No 3 (2026)

Investigation of the relationship between changes in the stress-strain state and structural damage of metals and changes in the parameters of electromagnetic-acoustic signal

Akchurin D.S., Bashirov M.G., Bashirova E.M., Yusupova I.G.

Abstract

Problem. Ensuring the technosphere safety of industrial facilities in the oil and gas sector is complicated by
processes of hidden microstructural degradation of metal, which initiates more than 31 % of emergency situations. Traditional
nondestructive testing methods are significantly limited by the need for thorough surface preparation and ensuring stable liquid acoustic contact, which hinders the operational monitoring of pipelines and pressure vessels through insulation layers.
Aim. The aim of this study is to establish quantitative relationships between the spectral parameters of the electromagneticacoustic (EMA) signal and the stages of stress-strain state and damage of structural steels. Methods. A series of experiments
was performed on St3sp, 09G2S, and 12Kh18N10T steels under static tension on a servohydraulic system. Signal registration
was carried out using an EMA thickness gauge. The analysis is based on dynamic approach: the control zone was identified as
a linear system, the mathematical reference of which is a second-order transfer function W(p) reconstructed by the method of
moments. To automate state recognition, a transition to frequency models in the form of hodographs of amplitude-phasefrequency characteristics (APFC) was implemented. An artificial neural network based on the ML.NET library was trained
on 3 samples of 720 measurements, using the amplitudes and phases of the first 15 signal harmonics as input features.
Results. It was experimentally proved that the accumulation of structural damage causes a regular migration of the roots of
the characteristic polynomial on the complex plane and a qualitative transformation of the shape of the APFC hodographs.
The developed intelligent classifier provided an identification accuracy of the stress-strain state (SSS) stages at the level of
92.16 %, while the error in determining the numerical stress values did not exceed 3.5 %. Conclusions. The spectral parameters of the EMA signal in combination with machine learning technologies make it possible to identify reliably pre-defect
states of metal. The proposed method minimises the influence of the human factor and ensures the detection of zones of critical stress concentration before the initiation of macroscopic cracks.

Frontier Materials & Technologies. 2026;(3):9-18
pages 9-18 views

Morphology, phase composition and tribological properties of W–Co coatings formed by electrospark alloying of St3 steel

Konchin V.A., Vornacheva I.V., Fetisov V.S., Loktionov A.I., Merkulov A.A.

Abstract

Problem. For W–Co coatings on low-carbon structural steel, the influence of the combined variation of
the discrete MODE and VIBRATION parameters during electrospark alloying on layer formation and the coordinated
change in its structural and tribological characteristics has not been established. This complicates the selection of a mode
that simultaneously provides coating density, strong adhesion to the substrate, and wear resistance. Aim. To identify
the influence of electrospark alloying modes with W–Co electrodes on the structure and tribological properties of coatings
on St3 steel. Methods. Coatings were deposited onto St3 steel specimens measuring 50×50×3 mm using electrodes composed of 85 % W and 15 % Co, produced by spark plasma sintering. On a UR-121 setup, five MODE and VIBRATION
combinations were investigated with five passes and a processing time of 180 s. The structure and properties were evaluated using SEM, X-ray phase analysis, 3D profilometry, measurements of microhardness, porosity, and adhesion;
tribological tests were carried out according to the ball-on-flat scheme. Results. Among the five studied modes, the optimal combination was MODE=2, VIBRATION=5, which formed the densest layer about 75 μm thick with a microhardness
of 1520±45 HV, porosity not exceeding 1.5 %, and adhesion of 75 MPa. The α-Fe, W, Co, Fe–W, WO3, and WC phases
were identified. At a load of 1 N, the mass wear intensity was 0.04–0.08 mg/(N·m), which is 2.5–4 times lower than that of
uncoated St3 steel (0.15–0.20 mg/(N·m). Conclusions. The MODE=2, VIBRATION=5 mode provides the best combination of microhardness, low porosity, adhesion, and wear resistance among those studied and can be used as a basis for local
restoration of worn surfaces of agricultural machinery parts.

