The influence of hafnium on high-magnesium alloys doped with transition metals during heat treatment
- Authors: Zorin I.A.1,2, Aryshenskiy E.V.2, Kudryavtsev E.A.3, Drits A.M.1, Konovalov S.V.2
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Affiliations:
- Samara National Research University
- Siberian State Industrial University
- Belgorod State National Research University
- Issue: No 1 (2024)
- Pages: 29-36
- Section: Articles
- URL: https://vektornaukitech.ru/jour/article/view/905
- DOI: https://doi.org/10.18323/2782-4039-2024-1-67-3
- ID: 905
Cite item
Abstract
The purpose of the work is to study the influence of hafnium additives on the mechanical properties and thermal stability of particles at elevated temperature during heat treatment of aluminum alloys with a high magnesium content. Two modifications of 1570 alloy were chosen for the study: without hafnium content and with its addition of 0.5 % by weight. Both alloys were subjected to homogenizing annealing at a temperature of 440 °C with different exposure modes, which ranged from 2 to 100 h. Microhardness was studied for various heat treatment modes, and the fine microstructure was studied as well using transmission microscopy. As a result, it was possible to identify that during annealing at a short exposure time (2–8 h), the alloy with the hafnium addition has higher microhardness values exceeding those of 1570 alloy by an average of 20 HV units. This is associated with the fact that in 1570 alloy with hafnium additives, during heat treatment, the number of precipitated particles increases while their average size decreases compared to the base alloy. At the same time, in 1570 alloy without hafnium content, when annealed at a temperature of 440 °C, there is no increase in microhardness. This is caused by the fact that in 1570 alloy without hafnium content, when cooled after casting, discontinuous decomposition occurs, which resulted in the fact that most of the scandium precipitates from the supersaturated solid solution in the form of dispersoids. This phenomenon is not observed in the alloy with hafnium additives, which indicates its ability to stop discontinuous decomposition during cooling the ingot after casting.
About the authors
Igor A. Zorin
Samara National Research University;Siberian State Industrial University
Author for correspondence.
Email: zorin.ia@ssau.ru
ORCID iD: 0000-0001-9349-2494
laboratory assistant-researcher, student, II category electronic engineer of the Laboratory of Mechanical Testing and Electron Microscopy
Russian Federation, 443086, Russia, Samara, Moskovskoye Shosse, 34; 654007, Russia, Novokuznetsk, Kirov Street, 42Evgeny V. Aryshenskiy
Siberian State Industrial University
Email: arishenskiy_ev@sibsiu.ru
ORCID iD: 0000-0003-3875-7749
Doctor of Sciences (Engineering), Associate Professor, senior researcher of the Laboratory of Electron Microscopy and Image Processing
Russian Federation, 654007, Russia, Novokuznetsk, Kirov Street, 42Egor A. Kudryavtsev
Belgorod State National Research University
Email: egoryoda@mail.ru
ORCID iD: 0000-0003-1113-0807
PhD (Engineering), researcher of the Common Use Center “Technologies and Materials of the National Research University BelSU”
Russian Federation, 308015, Russia, Belgorod, Pobedy Street, 85Aleksandr M. Drits
Samara National Research University
Email: alexander.drits@samara-metallurg.ru
ORCID iD: 0000-0002-9468-8736
PhD (Engineering), leading researcher
Russian Federation, 443086, Russia, Samara, Moskovskoye Shosse, 34Sergey V. Konovalov
Siberian State Industrial University
Email: konovalov@sibsiu.ru
ORCID iD: 0000-0003-4809-8660
Doctor of Sciences (Engineering), Professor, Pro-rector for Research and Innovative Activities
Russian Federation, 654007, Russia, Novokuznetsk, Kirov Street, 42References
- Ri E.Kh., Ri Kh., Deev V.B., Kolisova M.V. Effect of scandium on the structure, segregation and properties of the aluminium cast alloy АМ4.5CD. Tsvetnye metally, 2019, no. 7, pp. 78–85. doi: 10.17580/tsm.2019.07.10.
- Zakharov V.V., Fisenko I.A., Kunyavskaya T.M. Prospects of alloying of aluminium alloys with scandium. Tekhnologiya legkikh splavov, 2020, no. 1, pp. 28–34. EDN: PDWRPX.
- Lei Zhiguo, Wen Shengping, Huang Hui, Wei Wu, Nie Zuoren. Grain Refinement of Aluminum and Aluminum Alloys by Sc and Zr. Metals, 2023, vol. 13, no. 4, article number 751. doi: 10.3390/met13040751.
- Li Qinglin, Zhang Yushi, Lan Yefeng, Pei Ruijie, Feng Xiangyu, Xia Tiandong, Liu Dexue. Effect of scandium addition on microstructure and mechanical properties of as-cast Al–5%Cu alloys. Vacuum, 2020, vol. 177, article number 109385. doi: 10.1016/j.vacuum.2020.109385.
