Frontier Materials & TechnologiesFrontier Materials & TechnologiesFrontier Materials & Technologies2782-40392782-6074Togliatti State University89010.18323/2782-4039-2023-4-66-2ArticlesСтатьиSorption properties of layered double hydroxides produced by ultrasonic exposureСорбционные свойства слоистых двойных гидроксидов, полученных при ультразвуковом воздействииGolubevRoman AleksandrovichГолубевРоман Александрович
Belarus

junior researcher, postgraduate student

младший научный сотрудник, аспирант

asdfdss.asdasf@yandex.ruhttps://orcid.org/0000-0002-0350-1180RubanikVasily VasilievichРубаникВасилий Васильевич
Belarus

Doctor of Sciences (Engineering), corresponding member of the National Academy of Sciences of Belarus, Associate Professor, Head of Laboratory of Metal Physics

доктор технических наук, член-корреспондент Национальной академии наук Беларуси, доцент, заведующий лабораторией физики металлов

v.v.rubanik@tut.byhttps://orcid.org/0000-0002-9268-0167Rubanik Jr.Vasily VasilievichРубаник мл.Василий Васильевич
Belarus

Doctor of Sciences (Engineering), Associate Professor, Director

доктор технических наук, доцент, директор

ita@vitebsk.byhttps://orcid.org/0000-0003-0108-0690KritchenkovIlya SergeevichКритченковИлья Сергеевич
Belarus

PhD (Chemistry), senior researcher

кандидат химических наук, старший научный сотрудник

ilya.kritchenkov@gmail.comhttps://orcid.org/0000-0002-6411-5988KritchenkovAndrey SergeevichКритченковАндрей Сергеевич
Belarus

Doctor of Sciences (Chemistry), leading researcher

доктор химических наук, ведущий научный сотрудник

platinist@mail.ruInstitute of Technical Acoustics of the National Academy of Sciences of Belarus, Vitebsk RUDN University (Peoples’ Friendship University of Russia), MoscowИнститут технической акустики Национальной академии наук Беларуси, Витебск Российский университет дружбы народов, МоскваInstitute of Technical Acoustics of the National Academy of Sciences of Belarus, VitebskИнститут технической акустики Национальной академии наук Беларуси, ВитебскInstitute of Technical Acoustics of the National Academy of Sciences of Belarus, VitebskИнститут технической акустики Национальной академии наук Беларуси, ВитебскInstitute of Technical Acoustics of the National Academy of Sciences of Belarus, Vitebsk St. Petersburg State University, St. PetersburgИнститут технической акустики Национальной академии наук Беларуси, Витебск Санкт-Петербургский государственный университет, Санкт-ПетербургInstitute of Technical Acoustics of the National Academy of Sciences of Belarus, Vitebsk RUDN University (Peoples’ Friendship University of Russia), MoscowИнститут технической акустики Национальной академии наук Беларуси, Витебск Российский университет дружбы народов, Москва301220234193028122023https://vektornaukitech.ru/jour/article/view/890

Layered double hydroxides (LDH) can be classified as promising materials due to the ease of synthesis, as well as their wide scope of application. However, the process of LDH synthesis, depending on the LDH chemical composition, can take from tens of hours to several days. It was previously identified that ultrasound exposure during the LDH production significantly reduces the synthesis time, and LDHs produced in this way are interesting in relation to the study of their physicochemical properties and sorption capacity. In this work, the authors produced Mg/Fe LDHs in nitrate form by the traditional method and by the combined action of ultrasound and increased hydrostatic pressure. The resulting samples are characterized by a complex of physicochemical methods of analysis, including scanning electron microscopy (SEM), infrared spectroscopy (IR), X-ray phase analysis (XRD), and thermal gravimetric analysis (TGA) with differential scanning calorimetry (DSC). Experiments were carried out to study the sorption capacity of the obtained Fe/Mg LDH samples in relation to chromate ions under normal conditions and under the influence of ultrasound, including in combination with increased hydrostatic pressure. A photoelectric photometer was used to obtain and analyze data with quantitative values of the sorption process. Data of comprehensive analysis of the finished product indicate that the synthesized material is a Mg/Fe layered double hydroxide. X-ray phase analysis identified that the LDH synthesis using ultrasound and pressure increases the crystallinity degree of the finished product. It has been found that the sorption properties of LDHs produced by the conventional method and LDHs produced under the influence of ultrasound and pressure are different. In Mg/Fe LDHs synthesized by the conventional method, chromate sorption proceeds better than in samples synthesized using ultrasonic treatment in combination with increased hydrostatic pressure. The study shows that the sorption process of the examined LDH samples is described by different mathematical models.

