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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" article-type="other" dtd-version="1.2" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">Frontier Materials &amp; Technologies</journal-id><journal-title-group><journal-title xml:lang="en">Frontier Materials &amp; Technologies</journal-title><trans-title-group xml:lang="ru"><trans-title>Frontier Materials &amp; Technologies</trans-title></trans-title-group></journal-title-group><issn publication-format="print">2782-4039</issn><issn publication-format="electronic">2782-6074</issn><publisher><publisher-name xml:lang="en">Togliatti State University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="publisher-id">893</article-id><article-id pub-id-type="doi">10.18323/2782-4039-2023-4-66-6</article-id><article-categories><subj-group subj-group-type="toc-heading" xml:lang="en"><subject>Articles</subject></subj-group><subj-group subj-group-type="toc-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="article-type"><subject></subject></subj-group></article-categories><title-group><article-title xml:lang="en">Investigation of phase transformations in a two-layer Ti–Al–C+Y–Al–O coating on a heat-resistant nickel alloy</article-title><trans-title-group xml:lang="ru"><trans-title>Исследование фазовых превращений в двухслойном жаростойком покрытии Ti–Al–C+Y–Al–O на жаропрочном никелевом сплаве</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-4711-4721</contrib-id><name-alternatives><name xml:lang="en"><surname>Nazarov</surname><given-names>Almaz Yunirovich</given-names></name><name xml:lang="ru"><surname>Назаров</surname><given-names>Алмаз Юнирович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), assistant professor of Chair of Mechanical Engineering</p></bio><bio xml:lang="ru"><p>кандидат технических наук, доцент кафедры технологии машиностроения</p></bio><email>nazarov.ayu@ugatu.su</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2568-1784</contrib-id><name-alternatives><name xml:lang="en"><surname>Maslov</surname><given-names>Aleksey Andreevich</given-names></name><name xml:lang="ru"><surname>Маслов</surname><given-names>Алексей Андреевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>laboratory assistant of Chair of Mechanical Engineering</p></bio><bio xml:lang="ru"><p>лаборант кафедры технологии машиностроения</p></bio><email>alexey.maslov2011@gmail.com</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Nikolaev</surname><given-names>Aleksey Aleksandrovich</given-names></name><name xml:lang="ru"><surname>Николаев</surname><given-names>Алексей Александрович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>assistant of Chair of Mechanical Engineering</p></bio><bio xml:lang="ru"><p>ассистент кафедры технологии машиностроения</p></bio><email>nikolaev.aleksej95@gmail.com</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Shmakov</surname><given-names>Aleksandr Nikolaevich</given-names></name><name xml:lang="ru"><surname>Шмаков</surname><given-names>Александр Николаевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>leading researcher</p></bio><bio xml:lang="ru"><p>ведущий научный сотрудник</p></bio><email>highres@mail.ru</email><xref ref-type="aff" rid="aff2"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Denisov</surname><given-names>Vladimir Viktorovich</given-names></name><name xml:lang="ru"><surname>Денисов</surname><given-names>Владимир Викторович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), Head of Laboratory of Beam-Plasma Surface Engineering</p></bio><bio xml:lang="ru"><p>кандидат технических наук, заведующий лабораторией пучково-плазменной инженерии поверхности</p></bio><email>volodyadenisov@yandex.ru</email><xref ref-type="aff" rid="aff3"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Ramazanov</surname><given-names>Kamil Nurullaevich</given-names></name><name xml:lang="ru"><surname>Рамазанов</surname><given-names>Камиль Нуруллаевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>Doctor of Sciences (Engineering), Head of Chair of Mechanical Engineering</p></bio><bio xml:lang="ru"><p>доктор технических наук, заведующий кафедрой технологии машиностроения</p></bio><email>ramazanovkn@gmail.com</email><xref ref-type="aff" rid="aff1"/></contrib></contrib-group><aff-alternatives id="aff1"><aff><institution xml:lang="en">Ufa University of Science and Technology, Ufa</institution></aff><aff><institution xml:lang="ru">Уфимский университет науки и технологий, Уфа</institution></aff></aff-alternatives><aff-alternatives id="aff2"><aff><institution xml:lang="en">Federal Research Center Boreskov Institute of Catalysis SB of RAS, Novosibirsk&#13;
Institute of High Current Electronics SB of RAS, Tomsk</institution></aff><aff><institution xml:lang="ru">Федеральный исследовательский центр «Институт катализа им. Г.К. Борескова СО РАН», Новосибирск&#13;