Frontier Materials & Technologies. 2026;(3):19-28
pages 19-28 views

A method for investigating the dynamics of cavitation erosion of test specimens made of aluminum foil

Kurliuk E.A., Minchuk V.S., Dzezhkunou T.A., Lebed A.A., Dezhkunov N.V.

Abstract

Problem. The relevance of this work is caused by the absence of a generally accepted method for the quantitative assessment of cavitation activity, as well as the limitations of traditional erosion tests associated with long experiment durations, low reproducibility, and distortion of the cavitation field structure by massive test specimens. Aim. To
develop a highly sensitive and reproducible erosion test method that allows assessing the spatial distribution of erosion
activity in an ultrasonic field. Methods. To study the dynamics of cavitation erosion, it is proposed to use video recording
of the destruction process of aluminum foil followed by automated image processing. The developed software implements
computer vision algorithms using the OpenCV library and neural network segmentation based on a modified Segment
Anything Model (SAM) with a U-Net type output layer and a ResNet34 encoder. This allows delineating automatically
the erosion damage zone and calculating quantitative damage characteristics. The method was tested in the ultrasonic field
of a 22 kHz immersion transducer, varying the ultrasound intensity, distance to the transducer, and gas content of the liquid. Results. High reproducibility of the method was established. It is shown that the use of 15 μm thick foil (GOST 745-
2014) provides high sensitivity to non-stationary cavitation processes. It was found that the active cavitation zone in
the field of an immersion transducer is localised near the radiating surface (up to 5 mm), with the erosion rate rapidly
decreasing with increasing distance from the transducer. Conclusions. The developed method for recording and analysing
the dynamics of cavitation destruction of test specimens allows reducing the experiment duration by at least an order of
magnitude compared to the ASTM G32-16 method. The method also makes it possible to obtain the distribution of cavitation erosion activity in the investigated volume in a single pass, i.e., using a single specimen. The possibility of correlating
erosion damage characteristics with the parameters of the cavitation noise spectrum is demonstrated.

Frontier Materials & Technologies. 2026;(3):29-43
pages 29-43 views

Structure of hydroxyapatite coatings produced by electrodeposition on stainless steel and titanium nickelide substrates

Rubanik V.V., Bahrets D.A., Mozzharov S.E., Ngo T.T.

Abstract

Problem. Hydroxyapatite (HA, chemical formula Ca10(PO4)6(OH)2) is widely used as a biocompatible and
bioactive ceramic due to its structural and chemical similarity to the main mineral component of human hard tissues.
A disadvantage of hydroxyapatite is its low mechanical properties (strength, crack resistance, and impact resistance),
which undoubtedly limits its use as a structural material but not as a bioactive coating on metal implant surfaces.
Electrodeposition is one of the most promising methods for forming bioactive calcium-phosphate coatings on metal
implants due to the ability to control the composition, structure, and thickness of the coating at low process temperatures.
Aim. The aim of this work is to identify patterns in the formation of the composition and structure of hydroxyapatite coatings produced by electrodeposition on 12X18H10T stainless steel and titanium nickelide substrates, and to optimize
the deposition modes. Methods. The influence of electrolyte parameters (Ca2+ and PO4
3
ion concentration, pH, H2O2
and NaOH additives), temperature (23–85 °C), potential and deposition time on the stoichiometry, crystallinity, texture
and crystallite size of HA coatings was studied using X-ray fluorescence (XRF), X-ray diffraction (XRD), and
IR-spectroscopy. Results. It was shown that the brushite phase (CaHPO4·2H2O) is formed at room temperature regardless
of the electrolyte composition. Increasing the temperature to 65 °C or higher, when combined with optimization of pH
(4.1–6.0) and potential (−1.7…−3.4 V), allows the synthesis of coatings with a composition close to stoichiometric
hydroxyapatite. The regimes ensuring the production of single-phase, highly-crystalline HA coatings with a texture coefficient of up to 2.6, which corresponds to the structure most conducive to osseointegration, were experimentally determined.
Conclusions. The best coating characteristics (high crystallinity CI=9.1, crystallite size along the c-axis ~70 nm, c/a
ratio=0.730) were achieved for the sample synthesized at T=75 °C, pH=5.0, and U=−1.7 V.

