<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE root>
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" article-type="research-article" dtd-version="1.2" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">Frontier Materials &amp; Technologies</journal-id><journal-title-group><journal-title xml:lang="en">Frontier Materials &amp; Technologies</journal-title><trans-title-group xml:lang="ru"><trans-title>Frontier Materials &amp; Technologies</trans-title></trans-title-group></journal-title-group><issn publication-format="print">2782-4039</issn><issn publication-format="electronic">2782-6074</issn><publisher><publisher-name xml:lang="en">Togliatti State University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="publisher-id">966</article-id><article-id pub-id-type="doi">10.18323/2782-4039-2024-3-69-3</article-id><article-categories><subj-group subj-group-type="toc-heading" xml:lang="en"><subject>Articles</subject></subj-group><subj-group subj-group-type="toc-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="article-type"><subject>Research Article</subject></subj-group></article-categories><title-group><article-title xml:lang="en">The influence of phosphorus microalloying on the structure formation of CuZn32Mn3Al2FeNi multicomponent brass</article-title><trans-title-group xml:lang="ru"><trans-title>Влияние микролегирования фосфором на структурообразование многокомпонентной латуни ЛМцАЖН</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-8600-7566</contrib-id><name-alternatives><name xml:lang="en"><surname>Gnusina</surname><given-names>Anastasiya M.</given-names></name><name xml:lang="ru"><surname>Гнусина</surname><given-names>Анастасия Михайловна</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>postgraduate student of Chair “Nanotechnologies, Materials Science and Mechanics”</p></bio><bio xml:lang="ru"><p>аспирант кафедры «Нанотехнологии, материаловедение и механика»</p></bio><email>myripru@gmail.com</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-8121-9084</contrib-id><name-alternatives><name xml:lang="en"><surname>Svyatkin</surname><given-names>Aleksey V.</given-names></name><name xml:lang="ru"><surname>Святкин</surname><given-names>Алексей Владимирович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), assistant professor of Chair “Nanotechnologies, Materials Science and Mechanics”</p></bio><bio xml:lang="ru"><p>кандидат технических наук, доцент кафедры «Нанотехнологии, материаловедение и механика»</p></bio><email>astgl@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib></contrib-group><aff-alternatives id="aff1"><aff><institution xml:lang="en">Togliatti State University</institution></aff><aff><institution xml:lang="ru">Тольяттинский государственный университет</institution></aff></aff-alternatives><pub-date date-type="pub" iso-8601-date="2024-09-30" publication-format="electronic"><day>30</day><month>09</month><year>2024</year></pub-date><issue>3</issue><issue-title xml:lang="en"/><issue-title xml:lang="ru"/><fpage>31</fpage><lpage>40</lpage><history><date date-type="received" iso-8601-date="2024-10-16"><day>16</day><month>10</month><year>2024</year></date><date date-type="accepted" iso-8601-date="2024-10-16"><day>16</day><month>10</month><year>2024</year></date></history><permissions><copyright-statement xml:lang="en">Copyright ©; 2024, Gnusina A.M., Svyatkin A.V.</copyright-statement><copyright-statement xml:lang="ru">Copyright ©; 2024, Гнусина А.М., Святкин А.В.</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="en">Gnusina A.M., Svyatkin A.V.</copyright-holder><copyright-holder xml:lang="ru">Гнусина А.М., Святкин А.В.