Frontier Materials & TechnologiesFrontier Materials & TechnologiesFrontier Materials & Technologies2782-40392782-6074Togliatti State University93510.18323/2782-4039-2024-2-68-1ArticlesСтатьиResearch ArticleInfluence of high-pressure torsion on the structure and mechanical properties of Zn–1%Fe–5%Mg zinc alloyВлияние интенсивной пластической деформации кручением на структуру и механические свойства цинкового сплава Zn–1%Fe–5%Mghttps://orcid.org/0009-0009-2775-7488AbdrakhmanovaElmira D.АбдрахмановаЭльмира Дамировна
Russian Federation

student

студент

elmira.abdr2019@mail.ruhttps://orcid.org/0000-0002-4618-412XKhafizovaElvira D.ХафизоваЭльвира Динифовна
Russian Federation

PhD (Engineering), assistant professor of Chair of Materials Science and Physics of Metals, senior researcher of Scientific Research Laboratory “Metals and Alloys under Extreme Impacts”

кандидат технических наук, доцент кафедры материаловедения и физики металлов, старший научный сотрудник научно-исследовательской лаборатории «Металлы и сплавы при экстремальных воздействиях»

KhafizovaED@uust.ruhttps://orcid.org/0000-0001-9774-1689PolenokMilena V.ПоленокМилена Владиславовна
Russian Federation

student

студент

renaweiwei.179@mail.ruhttps://orcid.org/0000-0003-1280-6258NafikovRuslan K.НафиковРуслан Камилович
Russian Federation

junior researcher of Scientific Research Laboratory “Metals and Alloys under Extreme Impacts”

младший научный сотрудник научно-исследовательской лаборатории «Металлы и сплавы при экстремальных воздействиях»

nafickov.ruslan2011@yandex.ruhttps://orcid.org/0000-0002-5975-4849KorznikovaElena A.КорзниковаЕлена Александровна
Russian Federation

Doctor of Sciences (Physics and Mathematics), Professor, professor of Chair of Materials Science and Physics of Metals, Head of Scientific Research Laboratory “Metals and Alloys under Extreme Impacts”

доктор физико-математических наук, профессор, профессор кафедры материаловедения и физики металлов, заведующий научно-исследовательской лабораторией «Металлы и сплавы при экстремальных воздействиях»

elena.a.korznikova@gmail.comUfa University of Science and TechnologyУфимский университет науки и технологий2806202429222806202428062024Copyright ©; 2024, Abdrakhmanova E.D., Khafizova E.D., Polenok M.V., Nafikov R.K., Korznikova E.A.Copyright ©; 2024, Абдрахманова Э.Д., Хафизова Э.Д., Поленок М.В., Нафиков Р.К., Корзникова Е.А.2024Abdrakhmanova E.D., Khafizova E.D., Polenok M.V., Nafikov R.K., Korznikova E.A.Абдрахманова Э.Д., Хафизова Э.Д., Поленок М.В., Нафиков Р.К., Корзникова Е.А.https://creativecommons.org/licenses/by/4.0https://vektornaukitech.ru/jour/article/view/935

Currently, scientists search for new materials for temporary implants that can dissolve in the body, which leads to the fact that there is no need for repeated surgery. In the last decade, scientific interest has focused on zinc-based materials because, unlike other metals, it has suitable corrosion rates and good biocompatibility. The paper describes an experiment for the study of the influence of deformation on the microstructure, strength and corrosion properties of an alloy of the Zn–Fe–Mg system. The authors carried out energy dispersive analysis and calculation of the volume fraction of the second phase of the Zn–Fe–Mg zinc alloy. The corrosion properties of the Zn–Fe–Mg zinc alloy with different microstructures (before and after high-pressure torsion) were studied using the gravimetric method under conditions simulating conditions inside a living organism (temperature, corrosive environment composition). During the tests, the corrosion mechanism was determined, its rate and mass loss of the samples were calculated. The relief of the corrosion surface was studied using scanning electron microscopy. It has been found that the destruction of the material in a corrosive environment occurs through a matrix containing the active Mg metal. The results of calculations of the corrosion rate for the original sample and samples subjected to high-pressure torsion differed due to a more even distribution of second phase particles during severe plastic deformation. In this work, by alloying zinc with iron and magnesium, as well as using high-pressure torsion, it was possible to increase the microhardness of the samples to 239.6±8 HV, which is a high indicator for zinc alloys.

