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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:ali="http://www.niso.org/schemas/ali/1.0/" article-type="other" dtd-version="1.2" xml:lang="en"><front><journal-meta><journal-id journal-id-type="publisher-id">Frontier Materials &amp; Technologies</journal-id><journal-title-group><journal-title xml:lang="en">Frontier Materials &amp; Technologies</journal-title><trans-title-group xml:lang="ru"><trans-title>Frontier Materials &amp; Technologies</trans-title></trans-title-group></journal-title-group><issn publication-format="print">2782-4039</issn><issn publication-format="electronic">2782-6074</issn><publisher><publisher-name xml:lang="en">Togliatti State University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="publisher-id">847</article-id><article-id pub-id-type="doi">10.18323/2782-4039-2023-2-64-5</article-id><article-categories><subj-group subj-group-type="toc-heading" xml:lang="en"><subject>Articles</subject></subj-group><subj-group subj-group-type="toc-heading" xml:lang="ru"><subject>Статьи</subject></subj-group><subj-group subj-group-type="article-type"><subject></subject></subj-group></article-categories><title-group><article-title xml:lang="en">Electrically conductive nanocomposite bituminous binders containing carbon nanotubes and multilayer graphene</article-title><trans-title-group xml:lang="ru"><trans-title>Электропроводящие нанокомпозиционные битумные вяжущие, содержащие углеродные нанотрубки и многослойный графен</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-8067-9548</contrib-id><name-alternatives><name xml:lang="en"><surname>Tarov</surname><given-names>Dmitry V.</given-names></name><name xml:lang="ru"><surname>Таров</surname><given-names>Дмитрий Владимирович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), leading researcher<bold><italic> </italic></bold></p></bio><bio xml:lang="ru"><p>кандидат технических наук, ведущий научный сотрудник</p></bio><email>d_tarov@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><name-alternatives><name xml:lang="en"><surname>Evlakhin</surname><given-names>Daniil A.</given-names></name><name xml:lang="ru"><surname>Евлахин</surname><given-names>Даниил Андреевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>student</p></bio><bio xml:lang="ru"><p>студент</p></bio><email>evlahin.daniil2002@yandex.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-2399-9510</contrib-id><name-alternatives><name xml:lang="en"><surname>Zelenin</surname><given-names>Andrey D.</given-names></name><name xml:lang="ru"><surname>Зеленин</surname><given-names>Андрей Дмитриевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>junior researcher</p></bio><bio xml:lang="ru"><p>младший научный сотрудник</p></bio><email>zeleandrey@yandex.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-8495-3316</contrib-id><name-alternatives><name xml:lang="en"><surname>Stolyarov</surname><given-names>Roman A.</given-names></name><name xml:lang="ru"><surname>Столяров</surname><given-names>Роман Александрович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), senior researcher</p></bio><bio xml:lang="ru"><p>кандидат технических наук, старший научный сотрудник</p></bio><email>stolyarovra@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-4855-0530</contrib-id><name-alternatives><name xml:lang="en"><surname>Yagubov</surname><given-names>Viktor S.</given-names></name><name xml:lang="ru"><surname>Ягубов</surname><given-names>Виктор Сахибович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), senior researcher</p></bio><bio xml:lang="ru"><p>кандидат технических наук, старший научный сотрудник</p></bio><email>vitya-y@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-7449-5208</contrib-id><name-alternatives><name xml:lang="en"><surname>Memetov</surname><given-names>Nariman R.</given-names></name><name xml:lang="ru"><surname>Меметов</surname><given-names>Нариман Рустемович</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), leading researcher</p></bio><bio xml:lang="ru"><p>кандидат технических наук, ведущий научный сотрудник</p></bio><email>memetov.nr@mail.tstu.