</copyright-holder><ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/><license><ali:license_ref xmlns:ali="http://www.niso.org/schemas/ali/1.0/">https://creativecommons.org/licenses/by/4.0</ali:license_ref></license></permissions><self-uri xlink:href="https://vektornaukitech.ru/jour/article/view/966">https://vektornaukitech.ru/jour/article/view/966</self-uri><abstract xml:lang="en"><p>Phosphorus in brass can have both a positive effect, such as improving mechanical properties, increasing corrosion resistance and machinability, and a negative effect, such as adversely affecting weldability and causing cracking. The study of the role of phosphorus in the processes of brass structure formation is of practical relevance, since it helps optimise the properties of the material, reduce the risk of defects, improve treatment processes and control properties and quality. The work covers the study of the role of phosphorus in brass, the need to control its content during production by limiting the share of secondary use. The study revealed the possibility of a positive effect of modifying copper alloys with phosphorus in order to improve performance properties, as well as the prospects of using phosphorus as a safe replacement for lead in brass. The authors assessed the content and distribution of phosphorus impurity at a concentration of 0.005 % in a brass sample of the CuZn32Mn3Al2FeNi grade, studied the nature of its interaction with other components of the alloy and the changes occurring at different temperatures of heat treatment. It has been found that phosphorus actively participates in diffusion processes and forms phosphides in both defective and defect-free blanks. When heated to the hot deformation temperature range, phosphorus redistribution occurs, phosphide locally dissolves, and metastable inclusions form. Due to differences in the concentration of elements in areas adjacent to the phosphide, the brass structure changes leading to the formation of areas different from the matrix β-phase. Manganese phosphide in brass can improve its mechanical properties and cutting ability, but an excess of this compound can lead to problems with strength, crack resistance, and moulding.</p></abstract><trans-abstract xml:lang="ru"><p>Фосфор в латуни может оказывать как положительное влияние – улучшать механические свойства, повышать коррозионную стойкость и обрабатываемость, так и отрицательное – негативно сказываться на свариваемости и приводить к растрескиванию. Исследование роли фосфора в процессах структурообразования латуни имеет практическую актуальность, поскольку способствует оптимизации свойств материала, снижению возможности появления дефектов, улучшению процессов обработки и контролю свойств и качества. Работа посвящена исследованию роли фосфора в латуни, необходимости контроля его содержания при производстве путем ограничения доли вторичного использования. Выявлена возможность положительного влияния модификации медных сплавов фосфором с целью улучшения эксплуатационных свойств, а также перспектива использования фосфора в качестве безопасной замены свинца в латуни. Проведена оценка содержания и распределения примеси фосфора в концентрации 0,005 % в латунном образце марки ЛМцАЖН 59-3,5-2,3-0,5-0,3, изучены характер его взаимодействия с другими компонентами сплава и изменения, происходящие при различных температурах термической обработки. Установлено, что фосфор активно участвует в диффузионных процессах и образует фосфиды как в дефектных, так и в бездефектных заготовках. При нагреве в области температур горячей деформации происходит перераспределение фосфора, локальное растворение фосфида и образование метастабильных включений. Из-за различий в концентрации элементов в