В настоящее время ведутся поиски новых материалов для временных имплантатов, способных растворяться в организме, что приводит к исчезновению потребности в повторной операции. В последнее десятилетие интерес ученых был сосредоточен на материалах на основе цинка, так как он, в отличие от других металлов, имеет подходящую скорость коррозии и хорошую биосовместимость. В работе описан эксперимент по изучению влияния деформации на микроструктуру, прочностные и коррозионные свойства сплава системы Zn–Fe–Mg. Проведен энергодисперсионный анализ и расчет объемной доли второй фазы цинкового сплава Zn–Fe–Mg. Гравиметрическим методом исследованы коррозионные свойства цинкового сплава Zn–Fe–Mg с разной микроструктурой (до и после интенсивной пластической деформации кручением) в условиях, имитирующих условия внутри живого организма (температура, состав коррозионной среды). В ходе испытаний определен механизм протекания коррозии, рассчитаны ее скорость и потеря массы образцов. Проведены исследования рельефа коррозионной поверхности методом растровой электронной микроскопии. Установлено, что разрушение материала в коррозионной среде происходит по матрице, содержащей активный металл Mg. Результаты расчетов скорости коррозии у исходного и ИПДК-образцов отличались из-за более равномерного распределения частиц второй фазы во время интенсивной пластической деформации. В данной работе методом легирования цинка железом и магнием, а также применением интенсивной пластической деформации кручением получилось повысить микротвердость образцов до 239,6±8 НV, что является высоким показателем для цинковых сплавов.

