Special aspects of the microstructure evolution at the temperature-speed deformation of a medical purpose magnesium alloy of the Mg–Zn–Y alloying system

Abstract

Biocompatibility makes magnesium alloys attractive functional materials in terms of their use as biodegradable implants. However, the technologies for manufacturing semi-finished products carry a possible diversity of the local strain rate and temperature within a rather wide range, which affects the processed material structure and properties. The purpose of the study is to determine the range of temperatures and resistance to deformation, at which there is no negative effect on the main structural characteristics of the processed material, using the example of a medical purposes alloy of the Mg–Zn–Y alloying system. The authors carried out mechanical tests of a biodegradable Mg–1Zn–2.9Y magnesium alloy at various temperatures and strain rates. The influence of temperatures in the range of 20...400 °C on the structure and properties of the Mg–Zn–Y system alloy is disclosed. Starting from a temperature of 350 °C, the process of dynamic recrystallization is accompanied both by the complete restoration (return) of the original microstructure and by coarsening of the grain size, which can adversely affect the material functional characteristics. The high thermal stability of the biodegradable Mg–1Zn–2.9Y magnesium alloy is revealed, which probably results from the presence of the LPSO phase in it. The study shows that the deformation process is accompanied by twinning. At a strain rate of 2∙10−2 s−1 over the entire temperature range, the grain size distribution slightly narrows and shifts towards smaller diameters. The application of the obtained results in technological processes for manufacturing medical semi-finished products will help to solve the issue of microstructure instability at the stage of transition from a semi-finished product to a finished product during subsequent thermomechanical treatments.

About the authors

Kristina K. Kudasheva

Togliatti State University

Author for correspondence.
Email: a.abdugaffarova@gmail.com

engineer of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

Mikhail L. Linderov

Togliatti State University

Email: dartvi@gmail.com
ORCID iD: 0000-0001-8655-4191

PhD (Physics and Mathematics), senior researcher of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

Aleksandr I. Brilevskiy

Togliatti State University

Email: alexandrbril@yandex.ru
ORCID iD: 0000-0002-5780-6094

junior researcher of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

Aleksey V. Danyuk

Togliatti State University

Email: alexey.danyuk@gmail.com
ORCID iD: 0000-0002-7352-9947

PhD (Physics and Mathematics), senior researcher of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

Igor S. Yasnikov

Togliatti State University

Email: yasnikov@phystech.edu
ORCID iD: 0000-0002-6120-7836

Doctor of Sciences (Physics and Mathematics), Associate Professor, professor of Chair “General and Theoretical Physics”, leading researcher of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

Dmitry L. Merson

Togliatti State University

Email: d.merson@tltsu.ru
ORCID iD: 0000-0001-5006-4115

Doctor of Sciences (Physics and Mathematics), Professor, Director of the Research Institute of Advanced Technologies