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0002-1036-7389</contrib-id><name-alternatives><name xml:lang="en"><surname>Memetova</surname><given-names>Anastasiya E. Memetova</given-names></name><name xml:lang="ru"><surname>Меметова</surname><given-names>Анастасия Евгеньевна</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), assistant professor of Chair “Technology and Methods of Nanoproducts Manufacturing”</p></bio><bio xml:lang="ru"><p>кандидат технических наук, доцент кафедры «Техника и технологии производства нанопродуктов»</p></bio><email>anastasia.90k@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0001-9076-9400</contrib-id><name-alternatives><name xml:lang="en"><surname>Chapaksov</surname><given-names>Nikolay A.</given-names></name><name xml:lang="ru"><surname>Чапаксов</surname><given-names>Николай Андреевич</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>junior researcher of Chair “Nanotechnology Engineering”</p></bio><bio xml:lang="ru"><p>младший научный сотрудник кафедры «Инжиниринг нанотехнологий»</p></bio><email>tchapaxov.nikolaj@yandex.ru</email><xref ref-type="aff" rid="aff1"/></contrib><contrib contrib-type="author"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-1912-6642</contrib-id><name-alternatives><name xml:lang="en"><surname>Gerasimova</surname><given-names>Alena V.</given-names></name><name xml:lang="ru"><surname>Герасимова</surname><given-names>Алена Владимировна</given-names></name></name-alternatives><address><country country="RU">Russian Federation</country></address><bio xml:lang="en"><p>PhD (Engineering), senior lecturer of Chair “Technology and Methods of Nanoproducts Manufacturing”</p></bio><bio xml:lang="ru"><p>кандидат технических наук, старший преподаватель кафедры «Техника и технологии производства нанопродуктов»</p></bio><email>alyona_gerasimova_92@mail.ru</email><xref ref-type="aff" rid="aff1"/></contrib></contrib-group><aff-alternatives id="aff1"><aff><institution xml:lang="en">Tambov State Technical University, Tambov</institution></aff><aff><institution xml:lang="ru">Тамбовский государственный технический университет, Тамбов</institution></aff></aff-alternatives><pub-date date-type="pub" iso-8601-date="2023-06-30" publication-format="electronic"><day>30</day><month>06</month><year>2023</year></pub-date><issue>2</issue><issue-title xml:lang="en"/><issue-title xml:lang="ru"/><fpage>131</fpage><lpage>139</lpage><history><date date-type="received" iso-8601-date="2023-06-30"><day>30</day><month>06</month><year>2023</year></date></history><permissions><ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/></permissions><self-uri xlink:href="https://vektornaukitech.ru/jour/article/view/847">https://vektornaukitech.ru/jour/article/view/847</self-uri><abstract xml:lang="en"><p>In the modern literature, there are practically no data on the electrical characteristics of bituminous binders modified with carbon nanotubes and graphene nanoplates, while they are necessary for the design and development of innovative asphalt pavement compositions sensitive to the super-high-frequency microwave radiation. Contemporary bituminous binders are multi-component systems that may contain polymers, rubbers, synthetic or natural resins, inorganic salts, and even fragrances. As a result of application of modifying additives, bitumen acquires high performance characteristics. A special class of modifiers are micro- and nano-sized electrically conductive fibers and particles (steel wool, carbon fibers, carbon black, carbon nanotubes, graphene nanoplates), the use of which makes it possible to ensure the sensibility of bituminous binders to super-high-frequency microwave radiation and the implementation of the process of healing cracks in an asphalt pavement with its subsequent regeneration. As part of the study, the authors developed an original technique to produce bituminous binders modified with carbon nanotubes and multilayer graphene. Modified bituminous compositions in the concentration range from 0.2 to 6 and from 0.2 to 11 wt. % for multi-walled carbon nanotubes (MWCNT) and multilayer graphene nanoplates (MG), respectively were experimentally obtained. For the first time, the dependence of the specific volume electrical conductivity of bitumen-based nanocomposites on the concentration of nanostructured carbon filler (MWCNT and MG) was researched. The maximum values of electrical conductivity were 4.76×10<sup>−4</sup> S/cm and 3.5×10<sup>−4</sup> S/cm for nanocomposites containing 6 wt. % MWCNT and 11 wt. % MG, respectively. The study determined the filler volume fractions at the percolation threshold for nanocomposites containing MWCNT and MG. They amounted to 0.22 and 2.18, respectively. The formation of a percolation contour in nanocomposites containing MWCNT occurs at significantly lower filler concentrations compared to bituminous compositions containing MG.