zinc alloysZn–Fe–Mgbiodegradable implantshigh-pressure torsionbiocompatible materialsцинковые сплавыZn–Fe–Mgбиодеградируемые имплантатыинтенсивная пластическая деформация кручениембиосовместимые материалыThe research was financially supported by a grant in the field of science from the budget of the Republic of Bashkortostan for state support of young scientists (Scientific and Educational Center – Grant for Young Scientists – 2022, Agreement No. 1 of 13.12.2022). The work of Korznikova E.A., Nafikov R.K. was carried out under financial support of the Ministry of Science and Higher Education of the Russian Federation within the state assignment for public service delivery given to Ufa University of Science and Technology (Agreement No. 075-03-2024-123/1) “Youth Science and Research Laboratory of Scientific and Educational Center “Metals and Alloys under Extreme Impacts”. The research part of the work was carried out using the equipment of the Core Facility Centre “Nanotech” of Ufa University of Science and Technology. The paper was written on the reports of the participants of the XI International School of Physical Materials Science (SPM-2023), Togliatti, September 11–15, 2023.Исследования выполнены за счет средств гранта в области науки из бюджета Республики Башкортостан для государственной поддержки молодых ученых (НОЦ-ГМУ-2022, Соглашение № 1 от 13.12.2022). Работа Корзниковой Е.А., Нафикова Р.К. выполнена при финансовой поддержке Министерства науки и высшего образования РФ в рамках государственного задания на оказание государственных услуг ФГБОУ ВО УУНиТ (соглашение № 075-03-2024-123/1) «Молодежная научно-исследовательская лаборатория НОЦ "Металлы и сплавы при экстремальных воздействиях"». Исследовательская часть работы выполнена с использованием оборудования ЦКП «Нанотех» ФГБОУ ВО УУНиТ. Статья подготовлена по материалам докладов участников XI Международной школы «Физическое материаловедение» (ШФМ-2023), Тольятти, 11–15 сентября 2023 года.Kogan S., Sood A., Granick M.S. Zinc and Wound Healing: A Review of Zinc Physiology and Clinical Applications. Wounds, 2017, vol. 29, no. 4, pp. 102–106.Kogan S., Sood A., Granick M.S. Zinc and Wound Healing: A Review of Zinc Physiology and Clinical Applications // Wounds. 2017. Vol. 29. № 4. P. 102–106.Lin Mao, Li Shen, Jiahui Chen et al. A promising biodegradable magnesium alloy suitable for clinical vascular stent application. Scientific Reports, 2017, vol. 7, article number 46343. DOI: 10.1038/srep46343.Lin Mao, Li Shen, Jiahui Chen et al. A promising biodegradable magnesium alloy suitable for clinical vascular stent application // Scientific Reports. 2017. Vol. 7. Article number 46343. DOI: 10.1038/srep46343.Yang Hongtao, Jia Bo, Zhang Zechuan, Qu Xinhua, Li Guannan, Lin Wenjiao, Zhu Donghui, Dai Kerong, Zheng Yufeng. Alloying design of biodegradable zinc as promising bone implants for load-bearing applications. Nature Communications, 2020, vol. 11, article number 401. DOI: 10.1038/s41467-019-14153-7.Yang Hongtao, Jia Bo, Zhang Zechuan, Qu Xinhua, Li Guannan, Lin Wenjiao, Zhu Donghui, Dai Kerong, Zheng Yufeng. Alloying design of biodegradable zinc as promising bone implants for load-bearing applications // Nature Communications. 2020. Vol. 11. Article number 401. DOI: 10.1038/s41467-019-14153-7.Shi Zhangzhi, Li Changheng, Li Meng, Li Xiangmin, Wang Luning. Second phase refining induced optimization of Fe alloying in Zn: Significantly enhanced strengthening effect and corrosion uniformity. International Journal Minerals, Metallurgy and Materials, 2022, vol. 29, pp. 796–806. DOI: 10.1007/s12613-022-2468-6.Shi Zhangzhi, Li Changheng, Li Meng, Li Xiangmin, Wang Luning. Second phase refining induced optimization of Fe alloying in Zn: Significantly enhanced strengthening effect and corrosion uniformity // International Journal Minerals, Metallurgy and Materials. 