- Yu Kun, Li Wenxian, Li Songrui, Zhao Jun. Mechanical properties, and microstructure of aluminum alloy 2618 with Al3(Sc, Zr) phases. Materials Science and Engineering: A, 2004, vol. 368, no. 1-2, pp. 88–93. doi: 10.1016/j.msea.2003.09.092.
- Rokhlin L.L., Bochvar N.R., Tarytina I.E. Joint effect of scandium and zirconium on the recrystallization of aluminum Al–Mg2Si alloys. Russian metallurgy (Metally), 2015, vol. 2015, no. 5, pp. 381–388. doi: 10.1134/S0036029515050134.
- Davydov V.G., Elagin V.I., Zakharov V.V., Rostova T.D. About scandium and zirconium additions in aluminium alloys. Metal Science and Heat Treatment, 1996, vol. 38, no. 7-8, pp. 347–352. doi: 10.1007/bf01395323.
- Zakharov V.V. The effect of scandium on the structure and properties of aluminum alloys. Metal Science and Heat Treatment, 2003, vol. 45, no. 7-8, pp. 246–253. doi: 10.1023/A:1027368032062.
- Zakharov V.V. Kinetics of decomposition of the solid solution of scandium in aluminum in binary Al–Sc alloys. Metal Science and Heat Treatment, 2015, vol. 57, no. 7-8, pp. 410–414. doi: 10.1007/s11041-015-9897-z.
- Forbord B., Lefebvre W., Danoix F., Hallem H., Marthinsen K. Three-dimensional atom probe investigation on the formation of Al3(Sc, Zr)-dispersoids in aluminium alloys. Scripta materialia, 2004, vol. 51, no. 4, pp. 333–337. doi: 10.1016/j.scriptamat.2004.03.033.
- Zakharov V.V. Stability of the solid solution of scandium in aluminum. Metal Science and Heat Treatment, 1997, vol. 39, no. 1-2, pp. 61–66. doi: 10.1007/bf02467664.
- Röyset J., Ryum N. Scandium in aluminium alloys. International Materials Reviews, 2005, vol. 50, no. 1, pp. 19–44. doi: 10.1179/174328005X14311.
- Li Hong-ying, Li De-wang, Zhu Zhi-xiang, Chen Bao-an, Chen Xin, Yang Chang-long, Zhang Hong-yu, Kang Wei. Grain refinement mechanism of as-cast aluminum by hafnium. Transactions of Nonferrous Metals Society of China, 2016, vol. 26, no. 12, pp. 3059–3069. doi: 10.1016/S1003-6326(16)64438-2.
- Jia Zhi-Hong, Huang Hui-Lan, Wang Xue-Li, Xing Yuan, Liu Qing. Hafnium in aluminum alloys: a review. Acta Metallurgica Sinica, 2016, vol. 29, pp. 105–119. doi: 10.1007/s40195-016-0379-0.
- Drits A.M., Aryshenskiy E.V., Kudryavtsev E.A., Zorin I.A., Konovalov S.V. The study of supersaturated solid solution decomposition in magnesium-rich aluminum alloys with scandium and hafnium additions. Frontier Materials & Technologies, 2022, no. 4, pp. 38–48. doi: 10.18323/2782-4039-2022-4-38-48.
- Zorin I.A., Aryshenskiy E.V., Drits A.M., Konovalov S.V., Komarov V.S. Effect of hafnium on cast microstructure in alloy 1570. Izvestiya vysshikh uchebnykh zavedeniy. Tsvetnaya metallurgiya, 2023, vol. 29, no. 1, pp. 56–65. doi: 10.17073/0021-3438-2023-1-56-65.
- Yashin V.V., Rushchits S.V., Aryshenskiy E.V., Latushkin I.A. Rheological behavior of 01570 and AA5182 wrought aluminum alloys under hot deformation conditions. Tsvetnye metally, 2019, no. 3, pp. 64–69. doi: 10.17580/tsm.2019.03.09.
- Zorin I.A., Drits A.M., Aryshenskiy E.V., Konovalov S.V., Grechnikov F.V., Komarov V.S. Effect of transition metals on as-cast aluminum alloys microstructure composition. Fundamentalnye problemy sovremennogo materialovedeniya, 2022, vol. 19, no. 4, pp. 520–531. doi: 10.25712/ASTU.1811-1416.2022.04.011.
- Zakharov V.V. About joint alloying of aluminum alloys with scandium and zirconium. Metal Science and Heat Treatment, 2014, vol. 56, no. 5-6, pp. 281–286. doi: 10.1007/s11041-014-9746-5.