областях, прилегающих к фосфиду, происходит изменение структуры латуни, что приводит к образованию участков, отличных от матричной β-фазы. Фосфид марганца в латуни может улучшить ее механические свойства и обрабатываемость резанием, но избыток этого соединения может привести к проблемам с прочностью, трещиностойкостью и формованием. </p></trans-abstract><kwd-group xml:lang="en"><kwd>duplex and multicomponent brasses</kwd><kwd>phosphorus distribution analysis</kwd><kwd>silicides</kwd><kwd>phosphorus</kwd><kwd>compounds with phosphorus</kwd><kwd>shape and size of inclusions</kwd><kwd>effect of heating on microstructure</kwd><kwd>phosphorus redistribution</kwd><kwd>manganese phosphide</kwd><kwd>diffusion processes</kwd><kwd>metastable inclusions</kwd></kwd-group><kwd-group xml:lang="ru"><kwd>двойные и многокомпонентные латуни</kwd><kwd>анализ распределения фосфора</kwd><kwd>силициды</kwd><kwd>фосфор</kwd><kwd>соединения с фосфором</kwd><kwd>форма и размеры включений</kwd><kwd>влияние нагрева на микроструктуру</kwd><kwd>перераспределение фосфора</kwd><kwd>марганцевый фосфид</kwd><kwd>диффузионные процессы</kwd><kwd>метастабильные включения</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The paper was written on the reports of the participants of the XI International School of Physical Materials Science (SPM-2023), Togliatti, September 11–15, 2023.</funding-statement><funding-statement xml:lang="ru">Статья подготовлена по материалам докладов участников XI Международной школы «Физическое материаловедение» (ШФМ-2023), Тольятти, 11–15 сентября 2023 года.</funding-statement></funding-group></article-meta></front><body></body><back><ref-list><ref id="B1"><label>1.</label><citation-alternatives><mixed-citation xml:lang="en">Stavroulakis P., Toulfatzis A.I., Pantazopoulos G.A., Paipetis A.S. Machinable Leaded and Eco-Friendly Brass Alloys for High Performance Manufacturing Processes: A Critical Review. Metals, 2022, vol. 12, no. 2, article number 246. DOI: 10.3390/met12020246.</mixed-citation><mixed-citation xml:lang="ru">Stavroulakis P., Toulfatzis A.I., Pantazopoulos G.A., Paipetis A.S. Machinable Leaded and Eco-Friendly Brass Alloys for High Performance Manufacturing Processes: A Critical Review // Metals. 2022. Vol. 12. № 2. Article number 246. DOI: 10.3390/met12020246.</mixed-citation></citation-alternatives></ref><ref id="B2"><label>2.</label><citation-alternatives><mixed-citation xml:lang="en">Wang Jiong, Xua Honghui, Shang Shunli, Zhang Lijun, Du Yong, Zhang Wenqing, Liu Shuhong, Wang Peisheng, Liu Zi-Kui. Experimental investigation and thermodynamic modeling of the Cu–Si–Zn system with the refined description for the Cu–Zn system. Calphad, 2011, vol. 35, no. 35, pp. 191–203. DOI: 10.1016/j.calphad.2011.02.001.</mixed-citation><mixed-citation xml:lang="ru">Wang Jiong, Xua Honghui, Shang Shunli, Zhang Lijun, Du Yong, Zhang Wenqing, Liu Shuhong, Wang Peisheng, Liu Zi-Kui. Experimental investigation and thermodynamic modeling of the Cu–Si–Zn system with the refined description for the Cu–Zn system // Calphad. 2011. Vol. 35. № 35. P. 191–203. DOI: 10.1016/j.calphad.2011.02.001.</mixed-citation></citation-alternatives></ref><ref id="B3"><label>3.</label><citation-alternatives><mixed-citation xml:lang="en">Bie Lifu, Chen Xiaohong, Liu Ping, Zhang Tao, Xu Xiangliu. Morphology Evolution of Mn5Si3 Phase and Effect of Mn content on Wear Resistance of Special Brass. Metals and Materials International, 2019, vol. 26, pp. 431–443. DOI: 10.1007/s12540-019-00243-0.</mixed-citation><mixed-citation xml:lang="ru">Bie Lifu, Chen Xiaohong, Liu Ping, Zhang Tao, Xu Xiangliu. Morphology Evolution of Mn5Si3 Phase and Effect of Mn content on Wear Resistance of Special Brass // Metals and Materials International. 