Слоистые двойные гидроксиды (СДГ) можно отнести к классу перспективных материалов благодаря простоте синтеза, а также обширной сфере их применения. Однако процесс синтеза СДГ в зависимости от их химического состава может занимать от десятков часов до нескольких суток. Ранее было установлено, что воздействие ультразвуком в процессе получения СДГ значительно сокращает время синтеза, а полученные таким способом СДГ интересны в отношении изучения их физико-химических свойств, а также сорбционной способности. В работе получены Mg/Fe СДГ в нитратной форме традиционным методом, а также при совместном действии ультразвука и повышенного гидростатического давления. Полученные образцы охарактеризованы с помощью комплекса физико-химических методов анализа, включающих сканирующую электронную микроскопию (СЭМ), инфракрасную спектроскопию (ИК), рентгенофазовый анализ (РФА), термогравиметрический анализ (ТГА) с дифференциальной сканирующей калориметрией (ДСК). Проведены эксперименты по исследованию сорбционной способности полученных образцов Fe/Mg СДГ по отношению к хромат-ионам в нормальных условиях, а также при действии ультразвука, в т. ч. в сочетании с повышенным гидростатическим давлением. На фотоэлектрическом фотометре были получены и проанализированы данные c количественными значениями процесса сорбции. Данные, полученные в ходе комплексного анализа готового продукта, указывают на то, что синтезированный материал является Mg/Fe слоистым двойным гидроксидом. При проведении рентгенофазового анализа выявлено, что синтез СДГ с применением ультразвука и давления повышает степень кристалличности конечного продукта. Установлено, что сорбционные свойства СДГ, полученных традиционным способом, и СДГ, полученных под действием ультразвука и давления, отличаются. У Mg/Fe СДГ, синтезированных традиционным методом, сорбция хромата протекает лучше, чем у образцов, синтезированных при помощи ультразвуковой обработки в сочетании с повышенным гидростатическим давлением. Показано, что процесс сорбции исследованных образцов СДГ описывается разными математическими моделями.