Frontier Materials & Technologies. 2026;(3):45-55
pages 45-55 views

Features of structure formation during liquid carburizing of AISI 321 and AISI 310S chromium-nickel austenitic steels

Savrai R.A., Skorynina P.A., Kolobylin Y.M.

Abstract

Problem. Chromium-nickel austenitic steels of the AISI 300 series are important structural materials for industrial applications over a wide range of operating temperatures. The most effective way to increase the strength, wear
resistance, and durability of products made from such steels is the creation of diffusion or cladding layers, which both
harden the steel and perform a protective function. Aim. To identify the influence of the chemical composition of AISI
310S and AISI 321 chromium-nickel austenitic steels on the features of structure formation during liquid carburizing.
Methods. The studies were carried out using optical and scanning electron microscopy, X-ray diffraction, and durometric
analysis. Results. It was found that after liquid carburizing at a temperature of 780 °C, the total content of carbide phase in
AISI 310S steel is almost four times higher than in AISI 321 steel, amounting to 39.3 and 9.3 wt.%, respectively. Differences in the type of chromium carbides precipitated during carburizing of the investigated steels were revealed (Cr23C6 in
AISI 321 steel and Cr7C3 in AISI 310S steel). It was identified that in both investigated steels, cementite Fe3C is also
formed; however, discrepancies in the position of the characteristic peaks of cementite are observed. It was shown that
the intensity of carbide formation processes during liquid carburizing of austenitic steels directly affects the depth of
the hardened layer, which amounted to about 500 μm for AISI 321 steel and about 200 μm for AISI 310S steel. It was established that carburized AISI 321 steel has a significantly higher surface hardness (890 HV0.025) compared to the surface
hardness of carburized AISI 310S steel (590 HV0.025), which is due to the presence of α-martensite in the structure of
AISI 321 steel. Conclusions. The chemical composition of austenitic AISI 310S and AISI 321 steels has a significant impact on the processes of structure formation during liquid carburizing, which is caused by different diffusion conditions.

Frontier Materials & Technologies. 2026;(3):57-66
pages 57-66 views

Influence of the composition of coatings based on titanium and zirconium nitrides on the mechanical properties and performance of cutting tools

Tabakov V.P., Morozov O.I., Shavrygin A.S., Kamenov R.U.

Abstract

Problem. The influence of chromium and aluminum as alloying elements on the substructural parameters, stress state, and cyclic crack resistance of TiZrN nitride coatings has not been systematically investigated,
which hinders the informed selection of coating composition in the development of machining processes.
Aim. To establish the patterns of the influence of chromium and aluminum alloying on the structure, mechanical
properties, stress state, and cyclic crack resistance of TiZr-nitride coatings, as well as to evaluate their effect on
the tool life of MK8 and R6M5K5 inserts during turning of 30KhGSA steel. Methods. TiZrN, TiZrCrN (11.28 at.%
Cr), and TiZrAlN (9.25 at.% Al) PVD coatings were investigated. Structural parameters were determined by X-ray
diffraction analysis (DRON-3M); microhardness Hµ, elastic modulus E, and fracture toughness KIC were determined
by Knoop indentation. The stress state and cyclic crack resistance were calculated during turning of 30KhGSA steel
with MK8 inserts (V=180 m/min, t=0.5 mm) and R6M5K5 inserts (V=55 m/min, t=0.75 mm). Results. Al alloying
has a stronger effect on the substructural parameters: for TiZrAlN, β111=0.67°, D=14 nm versus β111=0.55°, D=18 nm
for TiZrN. Both elements increase microhardness (43.2 and 42.2 GPa) and compressive residual stresses
(up to −1422 MPa). TiZrAlN provided a tool life of MK8 inserts of 57 min at V=180 m/min – 2.0 times higher than
TiZrN and 1.3 times higher than TiZrCrN. Conclusions. The TiZrAlN coating (9.25 at.% Al) provides the best combination of substructural parameters, mechanical properties, and crack resistance among th e investigated Ti–Zr–N
coatings and is recommended for application to MK8 inserts in the turning of structural steels such as 30KhGSA.