2019. Vol. 26. P. 431–443. DOI: 10.1007/s12540-019-00243-0.</mixed-citation></citation-alternatives></ref><ref id="B4"><label>4.</label><citation-alternatives><mixed-citation xml:lang="en">Porter D.A., Easterling K.E., Sherif M.Y. Phase transformations in metals and alloys. London, Taylor &amp; Francis Group Publ., 2009. 538 p.</mixed-citation><mixed-citation xml:lang="ru">Porter D.A., Easterling K.E., Sherif M.Y. Phase transformations in metals and alloys. London: Taylor &amp; Francis Group, 2009. 538 p.</mixed-citation></citation-alternatives></ref><ref id="B5"><label>5.</label><citation-alternatives><mixed-citation xml:lang="en">Chen Nannan, Wang Hongliang, Veeresh P. et al. Achieving brittle-intermetallic-free and high-conductivity aluminum/copper joints using nickel-phosphorus coatings. Materials &amp; Design, 2021, vol. 199, article number 109435. DOI: 10.1016/j.matdes.2020.109435.</mixed-citation><mixed-citation xml:lang="ru">Chen Nannan, Wang Hongliang, Veeresh P. et al. Achieving brittle-intermetallic-free and high-conductivity aluminum/copper joints using nickel-phosphorus coatings // Materials &amp; Design. 2021. Vol. 199. Article number 109435. DOI: 10.1016/j.matdes.2020.109435.</mixed-citation></citation-alternatives></ref><ref id="B6"><label>6.</label><citation-alternatives><mixed-citation xml:lang="en">Gholami M.D., Hashemi R., Davoodi B. Investigation of microstructure evolution on the fracture toughness behaviour of Brass/Low Carbon Steel/Brass clad sheets fabricated by Cold Roll Bonding process. Journal of Materials Research and Technology, 2023, vol. 25, pp. 2570–2588. DOI: 10.1016/j.jmrt.2023.06.103.</mixed-citation><mixed-citation xml:lang="ru">Gholami M.D., Hashemi R., Davoodi B. Investigation of microstructure evolution on the fracture toughness behaviour of Brass/Low Carbon Steel/Brass clad sheets fabricated by Cold Roll Bonding process // Journal of Materials Research and Technology. 2023. Vol. 25. P. 2570–2588. DOI: 10.1016/j.jmrt.2023.06.103.</mixed-citation></citation-alternatives></ref><ref id="B7"><label>7.</label><citation-alternatives><mixed-citation xml:lang="en">Galai M., Benqlilou H., Ebntouhami M., Nassali H., Belhaj T., Berrami Kh., Mansouri I., Ouaki B. Effect of phosphorus content of α brass on its corrosion resistance in aggression soil: experimental and characterization studies. Euro-Mediterranean Journal for Environmental Integration, 2021, vol. 6, article number 41. DOI: 10.1007/s41207-021-00244-9.</mixed-citation><mixed-citation xml:lang="ru">Galai M., Benqlilou H., Ebntouhami M., Nassali H., Belhaj T., Berrami Kh., Mansouri I., Ouaki B. Effect of phosphorus content of α brass on its corrosion resistance in aggression soil: experimental and characterization studies // Euro-Mediterranean Journal for Environmental Integration. 2021. Vol. 6. Article number 41. DOI: 10.1007/s41207-021-00244-9.</mixed-citation></citation-alternatives></ref><ref id="B8"><label>8.</label><citation-alternatives><mixed-citation xml:lang="en">Alistratov V.N., Chigarev V.V., Ilenko V.V. Development of a powder tape composition intended for surfacing bronze operating under electrical erosion wear conditions. Vestnik Priazovskogo gosudarstvennogo tekhnicheskogo universiteta. Seriya: Tekhnicheskie nauki, 2003, no. 13, pp. 1–4.</mixed-citation><mixed-citation xml:lang="ru">Алистратов В.Н., Чигарев В.В., Ильенко В.В. Разработка состава порошковой ленты, предназначенной для наплавки бронзы, работающей в условиях электроэрозионного износа // Вестник Приазовского государственного технического университета. Серия: Технические науки. 2003. № 13. С. 1–4.