2022. Vol. 29. P. 796–806. DOI: 10.1007/s12613-022-2468-6.Mita K., Ikeda T., Maeda M. Phase diagram study of Fe–Zn intermetallics. Journal of Phase Equilibria, 2001, vol. 22, pp. 122–125. DOI: 10.1361/105497101770338978.Mita K., Ikeda T., Maeda M. Phase diagram study of Fe–Zn intermetallics // Journal of Phase Equilibria. 2001. Vol. 22. P. 122–125. DOI: 10.1361/105497101770338978.Su Yingchao, Fu Jiayin, Lee Wonsae, Du Shaokang, Qin Yi-Xian, Zheng Yufeng, Wang Yadong, Zhu Donghui. Improved mechanical, degradation, and biological perfomaces of Zn–Fe alloys as bioresorbable implants. Bioactive Materials, 2022, vol. 17, pp. 334–343. DOI: 10.1016/j.bioactmat.2021.12.030.Su Yingchao, Fu Jiayin, Lee Wonsae, Du Shaokang, Qin Yi-Xian, Zheng Yufeng, Wang Yadong, Zhu Donghui. Improved mechanical, degradation, and biological perfomaces of Zn–Fe alloys as bioresorbable implants // Bioactive Materials. 2022. Vol. 17. P. 334–343. DOI: 10.1016/j.bioactmat.2021.12.030.Shao Xiaoxi, Wang Xiang, Xu Fangfang et al. In vivo biocompatibility and degradability of a Zn–Mg–Fe alloy osteosynthesis system // Bioactive Materials. 2022. Vol. 7. P. 154–166. DOI: 10.1016/j.bioactmat.2021.05.012.Mostaed E., Sikora-Jasinska M., Mostaed A., Loffredo S., Demir A.G., Previtali B., Mantovani D., Beanland R., Vedani M. Novel Zn-based alloys for biodegradable stent applications: Design, development and in vitro degradation // Journal of the Mechanical Behavior of Biomedical Materials. 2016. Vol. 60. P. 581–602. DOI: 10.1016/j.jmbbm.2016.03.018.Vojtěch D., Kubásek J., Šerák J., Novák P. Mechanical and corrosion properties of newly developed biodegradable Zn-based alloys for bone fixation. Acta Biomaterialia, 2011, vol. 7, no. 9, pp. 3515–3522. DOI: 10.1016/j.actbio.2011.05.008.Vojtěch D., Kubásek J., Šerák J., Novák P. Mechanical and corrosion properties of newly developed biodegradable Zn-based alloys for bone fixation // Acta Biomaterialia. 2011. Vol. 7. № 9. P. 3515–3522. DOI: 10.1016/j.actbio.2011.05.008.Valiev R.Z., Islamgaliev R.K., Alexandrov I.V. Bulk nanostructured materials from severe plastic deformation. Progress in Materials Science, 2000, vol. 45, no. 2, pp. 103–189. DOI: 10.1016/S0079-6425(99)00007-9.Valiev R.Z., Islamgaliev R.K., Alexandrov I.V. Bulk nanostructured materials from severe plastic deformation // Progress in Materials Science. 2000. Vol. 45. № 2. P. 103–189. DOI: 10.1016/S0079-6425(99)00007-9.Li Baoping, Dong Anping, Zhu Guoliang, Chu Shuangjie, Qian Hongwei, Hu Chengjie, Sun Baode, Wang Jun. Investigation of the corrosion behaviors of continuously hot-dip galvanizing Zn–Mg coating. Surface and Coatings Technology, 2012, vol. 206, no. 19-20, pp. 3989–3999. DOI: 10.1016/j.surfcoat.2012.03.079.Li Baoping, Dong Anping, Zhu Guoliang, Chu Shuangjie, Qian Hongwei, Hu Chengjie, Sun Baode, Wang Jun. Investigation of the corrosion behaviors of continuously hot-dip galvanizing Zn–Mg coating // Surface and Coatings Technology. 2012. Vol. 206. № 19-20. P. 3989–3999. DOI: 10.1016/j.surfcoat.2012.03.079.Prosek T., Nazarov A., Bexell U., Thierry D., Serak J. Corrosion mechanism of model zinc–magnesium alloys in atmospheric conditions. Corrosion Science, 2008, vol. 50, no. 8, pp. 2216–2231. DOI: 10.1016/j.corsci.2008.06.008.Prosek T., Nazarov A., Bexell U., Thierry D., Serak J. Corrosion mechanism of model zinc–magnesium alloys in atmospheric conditions // Corrosion Science. 