Россия, 445020, Russia, Togliatti, Belorusskaya Street, 14

References

  1. Prakasam M., Locs J., Salma-Ancane K., Loca D., Largeteau A., Berzina-Cimdina L. Biodegradable materials and metallic implants-A review. Journal of Functional Biomaterials, 2017, vol. 8, no. 4, article number 44. doi: 10.3390/jfb8040044.
  2. Li Nan, Zheng Yufeng. Novel Magnesium Alloys Developed for Biomedical Application: A Review. Journal of Materials Science & Technology, 2013, vol. 29, no. 6, pp. 489–502. doi: 10.1016/j.jmst.2013.02.005.
  3. Kumar K., Gill R.S., Batra U. Challenges and opportunities for biodegradable magnesium alloy implants. Materials Technology, 2018, vol. 33, no. 2, pp. 153–172. doi: 10.1080/10667857.2017.1377973.
  4. Hort N., Huang Y., Fechner D. et al. Magnesium alloys as implant materials – Principles of property design for Mg–RE alloys. Acta Biomaterialia, 2010, vol. 6, no. 5, pp. 1714–1725. doi: 10.1016/j.actbio.2009.09.010.
  5. Song Guang-Ling, Song Shizhe. A Possible Biodegradable Magnesium Implant Material. Advanced Engineering Materials, 2007, vol. 9, no. 4, pp. 298–302. doi: 10.1002/adem.200600252.
  6. Ali W., Mehboob A., Han Min-Gu, Chang Seung-Hwan. Experimental study on degradation of mechanical properties of biodegradable magnesium alloy (AZ31) wires/poly(lactic acid) composite for bone fracture healing applications. Composite Structures, 2019, vol. 210, pp. 914–921. doi: 10.1016/j.compstruct.2018.12.011.
  7. Bommala V.K., Krishna M.G., Rao C.T. Magnesium matrix composites for biomedical applications: A review. Journal of Magnesium and Alloys, 2019, vol. 7, no. 1, pp. 72–79. doi: 10.1016/j.jma.2018.11.001.
  8. Suljevic O., Fischerauer S.F., Weinberg A.M., Sommer N.G. Immunological reaction to magnesium-based implants for orthopedic applications. What do we know so far? A systematic review on in vivo studies. Materials Today Bio, 2022, vol. 15, article number 100315. doi: 10.1016/j.mtbio.2022.100315.
  9. Liu Wenwen, Guo Shuo, Tang Zhen, Wei Xinghui, Gao Peng, Wang Ning, Li Xiaokang, Guo Zheng. Magnesium promotes bone formation and angiogenesis by enhancing MC3T3-E1 secretion of PDGF-BB. Biochemical and Biophysical Research Communications, 2020, vol. 528, no. 4, pp. 664–670. doi: 10.1016/j.bbrc.2020.05.113.
  10. Xia Yu, Wu Liang, Yao Wen-hui et al. In-situ layered double hydroxides on Mg−Ca alloy: Role of calcium in magnesium alloy. Transactions of Nonferrous Metals Society of China, 2021, vol. 31, no. 6, pp. 1612–1627. doi: 10.1016/S1003-6326(21)65602-9.
  11. Dong Jianhui, Lin Tao, Shao Huiping, Wang Hao, Wang Xueting, Song Ke, Li Qianghua. Advances in degradation behaviour of biomedical magnesium alloys: A review. Journal of Alloys and Compounds, 2022, vol. 908, article number 164600. doi: 10.1016/j.jallcom.2022.164600.
  12. Chen Junxiu, Kolawole S.K., Wang Jianhua, Su Xuping, Tan Lili, Yang Ke. Systems, Properties, Surface Modification and Applications of Biodegradable Magnesium-Based Alloys: A Review. Materials, 2022, vol. 15, no. 14, p. 5031. doi: 10.3390/ma15145031.
  13. Tekumalla S., Seetharaman S., Almajid A., Gupta M. Mechanical Properties of Magnesium-Rare Earth Alloy Systems: A Review. Metals, 2015, vol. 5, no. 1, pp. 1–39. doi: 10.3390/met5010001.
  14. Das A.K. Recent trends in laser cladding and alloying on magnesium alloys: A review. Materials Today: Proceedings, 2022, vol. 51, part 1, pp. 723–727. doi: 10.1016/j.matpr.2021.06.217.
  15. Gao Jia-cheng, Wu Sha, Qiao Li-ying, Wang Yong. Corrosion behavior of Mg and Mg-Zn alloys in simulated body fluid. Transactions of Nonferrous Metals Society of China, 2008, vol. 18, no. 3, pp. 588–592. doi: 10.1016/S1003-6326(08)60102-8.
  16. Jagadeesh G.V., Setti S.G. Surface Modification of Biodegradable Magnesium Alloy by Ball Burnishing Process. Recent Advances in Materials Technologies: Select Proceedings of ICEMT 2021. Springer Nature Singapore, 2023, pp. 327–334. doi: 10.1007/978-981-19-3895-5_26.
  17. Figueiredo R.B., Langdon T.G. Achieving Microstructural Refinement in Magnesium Alloys through Severe Plastic Deformation. Materials Transactions, 2009, vol. 50, no. 1, pp. 111–116. doi: 10.2320/matertrans.MD200818.
  18. Bryła K., Dutkiewicz J., Lityńska-Dobrzyńska L., Rokhlin L.L., Kurtyka P. Influence of number of ECAP passes on microstructure and mechanical properties of AZ31 magnesium alloy. Archives of Metallurgy and Materials, 2012, vol. 57, no. 3, pp. 711–717. doi: 10.2478/v10172-012-0077-5.
  19. Aksenov D.A., Nazarov A.A., Raab G.I., Raab A.G., Fakhretdinova E.I., Asfandiyarov R.N., Shishkunova M.A., Sementeeva Yu.R. Effects of Severe Plastic Deformation and Ultrasonic Treatment on the Structure, Strength, and Corrosion Resistance of Mg–Al–Zn Alloy. Materials, 2022, vol. 15, no. 20, p. 7200. doi: 10.3390/ma15207200.
  20. Merson D., Linderov M., Brilevsky A., Danyuk A., Vinogradov A. Monitoring Dynamic Recrystallisation in Bioresorbable Alloy Mg–1Zn–0.2Ca by Means of an In Situ Acoustic Emission Technique. Materials, 2022, vol. 15, no. 1, p. 328. doi: 10.3390/ma15010328.

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2024 Kudasheva K.K., Linderov M.L., Brilevskiy A.I., Danyuk A.V., Yasnikov I.S., Merson D.L.

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies