additional studies of the influence of the ultrasonic welding mode parameters and the size of the gap between the parts to be joined on the rate of the molten material flow into the gap.

Frontier Materials & Technologies. 2023;(1):57-67
pages 57-67 views

Fatigue strength of 30ХГСА–40ХМФА welded joints produced by rotary friction welding

Priymak E.Y., Kuzmina E.A., Gladkovskii S.V., Vichuzhanin D.I., Veselova V.E.

Abstract

Rotary friction welding (RFW) is used in the production of drill pipes for solid mineral prospecting. The need for the creation of the lightened drill strings for high-speed diamond drilling of ultradeep wells dictates the necessity of a greater focus on the study of a weld zone and setting the RFW technological parameters. This paper presents the results of experimental studies of a welded joint of a drill pipe of the H standard size according to ISO 10097, made of the 30ХГСА (pipe body) and 40ХМФА (tool joint) steels under the cyclic loads. The authors evaluated the influence of the force applied to the workpieces in the process of friction of the contacting surfaces (force during heating), and postweld tempering at a temperature of 550 °С on the cyclic life of welded joints, under the conditions of alternate tension-compression at the cycle amplitude stress of ±420 MPa. The study determined that with an increase in the force during heating, the microstructure changes occur in the zone of thermomechanical influence, contributing to an increase in the fatigue strength of welded joints. The authors identified the negative effect of postweld tempering on the fatigue strength of welded joints, which is expressed in the decrease in the number of cycles before failure by 15–40 %, depending on the magnitude of the force during heating. The optimal RFW mode of the specified combination of steels is determined, which provides the largest number of cycles before failure: the force during heating (at friction) Fh=120 kN, forging force Ffor=160 kN, rotational frequency during heating n=800 Rpm, and upset during heating l=8 mm. A series of fatigue tests have been carried out at various values of the cycle amplitude stress of the welded joint produced at the optimal mode and the 30ХГСА steel base metal; limited endurance curves have been plotted. It is shown that the differences in the limited endurance curves of the pipe body material (30ХГСА steel) and the welded joint are insignificant. The obtained results are supplemented by the microhardness measurement data and fractographs of fractured samples, revealing the mechanism of crack propagation under the cyclic loads.

Frontier Materials & Technologies. 2023;(1):69-81
pages 69-81 views

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