layered double hydroxidesMg/Feultrasonic synthesissorption propertieschromate ionsслоистые двойные гидроксидыMg/Feультразвуковой синтезсорбционные свойствахромат-анионыThe work was supported by the Belarusian Republican Foundation for Fundamental Research (project No. H21RM-081). The authors express gratitude to the Individual Project for Fundamental and Applied Research “Ultrasonic Synthesis of Medical-Purpose Layered Double Hydroxides”. The authors express their gratitude to Scientific Park of St. Petersburg State University (Interdisciplinary Resource Center “Nanotechnology” and Resource Center for Chemical Analysis and Materials Research) for their assistance in studying the microstructure (SEM) and IR-spectra of synthesized LDH samples. In commemoration of the 300th anniversary of St. Petersburg State University’s founding. The paper was written on the reports of the participants of the XI International School of Physical Materials Science (SPM-2023), Togliatti, September 11–15, 2023.Работа выполнена при поддержке БРФФИ (проект № Х21РМ-081). Авторы выражают благодарность Отдельному проекту фундаментальных и прикладных научных исследований «Ультразвуковой синтез слоистых двойных гидроксидов медицинского назначения». Авторы выражают признательность научному парку Санкт-Петербургского государственного университета (Междисциплинарный ресурсный центр по направлению «Нанотехнологии» и ресурсный центр «Методы анализа состава вещества») за оказанную помощь в исследовании микроструктуры (СЭМ) и измерении ИК-спектров синтезированных образцов СДГ. Посвящается 300-летнему юбилею основания Санкт-Петербургского государственного университета. Статья подготовлена по материалам докладов участников XI Международной школы «Физическое материаловедение» (ШФМ-2023), Тольятти, 11–15 сентября 2023 года.Aflak N., El Mersly L., Ben El Ayouchia H., Rafqah S., Anane H., Julve M., Stiriba S.E. A new Cu3Al-layered double hydroxide heterogeneous catalyst for azide-alkyne [3 + 2] cycloaddition reaction in water. Journal of Coordination Chemistry, 2022, vol. 75, no. 17-18, pp. 2346–2358. DOI: 10.1080/00958972.2022.2105701.Aflak N., El Mersly L., Ben El Ayouchia H., Rafqah S., Anane H., Julve M., Stiriba S.E. A new Cu3Al-layered double hydroxide heterogeneous catalyst for azide-alkyne [3 + 2] cycloaddition reaction in water // Journal of Coordination Chemistry. 2022. Vol. 75. № 17-18. P. 2346–2358. DOI: 10.1080/00958972.2022.2105701.Seung Yu Seungjin, Piao Huiyan, Rejinold N. Sanoj, Lee Hanna, Choi Goeun, Choy Jin-Ho. pH-Responsive Inorganic/Organic Nanohybrids System for Controlled Nicotinic Acid Drug Release. Molecules, 2022, vol. 27, no. 19, article number 6439. DOI: 10.3390/molecules27196439.Yu Seungjin, Piao Huiyan, Rejinold N. Sanoj, Lee Hanna, Choi Goeun, Choy Jin-Ho. pH-Responsive Inorganic/Organic Nanohybrids System for Controlled Nicotinic Acid Drug Release // Molecules. 2022. Vol. 27. № 19. Article number 6439. DOI: 10.3390/molecules27196439.de Souza dos Santos G.E., dos Santos Lins P.V., Oliveira L.M.T.M., Oliveira da Silva E., Anastopoulos I., Erto A., Giannakoudakis D.A., Almeida A.R.F., Duarte J.L., Meili L. Layered double hydroxides/biochar composites as adsorbents for water remediation applications: recent trends and perspectives. Journal of Cleaner Production, 2020, vol. 284, article number 124755. DOI: 10.1016/j.jclepro.2020.124755.de Souza dos Santos G.E., dos Santos Lins P.V., Oliveira L.M.T.M., Oliveira da Silva E., Anastopoulos I., Erto A., Giannakoudakis D.A., Almeida A.R.F., Duarte J.L., Meili L. Layered double hydroxides/biochar composites as adsorbents for water remediation applications: recent trends and perspectives // Journal of Cleaner Production. 