Frontier Materials & Technologies. 2026;(3):67-77
pages 67-77 views

Electronic properties and strain-induced optical response of monolayer CrS2

Quang T.T., Bang L.N.

Abstract

Problem. Two-dimensional transition metal dichalcogenides (TMDs) are promising candidates for
applications in next-generation optoelectronic and plasmonic devices due to their outstanding electronic and optical
properties. However, monolayer CrS2 remains understudied, and its strain-dependent optical response has not been
systematically investigated. Aim. To conduct a comprehensive first‑principles investigation of the effects of biaxial strain
on the optoelectronic properties of monolayer CrS2, in order to elucidate the microscopic mechanisms governing
strain‑induced optical responses and to provide a theoretical basis for the design of tunable optoelectronic and plasmonic
devices based on 2D materials. Methods. The study used density function theory (DFT) to analyze the electronic band
structure, dielectric function, and optical constant under different strain levels. Results. The results show that CrS2
possesses a direct bandgap of ~0.96 eV at the K-point, and the complex dielectric function ε(ω) exhibits distinct anisotropy
between in-plane and out-of-plane orientations. Furthermore, optical constants, including refractive index (n), extinction
coefficient (k), absorption coefficient (α), reflectivity (R), and energy loss function (L), are comprehensively analyzed.
Under biaxial strain ranging from −6 % to +6 %, a pronounced variation in the absorption and attenuation coefficients was
observed, with intensity increasing under tensile strain and decreasing under compressive strain, while reflectivity
remained low in the infrared–visible region, confirming optical behavior dominated by absorption. The energy loss
function revealed that plasmon resonances can be tuned by strain in the ultraviolet region. Conclusions. These findings
demonstrate that biaxial strain is an effective strategy for tuning the optical response of monolayer CrS2, highlighting its
potential in tunable optoelectronic and plasmonic applications.

Frontier Materials & Technologies. 2026;(3):79-91
pages 79-91 views

Evaluation of adhesive strength of polymer coatings for oilfield pipes after exposure to a CO2 environment

Yudin P.E., Amosov A.P., Lozhkomoev A.S., Maidan D.A.

Abstract

Problem. The effect of polymer coatings on the protection of steels against CO2 corrosion has been little
studied, and existing standards for evaluating their adhesive strength contain contradictions in the interpretation of test
results. Aim. To develop a model of changes in the adhesive strength of coatings for oilfield and tubing pipes in a CO2-
containing environment for predicting their service life. Methods. Three types of polymer coatings used for the protection
of oilfield and tubing pipes (tubing) were studied: a liquid non-thermosetting coating (coating 1) and two two-layer powder coatings (coatings 2 and 3). The tests were carried out using an autoclave complex. The conditions in the autoclave
were the following: total system pressure 10±0.5 MPa; temperature 90±3 °С; electrolyte – sodium chloride solution in
distilled water with a mass fraction of 3 %; exposure duration – 50 days. Adhesive strength was determined by the dolly
pull-off method. For microscopic analysis, cross-sections of the coatings at locations of blisters were prepared, then metallographic sections were prepared. Results. After 50 days of exposure in a CO2 environment, the adhesive strength of
the coatings decreased: for coating 1 – from 7.8 to 2.9 MPa, for coating 2 – from 27.1 to 10.2 MPa, for coating 3 – from
16.1 to 11.3 MPa. Coating 1 showed low initial adhesive strength values that did not meet industry standards. For coating 2, adhesion decreased in the 0–10 and 20–30 day intervals and then stabilised. For coating 3, an initial increase in adhesion was observed, followed by a decrease. Conclusions. After 50 days of exposure in a CO2 environment, the adhesive
strength of coating 1 decreased by 37 % of its initial strength, of coating 2 – by 38 %, and of coating 3 – by 7 %, which
recommends it for operation under similar conditions.

Frontier Materials & Technologies. 2026;(3):93-103
pages 93-103 views