2008. Vol. 50. № 8. P. 2216–2231. DOI: 10.1016/j.corsci.2008.06.008.Xue Penghao, Ma Minglong, Li Yongjun, Li Xinggang, Yuan Jiawei, Shi Guoliang, Wang Kaikun, Zhang Kui. Microstructure, Hot Deformation Behavior, and Recrystallization Behavior of Zn–1Fe–1Mg Alloy under Isothermal Compression. Materials, 2021, vol. 14, no. 7, article number 1735. DOI: 10.3390/ma14071735.Xue Penghao, Ma Minglong, Li Yongjun, Li Xinggang, Yuan Jiawei, Shi Guoliang, Wang Kaikun, Zhang Kui. Microstructure, Hot Deformation Behavior, and Recrystallization Behavior of Zn–1Fe–1Mg Alloy under Isothermal Compression // Materials. 2021. Vol. 14. № 7. Article number 1735. DOI: 10.3390/ma14071735.Xue Penghao, Ma Minglong, Li Yongjun, Li Xinggang, Yuan Jiawei, Shi Guoliang, Wang Kaikun, Zhang Kui. Microstructure, Mechanical Properties, and In Vitro Corrosion Behavior of Biodegradable Zn–1Fe–xMg Alloy. Materials, 2020, vol. 13, no. 21, article number 4835. DOI: 10.3390/ma13214835.Xue Penghao, Ma Minglong, Li Yongjun, Li Xinggang, Yuan Jiawei, Shi Guoliang, Wang Kaikun, Zhang Kui. Microstructure, Mechanical Properties, and In Vitro Corrosion Behavior of Biodegradable Zn–1Fe–xMg Alloy // Materials. 2020. Vol. 13. № 21. Article number 4835. DOI: 10.3390/ma13214835.Polenok M.V., Khafizova E.D., Islamgaliev R.K. The influence of severe plastic deformation on mechanical properties of pure zinc. Frontier Materials & Technologies, 2022, no. 3-2, pp. 25–31. DOI: 10.18323/2782-4039-2022-3-2-25-31.Поленок М.В., Хафизова Э.Д., Исламгалиев Р.К. Влияние интенсивной пластической деформации на механические свойства чистого цинка // Frontier Materials & Technologies. 2022. № 3-2. C. 25–31. DOI: 10.18323/2782-4039-2022-3-2-25-31.Mostaed E., Sikora-Jasinska M., Drelich J.W., Vedani M. Zinc-based alloys for degradable vascular stent application. Acta Biomaterialia, 2018, vol. 71, pp. 1–23. DOI: 10.1016/j.actbio.2018.03.005.Mostaed E., Sikora-Jasinska M., Drelich J.W., Vedani M. Zinc-based alloys for degradable vascular stent application // Acta Biomaterialia. 2018. Vol. 71. P. 1–23. DOI: 10.1016/j.actbio.2018.03.005.Razumov I.K., Ermakov A.Y., Gornostyrev Yu.N., Straumal B.B. Nonequilibrium phase transformations in alloys under severe plastic deformation. Physics-Uspekhi, 2020, vol. 63, no. 8, pp. 733–757. DOI: DOI: 10.3367/UFNe.2019.10.038671.Разумов И.К., Ермаков А.Е., Горностырев Ю.Н., Страумал Б.Б. Неравновесные фазовые превращения в сплавах // Успехи физических наук. 2019. Т. 190. № 8. С. 785–810. DOI: 10.3367/UFNr.2019.10.038671.Zhang Xiaoge Gregory. Corrosion potential and corrosion current. Corrosion and Electrochemistry of Zinc. Boston, Springer Publ., 1996, pp. 125–156. DOI: 10.1007/978-1-4757-9877-7_5.Zhang Xiaoge Gregory. Corrosion potential and corrosion current // Corrosion and Electrochemistry of Zinc. Boston: Springer, 1996. P. 125–156. DOI: 10.1007/978-1-4757-9877-7_5.Khudododova G.D., Kulyasova O.B., Islamgaliev R.K. Strength and corrosion resistance of the UFG Mg-Zn-Ca alloy. Nanoindustriya, 2022, vol. 15, no. 7-8, pp. 426–433. DOI: 10.22184/1993-8578.2022.15.7-8.426.433.Худододова Г.Д., Кулясова О.Б., Исламгалиев Р.К. Прочностные и коррозионные свойства УМЗ-сплава Mg–Zn–Ca // Наноиндустрия. 2022. Т. 15. № 7-8. С. 426–433. DOI: 10.22184/1993-8578.2022.15.7-8.426.433.Byun Jong Min, Yu Jin Min, Kim Dae Kyung, Kim Tae Yeob, Jun Woo Sung, Kim Young Do. Corrosion Behavior of Mg2Zn11 and MgZn2 Single Phases. Korean Journal of Metals and Materials, 2013, vol. 51, no. 6, pp. 413–419. DOI: 10.3365/KJMM.2013.51.6.413.Byun Jong Min, Yu Jin Min, Kim Dae Kyung, Kim Tae Yeob, Jun Woo Sung, Kim Young Do. Corrosion Behavior of Mg2Zn11 and MgZn2 Single Phases // Korean Journal of Metals and Materials. 