THE INFLUENCE OF THE ADDITION OF SiO2 NANO-DIMENSIONAL PARTICLES TO THE ELECTROLYTE ON THE COMPOSITION AND PROPERTIES OF THE OXIDE LAYERS FORMED BY THE PLASMA-ELECTROLYTIC OXIDATION ON MAGNESIUM


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Abstract

Magnesium and its alloys, due to the combination of lightness and strength characteristics, are of interest in all production industries particular about the weight of products - shipbuilding, aviation, rocketry. However, the surface properties of magnesium alloys fail to meet many requirements, and at the moment, there is no the effective method for their improvement. The electrochemical method of plasma electrolytic oxidation (PEO) is promising in this case but the technology of obtaining the oxide layers using this method needs to be improved. One of the ways of modifying the PEO layers is the addition of nanoparticles to the electrolyte. The paper describes the synthesizing of the oxide layers on the pure magnesium by the PEO method using the electrolyte without nanoparticles and with the addition of SiO2 nanoparticles to the electrolyte. The authors studied the obtained oxide layers using the methods of scanning electron microscopy, X-ray spectral microanalysis, X-ray phase analysis, instrumental indentation, and the electrochemical tests. The structure, element and phase composition, adhesion strength to the substrate and the corrosion resistance of the oxide layers on magnesium were studied.
The study demonstrated the positive effect of the SiO2 nanoparticles additions to the electrolyte on the functional properties of the oxide layer - the adhesion strength to the substrate and corrosion resistance. The mechanism of the positive effect of nanoparticles on these characteristics was suggested. The study detected the phase of magnesium silicate Mg2SiO4, as well as magnesium phosphate Mg3(PO4)2 in the oxide layer which indicates the participation of both the electrolyte components - phosphorus, and the added nanosized particles of silicon dioxide in the formation of the layer.

About the authors

E. D. Borgardt

Togliatti State University

Author for correspondence.
Email: euletech13@gmail.com

Borgardt Evgeny Dmitrievich - junior researcher of the Research Division No. 4 of the Research Institute of Advanced Technologies.
445020, Togliatti, Belorusskaya Street, 14.

Russian Federation

A. V. Polunin

Togliatti State University

Email: Anpol86@gmail.com

Polunin Anton Viktorovich - PhD (Engineering), senior researcher of the Research Division No. 4 of the Research Institute of Advanced Technologies.
445020, Togliatti, Belorusskaya Street, 14.

Russian Federation

P. V. Ivashin

Togliatti State University

Email: ivashinpv@gmail.com

Ivashin Pavel Valentinovich - PhD (Engineering), leading researcher of the Research Division No. 4 of the Research Institute of Advanced Technologies.
445020, Togliatti, Belorusskaya Street, 14.

Russian Federation

M. M. Krishtal

Togliatti State University

Email: krishtal@tltsu.ru

Krishtal Mikhail Mikhailovich - Doctor of Sciences (Physics and Mathematics), Professor, Rector.
445020, Togliatti, Belorusskaya Street, 14.