</mixed-citation></citation-alternatives></ref><ref id="B9"><label>9.</label><citation-alternatives><mixed-citation xml:lang="en">Kozaderov O.A., Taranov D.M., Krivoshlykov A.N., Borodkina S.V. Kinetics of Phase Transformations during Selective Dissolution of Cu5Zn8. Condensed Matter and Interphases, 2020, vol. 22, no. 3, pp. 344–352. DOI: 10.17308/kcmf.2020.22/2965.</mixed-citation><mixed-citation xml:lang="ru">Козадеров О.А., Таранов Д.М., Кривошлыков А.Н., Бородкина С.В. Кинетика фазовых превращений при селективном растворении интерметаллида Cu5Zn8 // Конденсированные среды и межфазные границы. 2020. Т. 22. № 3. С. 344–352. DOI: 10.17308/kcmf.2020.22/2965.</mixed-citation></citation-alternatives></ref><ref id="B10"><label>10.</label><citation-alternatives><mixed-citation xml:lang="en">Dürrschnabel W. Eisen und Phosphor in CuZn36: I. Die Löslichkeit von Eisen und Phosphor in CuZn36. International Journal of Materials Research, 1968, vol. 59, no. 12, pp. 887–894. DOI: 10.1515/ijmr-1968-591201.</mixed-citation><mixed-citation xml:lang="ru">Dürrschnabel W. Eisen und Phosphor in CuZn36: I. Die Löslichkeit von Eisen und Phosphor in CuZn36 // International Journal of Materials Research. 1968. Vol. 59. № 12. P. 887–894. DOI: 10.1515/ijmr-1968-591201.</mixed-citation></citation-alternatives></ref><ref id="B11"><label>11.</label><citation-alternatives><mixed-citation xml:lang="en">Shchepochkina Yu.A. Latun [Brass], patent RF no. 2625853, 2017. 3 p.</mixed-citation><mixed-citation xml:lang="ru">Щепочкина Ю.А. Латунь: патент РФ № 2625853, 2017. 3 с.</mixed-citation></citation-alternatives></ref><ref id="B12"><label>12.</label><citation-alternatives><mixed-citation xml:lang="en">Stetsenko V.Yu. On modifying of hypereutectic silumins. Lite i metallurgiya, 2008, no. 1, pp. 151–154. EDN: WAMPTB.</mixed-citation><mixed-citation xml:lang="ru">Стеценко В.Ю. О модифицировании заэвтектических сулуминов // Литье и металлургия. 2008. № 1. С. 151–154. EDN: WAMPTB.</mixed-citation></citation-alternatives></ref><ref id="B13"><label>13.</label><citation-alternatives><mixed-citation xml:lang="en">Adineh M., Doostmohammadi H., Raiszadeh R. Effect of Si and Al on the Microstructure, Mechanical Properties and Machinability of 65Cu–35Zn Brass. Iranian Journal of Materials Science &amp; Engineering, 2019, vol. 16, no. 2, pp. 21–32. DOI: 10.22068/IJMSE.16.2.21.</mixed-citation><mixed-citation xml:lang="ru">Adineh M., Doostmohammadi H., Raiszadeh R. Effect of Si and Al on the Microstructure, Mechanical Properties and Machinability of 65Cu–35Zn Brass // Iranian Journal of Materials Science &amp; Engineering. 2019. Vol. 16. № 2. P. 21–32. DOI: 10.22068/IJMSE.16.2.21.</mixed-citation></citation-alternatives></ref><ref id="B14"><label>14.</label><citation-alternatives><mixed-citation xml:lang="en">Huang Hui-zhen, Lu De, Shuai Ge-wang, Wei Xiu-qin. Effects of Phosphorus Addition on the Corrosion Resistance of Sn–0.7Cu Lead-Free Solder Alloy. Transactions of the Indian Institute of Metals, 2016, vol. 69, pp. 1537–1543. DOI: 10.1007/s12666-015-0727-1.</mixed-citation><mixed-citation xml:lang="ru">Huang Hui-zhen, Lu De, Shuai Ge-wang, Wei Xiu-qin. Effects of Phosphorus Addition on the Corrosion Resistance of Sn–0.7Cu Lead-Free Solder Alloy // Transactions of the Indian Institute of Metals. 2016. Vol. 69. P. 1537–1543. DOI: 10.1007/s12666-015-0727-1.</mixed-citation></citation-alternatives></ref><ref id="B15"><label>15.</label><citation-alternatives><mixed-citation xml:lang="en">Svyatkin A.V. The influence of heating temperature for forging on the cracking tendency of a Cu-Mn-Al-Fe-Ni 59-3.5-2.5-0.5-0.4 workpiece. Science Vector of Togliatti State University, 2018, no. 3, pp. 48–56. DOI: 10.18323/2073-5073-2018-3-48-56.