2020. Vol. 284. Article number 124755. DOI: 10.1016/j.jclepro.2020.124755.Johnston A.-L., Lester E., Williams O., Gomes R. Understanding Layered Double Hydroxide properties as sorbent materials for removing organic pollutants from environmental waters. Journal of Environmental Chemical Engineering, 2021, vol. 9, no. 4, article number 105197. DOI: 10.1016/j.jece.2021.105197.Johnston A.-L., Lester E., Williams O., Gomes R. Understanding Layered Double Hydroxide properties as sorbent materials for removing organic pollutants from environmental waters // Journal of Environmental Chemical Engineering. 2021. Vol. 9. № 4. Article number 105197. DOI: 10.1016/j.jece.2021.105197.Matusik J., Rybka K. Removal of chromates and sulphates by Mg/Fe LDH and heterostructured LDH/halloysite materials: Efficiency, selectivity, and stability of adsorbents in single- and multi-element systems. Materials, 2019, vol. 12, no. 9, article number 1373. DOI: 10.3390/ma12091373.Matusik J., Rybka K. Removal of chromates and sulphates by Mg/Fe LDH and heterostructured LDH/halloysite materials: Efficiency, selectivity, and stability of adsorbents in single- and multi-element systems // Materials. 2019. Vol. 12. № 9. Article number 1373. DOI: 10.3390/ma12091373.Shafiq M., Alazba A.A., Amin M.T. Preparation of ZnMgAl-Layered Double Hydroxide and Rice Husk Biochar Composites for Cu(II) and Pb(II) Ions Removal from Synthetic Wastewater. Water (Switzerland), 2023, vol. 15, no. 12, article number 2207. DOI: 10.3390/w15122207.Shafiq M., Alazba A.A., Amin M.T. Preparation of ZnMgAl-Layered Double Hydroxide and Rice Husk Biochar Composites for Cu(II) and Pb(II) Ions Removal from Synthetic Wastewater // Water (Switzerland). 2023. Vol. 15. № 12. Article number 2207. DOI: 10.3390/w15122207.Roy S.C., Rahman M.A., Celik A. et al. Efficient removal of chromium(VI) ions by hexagonal nanosheets of CoAl–MoS4 layered double hydroxide. Journal of Coordination Chemistry, 2022, vol. 75, no. 11-14, pp. 1581–1595. DOI: 10.1080/00958972.2022.2101103.Roy S.C., Rahman M.A., Celik A. et al. Efficient removal of chromium(VI) ions by hexagonal nanosheets of CoAl–MoS4 layered double hydroxide // Journal of Coordination Chemistry. 2022. Vol. 75. № 11-14. P. 1581–1595. DOI: 10.1080/00958972.2022.2101103.Ma Lijiao, Islam S.M., Liu Hongyun, Zhao Jing, Sun Genban, Li Huifeng, Ma Shulan, Kanatzidis M.G. Selective and Efficient Removal of Toxic Oxoanions of As(III), As(V), and Cr(VI) by Layered Double Hydroxide Intercalated with MoS42−. Chemistry of Materials, 2017, vol. 29, no. 7, pp. 3274–3284. DOI: 10.1021/acs.chemmater.7b00618.Ma Lijiao, Islam S.M., Liu Hongyun, Zhao Jing, Sun Genban, Li Huifeng, Ma Shulan, Kanatzidis M.G. Selective and Efficient Removal of Toxic Oxoanions of As(III), As(V), and Cr(VI) by Layered Double Hydroxide Intercalated with MoS42− // Chemistry of Materials. 2017. Vol. 29. № 7. P. 3274–3284. DOI: 10.1021/acs.chemmater.7b00618.Sankaranarayanan S., Gupta M. Emergence of God’s favorite metallic element: Magnesium based materials for engineering and biomedical applications. Materials Today: Proceedings, 2021, vol. 39, pp. 311–316. DOI: 10.1016/j.matpr.2020.07.220.Sankaranarayanan S., Gupta M. Emergence of God’s favorite metallic element: Magnesium based materials for engineering and biomedical applications // Materials Today: Proceedings. 