Институт сильноточной электроники СО РАН, Томск</institution></aff></aff-alternatives><aff-alternatives id="aff3"><aff><institution xml:lang="en">Institute of High Current Electronics SB of RAS, Tomsk</institution></aff><aff><institution xml:lang="ru">Институт сильноточной электроники СО РАН, Томск</institution></aff></aff-alternatives><pub-date date-type="pub" iso-8601-date="2023-12-30" publication-format="electronic"><day>30</day><month>12</month><year>2023</year></pub-date><issue>4</issue><issue-title xml:lang="en"/><issue-title xml:lang="ru"/><fpage>63</fpage><lpage>71</lpage><history><date date-type="received" iso-8601-date="2023-12-28"><day>28</day><month>12</month><year>2023</year></date></history><permissions><ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/></permissions><self-uri xlink:href="https://vektornaukitech.ru/jour/article/view/893">https://vektornaukitech.ru/jour/article/view/893</self-uri><abstract xml:lang="en"><p>Currently, an active increase in requirements for fuel efficiency and specific gravity of aircraft turbojet engines is observed. Existing coatings based on zirconium dioxide intended for protecting engine parts are largely outdated and have exhausted their development potential, so new ceramic systems for the production of protective coatings based on them are an area of research. The authors carried out a study of a heat-resistant two-layer coating based on the Y–Al–O system (outer layer) and the Ti<sub>2</sub>AlC MAX phase of the Ti–Al–C system (sublayer) produced using vacuum-arc deposition on the Inconel 738 heat-resistant nickel alloy and molybdenum by alternate deposition of layers based on Ti–Al–C and a Y–Al–O layer. Using synchrotron radiation, phase transformations in the coating were examined when samples were heated to 1400 °C in a vacuum and to 1100 °C in the atmosphere to study the process of oxidation and coating formation in the presence of oxygen. Using scanning electron microscopy, the authors studied the microstructure and chemical composition of the coating. The study identified that heating the coating in a vacuum and in the atmosphere causes various phase transformations in it, but in both cases, the formation of a mixture of oxides of the Y–Al–O group and destabilization of the Ti–Al–C-based sublayer are observed. After heating the coating in the atmosphere without preliminary heat treatment, the coating was destroyed upon cooling, which was not observed when the coating was heated in a vacuum. </p></abstract><trans-abstract xml:lang="ru"><p>На сегодняшний день происходит активный рост требований к топливной эффективности и удельному весу авиационных турбореактивных двигателей. Существующие покрытия для защиты деталей двигателей на основе диоксида циркония во многом устарели и исчерпали потенциал развития, поэтому ведутся исследования новых керамических систем для производства защитных покрытий на их основе. В работе проведено исследование жаростойкого двуслойного покрытия на основе системы Y–Al–O (внешний слой) и МАХ-фазы Ti<sub>2</sub>AlC системы Ti–Al–C (подслой), полученного методом вакуумно-дугового осаждения на жаропрочном никелевом сплаве Inconel 738 и на молибдене поочередным осаждением слоев на основе Ti–Al–C и слоя Y–Al–O. При помощи синхротронного излучения исследованы фазовые превращения в покрытии при нагреве образцов до 1400 °С в вакууме и до 1100 °С в атмосфере с целью изучения процесса окисления и формирования покрытия в условиях присутствия кислорода. При помощи растровой электронной микроскопии изучены микроструктура и химический состав покрытия. Установлено, что нагрев покрытия в вакууме и в атмосфере вызывает в нем различные фазовые превращения, но в обоих случаях наблюдается формирование смеси оксидов группы Y–Al–O и дестабилизация подслоя на основе Ti–Al–C. После нагрева покрытия в атмосфере без предварительной термообработки при остывании покрытие разрушилось, чего не наблюдалось при нагреве покрытия в вакууме.</p></trans-abstract><kwd-group xml:lang="en"><kwd>heat-resistant coating</kwd><kwd>ceramic coating</kwd><kwd>MAX phase</kwd><kwd>yttrium oxide</kwd><kwd>vacuum-arc deposition</kwd><kwd>synchrotron radiation</kwd></kwd-group><kwd-group xml:lang="ru"><kwd>жаростойкое покрытие</kwd><kwd>керамическое покрытие</kwd><kwd>MAX-фаза</kwd><kwd>оксид иттрия</kwd><kwd>вакуумно-дуговое осаждение</kwd><kwd>синхротронное излучение</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 075-15-2021-1348). The paper was written on the reports of the participants of the XI International School of Physical Materials Science (SPM-2023), Togliatti, September 11–15, 2023.</funding-statement><funding-statement xml:lang="ru">Работа выполнена при финансовой поддержке Министерства науки и высшего образования Российской Федерации (проект № 075-15-2021-1348). Статья подготовлена по материалам докладов участников XI Международной школы «Физическое материаловедение» (ШФМ-2023), Тольятти, 11–15 сентября 2023 года.</funding-statement></funding-group></article-meta></front><body></body><back><ref-list><ref id="B1"><label>1.</label><citation-alternatives><mixed-citation xml:lang="en">Mondal K., Nunez L., Lii C.M., Downey I.J., Rooyen I.J. Thermal barrier coatings overview: Design, manufacturing, and applications in high-temperature industries. Industrial &amp; Engineering Chemistry Research, 2021, vol. 60, no. 17, pp. 6061–6077. 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