2013. Vol. 51. № 6. P. 413–419. DOI: 10.3365/KJMM.2013.51.6.413.Wątroba M., Mech K., Bednarczyk W., Kawałko J., Marciszko-Wiąckowska M., Marzec M., Shepherd D.E.T., Bała P. Long-term in vitro corrosion behavior of Zn–3Ag and Zn–3Ag–0.5Mg alloys considered for biodegradable implant applications. Materials & Design, 2022, vol. 213, article number110289. DOI: 10.1016/j.matdes.2021.110289.Wątroba M., Mech K., Bednarczyk W., Kawałko J., Marciszko-Wiąckowska M., Marzec M., Shepherd D.E.T., Bała P. Long-term in vitro corrosion behavior of Zn–3Ag and Zn–3Ag–0.5Mg alloys considered for biodegradable implant applications // Materials & Design. 2022. Vol. 213. Article number110289. DOI: 10.1016/j.matdes.2021.110289.Bowen P.K., Shearier E.R., Shan Zhao, Guillory R.J., Feng Zhao, Goldman J., Drelich J.W. Biodegradable Metals for Cardiovascular Stents: from Clinical Concerns to Recent Zn-Alloys. Advanced Healthcare Materials, 2016, vol. 5, no. 10, pp. 1121–1140. DOI: 10.1002/adhm.201501019.Bowen P.K., Shearier E.R., Shan Zhao, Guillory R.J., Feng Zhao, Goldman J., Drelich J.W. Biodegradable Metals for Cardiovascular Stents: from Clinical Concerns to Recent Zn-Alloys // Advanced Healthcare Materials. 2016. Vol. 5. № 10. P. 1121–1140. DOI: 10.1002/adhm.201501019.Shi Zhang-Zhi, Gao Xi-Xian, Chen Hong-Ting, Liu Xue-Feng, Li Ang, Zhang Hai-Jun, Wang Lu-Ning. Enhancement in mechanical and corrosion resistance properties of a biodegradable Zn–Fe alloy through second phase refinement. Materials Science and Engineering: C, 2020, vol. 116, article number 111197. DOI: 10.1016/j.msec.2020.111197.Shi Zhang-Zhi, Gao Xi-Xian, Chen Hong-Ting, Liu Xue-Feng, Li Ang, Zhang Hai-Jun, Wang Lu-Ning. Enhancement in mechanical and corrosion resistance properties of a biodegradable Zn–Fe alloy through second phase refinement // Materials Science and Engineering: C. 2020. Vol. 116. Article number 111197. DOI: 10.1016/j.msec.2020.111197.Yan Zhaoming, Zhu Jiaxuan, Zhang Zhimin, Wang Qiang, Xue Yong. The microstructural, textural, and mechanical effects of high-pressure torsion processing on Mg alloys: A review. Frontiers in Materials, 2022, vol. 9, article number 964992. DOI: 10.3389/fmats.2022.964992.Yan Zhaoming, Zhu Jiaxuan, Zhang Zhimin, Wang Qiang, Xue Yong. The microstructural, textural, and mechanical effects of high-pressure torsion processing on Mg alloys: A review // Frontiers in Materials. 2022. Vol. 9. Article number 964992. DOI: 10.3389/fmats.2022.964992.Myagkikh P.N., Merson E.D., Poluyanov V.A., Merson D.L. The dependence of the biodegradable ZX10 alloy corrosion process on the structural factors and local pH level. Frontier Materials & Technologies, 2023, no. 2, pp. 59–76. DOI: 10.18323/2782-4039-2023-2-64-3.Мягких П.Н., Мерсон Е.Д., Полуянов В.А., Мерсон Д.Л. Зависимость процесса коррозии биорезорбируемого сплава ZX10 от структурных факторов и локального уровня pH // Frontier Materials & Technologies. 2023. № 2. С. 59–76. DOI: 10.18323/2782-4039-2023-2-64-3.Vinogradov A., Merson E., Myagkikh P., Linderov M., Brilevsky A., Merson D. Attaining High Functional Performance in Biodegradable Mg-Alloys: An Overview of Challenges and Prospects for the Mg–Zn–Ca System. Materials, 2023, vol. 16, no. 3, article number 1324. DOI: 10.3390/ma16031324.Vinogradov A., Merson E., Myagkikh P., Linderov M., Brilevsky A., Merson D. Attaining High Functional Performance in Biodegradable Mg-Alloys: An Overview of Challenges and Prospects for the Mg–Zn–Ca System // Materials. 2023. Vol. 16. № 3. Article number 1324. DOI: 10.3390/ma16031324.Yao Caizhen, Wang Zichao, Tay See Leng, Zhu Tianping, Gao Wei. Effects of Mg on microstructure and corrosion properties of Zn–Mg alloy. Journal of Alloys and Compounds, 2014, vol. 602, pp. 101–107. DOI: 10.1016/j.jallcom.2014.03.025.Yao Caizhen, Wang Zichao, Tay See Leng, Zhu Tianping, Gao Wei. Effects of Mg on microstructure and corrosion properties of Zn–Mg alloy // Journal of Alloys and Compounds. 2014. Vol. 602. P. 101–107. DOI: 10.1016/j.jallcom.2014.03.025.