2021. Vol. 39. P. 311–316. DOI: 10.1016/j.matpr.2020.07.220.Williams G.R., O'Hare D. Towards Understanding, Control and Application of Layered Double Hydroxide Chemistry. Cheminform, 2006, vol. 37, no. 45. DOI: 10.1002/chin.200645266.Williams G.R., O'Hare D. Towards Understanding, Control and Application of Layered Double Hydroxide Chemistry // Cheminform. 2006. Vol. 37. № 45. DOI: 10.1002/chin.200645266.Evans D.G., Slade R.C.T. Structural Aspects of Layered Double Hydroxides. Layered Double Hydroxides. Berlin, Springer Berlin Heidelberg Publ., 2006, pp. 1–87. DOI: 10.1007/430_005.Evans D.G., Slade R.C.T. Structural Aspects of Layered Double Hydroxides // Layered Double Hydroxides. Berlin: Springer Berlin Heidelberg, 2006. P. 1–87. DOI: 10.1007/430_005.Srilakshmi Ch., Thirunavukkarasu Th. Enhanced adsorption of Congo red on microwave synthesized layered Zn–Al double hydroxides and its adsorption behaviour using mixture of dyes from aqueous solution. Inorganic Chemistry Communications, 2019, vol. 100, pp. 107–117. DOI: 10.1016/j.inoche.2018.12.027.Srilakshmi Ch., Thirunavukkarasu Th. Enhanced adsorption of Congo red on microwave synthesized layered Zn–Al double hydroxides and its adsorption behaviour using mixture of dyes from aqueous solution // Inorganic Chemistry Communications. 2019. Vol. 100. P. 107–117. DOI: 10.1016/j.inoche.2018.12.027.Go Goh Kok-Hui, Lim Teik Thye, Dong Zhili. Application of layered double hydroxides for removal of oxyanions: A review. Water Research, 2008, vol. 42, no. 6-7, pp. 1343–1368. DOI: 10.1016/j.watres.2007.10.043.Goh Kok-Hui, Lim Teik Thye, Dong Zhili. Application of layered double hydroxides for removal of oxyanions: A review // Water Research. 2008. Vol. 42. № 6-7. P. 1343–1368. DOI: 10.1016/j.watres.2007.10.043.Huang Weiya, Yu Xiang, Li Dan. Adsorption removal of Congo red over flower-like porous microspheres derived from Ni/Al layered double hydroxide. RSC Advances, 2015, vol. 5, no. 103, pp. 84937–84946. DOI: 10.1039/C5RA13922H.Huang Weiya, Yu Xiang, Li Dan. Adsorption removal of Congo red over flower-like porous microspheres derived from Ni/Al layered double hydroxide // RSC Advances. 2015. Vol. 5. № 103. P. 84937–84946. DOI: 10.1039/C5RA13922H.Ibrahimova K.A. The Synthesis Methods and Applications of Layered Double Hydroxides – a Brief Review. NNC RK Bulletin, 2022, no. 4, pp. 16–29. DOI: 10.52676/1729-7885-2022-4-17-29.Ibrahimova K.A. The Synthesis Methods and Applications of Layered Double Hydroxides – a Brief Review // NNC RK Bulletin. 2022. № 4. P. 16–29. DOI: 10.52676/1729-7885-2022-4-17-29.Olanrewaju J., Newalkar B.L., Mancino C., Komarneni S. Simplified synthesis of nitrate form of layered double hydroxide. Materials Letters, 2000, vol. 45, no. 6, pp. 307–310. DOI: 10.1016/S0167-577X(00)00123-3.Olanrewaju J., Newalkar B.L., Mancino C., Komarneni S. Simplified synthesis of nitrate form of layered double hydroxide // Materials Letters. 