</p></abstract><trans-abstract xml:lang="ru"><p>В современной литературе практически отсутствуют данные об электрических характеристиках битумных вяжущих, модифицированных углеродными нанотрубками и графеновыми нанопластинками, между тем как они необходимы для проектирования и разработки инновационных составов асфальтовых покрытий, восприимчивых к сверхвысокочастотному микроволновому излучению. Современные битумные вяжущие представляют собой многокомпонентные системы, которые могут содержать полимеры, каучуки, синтетические или природные смолы, неорганические соли и даже ароматизаторы. В результате применения модифицирующих добавок битум приобретает высокие эксплуатационные характеристики. Особый класс модификаторов составляют микро- и наноразмерные электропроводящие волокна и частицы (стальная вата, углеродные волокна, технический углерод, углеродные нанотрубки, графеновые нанопластинки), применение которых позволяет обеспечивать восприимчивость битумных вяжущих к сверхвысокочастотному микроволновому излучению и реализацию процесса залечивания трещин в асфальтовом покрытии с его последующей регенерацией. В рамках исследования разработана оригинальная методика получения битумных вяжущих, модифицированных углеродными нанотрубками и многослойным графеном. Экспериментально получены модифицированные битумные составы в диапазоне концентраций от 0,2 до 6 и от 0,2 до 11 масс. % для многостенных углеродных нанотрубок (МУНТ) и многослойных графеновых нанопластинок (МГ) соответственно. Впервые проведено исследование зависимости удельной объемной электрической проводимости нанокомпозитов на основе битума от концентрации наноструктурного углеродного наполнителя (МУНТ и МГ). Максимальные значения электрической проводимости составили 4,76×10<sup>−4</sup> См/см и 3,5×10<sup>−4</sup> См/см для нанокомпозитов, содержащих 6 масс. % МУНТ и 11 масс. % МГ соответственно. Определены объемные доли наполнителя на пороге перколяции для нанокомпозитов, содержащих МУНТ и МГ. Они составили 0,22 и 2,18 соответственно. Образование перколяционного контура у нанокомпозитов, содержащих МУНТ, происходит при значительно меньших концентрациях наполнителя по сравнению с битумными композициями, имеющими в своем составе МГ.</p></trans-abstract><kwd-group xml:lang="en"><kwd>bituminous binders</kwd><kwd>electrically conductive nanocomposites</kwd><kwd>carbon nanotubes</kwd><kwd>multilayer graphene</kwd><kwd>graphene nanoplates</kwd><kwd>percolation threshold</kwd></kwd-group><kwd-group xml:lang="ru"><kwd>битумные вяжущие</kwd><kwd>электропроводящие нанокомпозиты</kwd><kwd>углеродные нанотрубки</kwd><kwd>многослойный графен</kwd><kwd>графеновые нанопластинки</kwd><kwd>порог перколяции</kwd></kwd-group><funding-group><funding-statement xml:lang="en">The study was financially supported by the Department of Education and Science of the Tambov Region and the Coordinating Council for Higher Education and Science within the scientific project No. MU2022-02/18 “Grant to support applied research of young scientists in 2022”.</funding-statement><funding-statement xml:lang="ru">Исследование выполнено при финансовой поддержке Управления образования и науки Тамбовской области и Координационного совета по вопросам высшего образования и науки в рамках научного проекта № МУ2022-02/18 «Грант для поддержки прикладных исследований молодых ученых 2022 года».</funding-statement></funding-group></article-meta></front><body></body><back><ref-list><ref id="B1"><label>1.</label><citation-alternatives><mixed-citation xml:lang="en">Zhu J., Birgisson B., Kringos N. 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