</mixed-citation><mixed-citation xml:lang="ru">Святкин А.В. Влияние температуры нагрева под штамповку на склонность к растрескиванию заготовок из ЛМцАЖН 59-3,5-2,5-0,4-0,2 // Вектор науки Тольяттинского государственного университета. 2018. № 3. С. 48–56. DOI: 10.18323/2073-5073-2018-3-48-56.</mixed-citation></citation-alternatives></ref><ref id="B16"><label>16.</label><mixed-citation>Sandström R. The role of phosphorus for mechanical properties in copper: technical reports. Stralsäkerhetsmyndigheten, 2014. 23 p.</mixed-citation></ref><ref id="B17"><label>17.</label><citation-alternatives><mixed-citation xml:lang="en">Yunguo Li, Korzhavyi P.A., Sandström R., Lilja C. Impurity effects on the grain boundary cohesion in copper. Physical Review Materials, 2017, vol. 1, no. 7, article number 070602(R). DOI: 10.1103/PhysRevMaterials.1.070602.</mixed-citation><mixed-citation xml:lang="ru">Yunguo Li, Korzhavyi P.A., Sandström R., Lilja C. Impurity effects on the grain boundary cohesion in copper // Physical Review Materials. 2017. Vol. 1. № 7. Article number 070602(R). DOI: 10.1103/PhysRevMaterials.1.070602.</mixed-citation></citation-alternatives></ref><ref id="B18"><label>18.</label><citation-alternatives><mixed-citation xml:lang="en">Sandström R., Lousada C. The role of binding energies for phosphorus and sulphur at grain boundaries in copper. Journal of Nuclear Materials, 2020, vol. 544, article number 152682. DOI: 10.1016/j.jnucmat.2020.152682.</mixed-citation><mixed-citation xml:lang="ru">Sandström R., Lousada C. The role of binding energies for phosphorus and sulphur at grain boundaries in copper // Journal of Nuclear Materials. 2020. Vol. 544. Article number 152682. DOI: 10.1016/j.jnucmat.2020.152682.</mixed-citation></citation-alternatives></ref><ref id="B19"><label>19.</label><citation-alternatives><mixed-citation xml:lang="en">Svyatkin A.V., Vyboyshchik M.A., Gnusina A.M. Effect of metastable compounds on susceptibility to cracking of multicomponent brasses. Deformatsiya i razrushenie materialov, 2024, no. 4, pp. 32–40. EDN: OGLZJL.</mixed-citation><mixed-citation xml:lang="ru">Святкин А.В., Выбойщик М.А., Гнусина А.М. Влияние метастабильных соединений на склонность к растрескиванию многокомпонентных латуней // Деформация и разрушение материалов. 2024. № 4. С. 32–40. EDN: OGLZJL.</mixed-citation></citation-alternatives></ref><ref id="B20"><label>20.</label><citation-alternatives><mixed-citation xml:lang="en">Kamali-M S., Häggström L., Ericsson T., Wappling R. Metallurgical behavior of iron in brass studied using Mössbauer spectroscopy. Hyperfine Interact, 2006, vol. 168, pp. 995–999. DOI: 10.1007/s10751-006-9386-2.</mixed-citation><mixed-citation xml:lang="ru">Kamali-M S., Häggström L., Ericsson T., Wappling R. Metallurgical behavior of iron in brass studied using Mössbauer spectroscopy // Hyperfine Interact. 2006. Vol. 168. P. 995–999. DOI: 10.1007/s10751-006-9386-2.</mixed-citation></citation-alternatives></ref><ref id="B21"><label>21.</label><citation-alternatives><mixed-citation xml:lang="en">Svyatkin A.V., Gnusina A.M., Gryzunova N.N. On the effect of heating of two-phase alloyed brasses on morphological perculiarities of intermetallic inclusions. Physics of Metals and Metallography, 2024, vol. 125, no. 6, pp. 594–602.</mixed-citation><mixed-citation xml:lang="ru">Svyatkin A.V., Gnusina A.M., Gryzunova N.N. On the effect of heating of two-phase alloyed brasses on morphological perculiarities of intermetallic inclusions // Physics of Metals and Metallography. 2024. Vol. 125. № 6. P. 594–602.</mixed-citation></citation-alternatives></ref></ref-list></back></article>