2000. Vol. 45. № 6. P. 307–310. DOI: 10.1016/S0167-577X(00)00123-3.Li Yanlin, Wang Jun, Li Zhanshuang, Liu Qi, Liu Jingyuan, Liu Lianhe, Zhang Xiaofei, Yu Jing. Ultrasound assisted synthesis of Ca–Al hydrotalcite for U (VI) and Cr (VI) adsorption. Chemical Engineering Journal, 2013, vol. 218, pp. 295–302. DOI: 10.1016/j.cej.2012.12.051.Li Yanlin, Wang Jun, Li Zhanshuang, Liu Qi, Liu Jingyuan, Liu Lianhe, Zhang Xiaofei, Yu Jing. Ultrasound assisted synthesis of Ca–Al hydrotalcite for U (VI) and Cr (VI) adsorption // Chemical Engineering Journal. 2013. Vol. 218. P. 295–302. DOI: 10.1016/j.cej.2012.12.051.Salak A.N., Vieira D.E.L., Lukienko I.M. et al. High-Power Ultrasonic Synthesis and Magnetic-Field-Assisted Arrangement of Nanosized Crystallites of Cobalt-Containing Layered Double Hydroxides. ChemEngineering, 2019, vol. 3, no. 3, article number 62. DOI: 10.3390/chemengineering3030062.Salak A.N., Vieira D.E.L., Lukienko I.M. et al. High-Power Ultrasonic Synthesis and Magnetic-Field-Assisted Arrangement of Nanosized Crystallites of Cobalt-Containing Layered Double Hydroxides // ChemEngineering. 2019. Vol. 3. № 3. Article number 62. DOI: 10.3390/chemengineering3030062.Sokol D., Vieira D.E.L., Zarkov A., Ferreira M.G.S., Beganskiene A., Rubanik V.V., Shilin A.D., Kareiva A., Salak A.N. Sonication accelerated formation of Mg–Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides. Scientific Reports, 2019, vol. 9, no. 1, article number 10419. DOI: 10.1038/s41598-019-46910-5.Sokol D., Vieira D.E.L., Zarkov A., Ferreira M.G.S., Beganskiene A., Rubanik V.V., Shilin A.D., Kareiva A., Salak A.N. Sonication accelerated formation of Mg–Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides // Scientific Reports. 2019. Vol. 9. № 1. Article number 10419. DOI: 10.1038/s41598-019-46910-5.Abdel Aziz S.A.A., GadelHak Y., Mohamed M.B.E.D., Mahmoud R. Antimicrobial properties of promising Zn–Fe based layered double hydroxides for the disinfection of real dairy wastewater effluents. Scientific Reports, 2023, vol. 13, no. 1, article number 7601. DOI: 10.1038/s41598-023-34488-y.Abdel Aziz S.A.A., GadelHak Y., Mohamed M.B.E.D., Mahmoud R. Antimicrobial properties of promising Zn–Fe based layered double hydroxides for the disinfection of real dairy wastewater effluents // Scientific Reports. 2023. Vol. 13. № 1. Article number 7601. DOI: 10.1038/s41598-023-34488-y.Abdel-Hady E.E., Mohamed H.F.M., Hafez S.H.M., Fahmy A.M.M., Magdy A., Mohamed A.S., Ali E.O., Abdelhamed H.R., Mahmoud O.M. Textural properties and adsorption behavior of Zn–Mg–Al layered double hydroxide upon crystal violet dye removal as a low cost, effective, and recyclable adsorbent. Scientific Reports, 2023, vol. 13, no. 1, article number 6435. DOI: 10.1038/s41598-023-33142-x.Abdel-Hady E.E., Mohamed H.F.M., Hafez S.H.M., Fahmy A.M.M., Magdy A., Mohamed A.S., Ali E.O., Abdelhamed H.R., Mahmoud O.M. Textural properties and adsorption behavior of Zn–Mg–Al layered double hydroxide upon crystal violet dye removal as a low cost, effective, and recyclable adsorbent // Scientific Reports. 2023. Vol. 13. № 1. Article number 6435. DOI: 10.1038/s41598-023-33142-x.Ghanbari N., Ghafuri H. Preparation of novel Zn–Al layered double hydroxide composite as adsorbent for removal of organophosphorus insecticides from water. Scientific Reports, 2023, vol. 13, no. 1, article number 10215. DOI: 10.1038/s41598-023-37070-8.Ghanbari N., Ghafuri H. Preparation of novel Zn–Al layered double hydroxide composite as adsorbent for removal of organophosphorus insecticides from water // Scientific Reports. 2023. Vol. 13. № 1. Article number 10215. DOI: 10.1038/s41598-023-37070-8.