Russian Federation

References

  1. Hussein R.O., Zhang P., Nie X., Xia Y., Northwood D.O. The effect of current mode and discharge type on the corrosion resistance of plasma electrolytic oxidation (PEO) coated magnesium alloy AJ62. Surface and Coatings Technology, 2011, vol. 206, no. 7, pp. 1990-1997.
  2. Nikolas A., Rolnik S. Application of magnesium components in the aerospace industry. Aerokosmicheskiy kuryer, 2011, no. 1, pp. 42-44.
  3. Czerwinski F., ed. Magnesium Alloys. Corrosion and Surface Treatments. InTech, 2011. 353 p. ISBN 978953-307-972-1.
  4. Hanshan D. Surface engineering of light alloys. Aluminium, magnesium and titanium alloys. Woodhead Publishing Limited, 2010. 680 p. ISBN 978-1-84569-537-8.
  5. Apelfeld A., Krit B., Ludin V., Morozova N., Vladimirov B., Wud R.Z. The characterization of plasma electrolytic oxidation coatings on AZ41 magnesium alloy. Surface and Coatings Technology, 2017, vol. 322, pp. 127-133.
  6. Suminov I.V., Belkin P.N., Epelfeld A.V., Lyudin V., Krit B., Borisov A. Plazmenno-elektroliticheskoe modifitsirovanie poverkhnosti metallov i splavov [Plasma-electrolytic modification of the surface of metals and alloys]. Moscow, Tekhnosfera Publ., 2011. Vol. 2, 512 p.
  7. Krishtal M.M., Ivashin P.V., Yasnikov I.S., Polunin A.V. Effect of nanosize SiO2 particles added into electrolyte on the composition and morphology of oxide layers formed in alloy AD6M2 under microarc oxidizing. Metal Science and Heat Treatment, 2015, vol. 57, no. 7-8, p. 428-435.
  8. Krishtal M.M., Ivashin P.V., Rastegaev I.A., Polunin A.V., Borgardt E.D. The influence of nano-sized silicon dioxide addition in electrolyte on characteristics of oxide layers formed with microarc oxidation on Al-Si alloy 361.0. Vektor nauki Tolyattinskogo gosudarstven-nogo universiteta, 2014, no. 1, pp. 48-52.
  9. Krishtal M.M., Ivashin P.V., Polunin A.V., Borgardt E.D., Tverdokhlebov A.Ya. Improvement of the efficiency of technology of aluminum-silicon alloys micro-arc oxidation. Vektor nauki Tolyattinskogo gosu-darstvennogo universiteta, 2015, no. 2-2, pp. 86-93.
  10. Polunin A.V., Ivashin P.V., Rastegaev I.A., Borgardt E.D., Krishtal M.M. Wear resistance of the oxide layers formed on AK9Pch silumin by microarc oxidation in an electrolyte modified by silicon dioxide nanoparticles. Russian Metallurgy (Metally), 2016, vol. 2016, no. 4, pp. 385-388.
  11. Guo J., Wang L., Wang S.C., Liang J., Xue Q., Yan F. Preparation and performance of a novel multifunctional plasma electrolytic oxidation composite coating formed on magnesium alloy. Journal of Materials Science, 2009, vol. 44, no. 8, pp. 1998-2006.
  12. Blawert C., Sah S.P., Liang J., Huang Y., Hoche D. Role of sintering and clay particle additions on coating formation during PEO processing of AM50 magnesium alloy. Surface and Coatings Technology, 2012, vol. 213, pp. 48-58.
  13. Lu X., Blawert C., Huang Y., Ovri H., Zheludke-vich M.L., Kainer K.U. Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO2 particles. Electrochimica Acta, 2016, vol. 187, pp. 20-33.
  14. Gnedenkov S.V., Sinebryukhov S.L., Mashtalyar D.V., Imshinetskiy I.M., Samokhin A.V., Tsvetkov Y.V. Fabrication of Coatings on the Surface of Magnesium Alloy by Plasma Electrolytic Oxidation Using ZrO2 and SiO2 Nanoparticles. Journal of Nanomaterials, 2015, vol. 2015, p. 154298. doi: 10.1155/2015/154298.
  15. Abzaev Yu.A., Kopanina N.O., Klimenov V.A., Sarkisov Yu.S., Gorlenko N.P., Demyanenko O.V., Zavyalov A.P. Structural state modeling of amorphous tarkosil. Vestnik Tomskogo gosudarstvennogo arkhitekturno-stroitelnogo universiteta, 2015, no. 3, pp. 121-133.
  16. Jenkins R., Snyder R.L. Introduction to X-ray Powder Diffractometry. NY Wiley, 2012. 432 p. ISBN 9781118520918.
  17. Bard A.J., Faulkner L.R. Electrochemical Methods. Fundamentals and Applications. 2nd ed. John Wiley & Sons, 2001. 856 p. ISBN 0-471-04372-9.
  18. Lu X., Blawert C., Kainer K.U., Zheludkevich M.L. Investigation of the formation mechanisms of plasma electrolytic oxidation coatings on Mg alloy AM50 using particles. Electrochimica Acta, 2016, vol. 196, pp. 680-691.
  19. Lu X., Blawert C., Zheludkevich M.L., Kainer K.U. Insights into plasma electrolytic oxidation treatment with particle addition. Corrosion Science, 2015, vol. 101, pp. 201-207.
  20. Lu X., Mohedano M., Blawert C., Matykina E., Arrabal R., Kainer K.U., Zheludkevich M.L. Plasma electrolytic oxidation coatings with particle additions - A Review. Surface and Coatings Technology, 2016, vol. 307, pp. 1165-1182.
  21. Dong E.T., Shen P., Shi L.X., Zhang D., Jiang Q.C. Wetting and adhesion at Mg/MgO interfaces. Journal of Material Science, 2013, vol. 48, no. 17, pp. 60086017.

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