Frontier Materials & TechnologiesFrontier Materials & TechnologiesFrontier Materials & Technologies2782-40392782-6074Togliatti State University106110.18323/2782-4039-2025-2-72-7ArticlesСтатьиResearch ArticleThe influence of cavitational synthesis nanodiamonds on the tribological properties of a water-oil-based cooling lubricantВлияние наноалмазов кавитационного синтеза на трибологические свойства смазывающе-охлаждающей жидкости на водомасляной основеhttps://orcid.org/0000-0002-0165-7536FominovEvgeny V.ФоминовЕвгений Валерьевич
Russian Federation

PhD (Engineering), Associate Professor

кандидат технических наук, доцент

fominoff83@mail.ruhttps://orcid.org/0009-0003-1489-8333KovtunMaksim V.КовтунМаксим Витальевич
Russian Federation

Head of Research and Technology Center

руководитель научно-технического центра

79185530688@ya.ruhttps://orcid.org/0009-0002-3606-6311KurlovichSergey A.КурловичСергей Анатольевич
Russian Federation

Director

директор

mtdos@mail.ruhttps://orcid.org/0000-0003-2292-256XGladkikhDmitry I.ГладкихДмитрий Игоревич
Russian Federation

postgraduate student

аспирант

ya.gladckih-dmitriy@yandex.ruhttps://orcid.org/0000-0002-8283-7730LavrenovaTatyana V.ЛавреноваТатьяна Владимировна
Russian Federation

senior lecturer

старший преподаватель

bys_ka87@mail.ruDon State Technical UniversityДонской государственный технический университетTrading and Industrial Company SYNTEZТПК «СИНТЕЗ»300620252879430062025Copyright ©; 2025, Fominov E.V., Kovtun M.V., Kurlovich S.A., Gladkikh D.I., Lavrenova T.V.Copyright ©; 2025, Фоминов Е.В., Ковтун М.В., Курлович С.А., Гладких Д.И., Лавренова Т.В.2025Fominov E.V., Kovtun M.V., Kurlovich S.A., Gladkikh D.I., Lavrenova T.V.Фоминов Е.В., Ковтун М.В., Курлович С.А., Гладких Д.И., Лавренова Т.В.https://creativecommons.org/licenses/by/4.0https://vektornaukitech.ru/jour/article/view/1061

This paper deals with the study of the influence of nanosized diamonds produced by the cavitational synthesis method on the tribological properties of a commercial water-oil-based cooling lubricant. The study is aimed at assessing the prospects for application of this type of nanodiamonds as an antifriction and antiwear additive. Tribological tests were carried out using the “indenter on a disk” friction scheme at a constant load and sliding speed. High-speed P18 steel for the indenter and 30HGSA steel for the rotating counterbody (disk) were used as friction couple materials. The studies were carried out for the base lubricant and two variants of its composition modifications using colloidal dispersion (distilled water with dispersed nanodiamonds) with a final additive concentration of 0.5 and 2.5 %. It was experimentally found that both variants of modification of the base water-oil emulsion resulted in increase of the bearing capacity of lubricating layers, decreasing the total linear wear of friction couple elements by 1.8–2.4 times. The presence of nanodiamonds in the composition enhanced as well the shielding effect of the cutting coolant. A decrease in visible damage to friction surfaces was recorded using optical microscopy. Analysis of profile diagrams of worn areas in the transverse direction showed a decrease in the size of a groove on the counterbody against the background of a decrease in roughness from Ra=0.49 μm in the basic variant to Ra=0.29–0.34 μm. Evaluation of the loss in counterbody weight for nanodiamond concentrations of 0.5 and 2.5 % showed a decrease in their value by 1.3 and 1.9 times, respectively; for the indenter, the decrease in this parameter was 1.2 and 1.5 times. Thus, the use of cavitational synthesis nanodiamonds as an additive may become a promising direction for increasing the antiwear properties of water-oil-based cooling lubricants.

Статья посвящена изучению влияния наноразмерных алмазов, полученных методом кавитационного синтеза, на трибологические характеристики коммерческой смазывающе-охлаждающей жидкости на водомасляной основе. Исследование направлено на оценку перспектив применения наноалмазов данного типа в качестве антифрикционной и противоизносной присадки. Трибологические испытания проводились по схеме трения «индентор по диску» при постоянной нагрузке и скорости скольжения. В качестве материалов пары трения использованы быстрорежущая сталь Р18 для индентора и сталь 30ХГСА для вращающегося контртела (диска). Исследования проведены для базового смазочного материала и двух вариантов модификаций его состава коллоидной дисперсией (дистиллированная вода с диспергированными наноалмазами) с окончательной концентрацией присадки 0,5 и 2,5 %. Экспериментально установлено, что оба варианта модификации базовой водомасляной эмульсии привели к увеличению несущей способности смазочных слоев, снизив суммарный линейный износ элементов пары трения в 1,8–2,4 раза. Присутствие наноалмазов в составе также усилило экранирующий эффект смазочно-охлаждающей жидкости. Посредством оптической микроскопии было зафиксировано снижение видимых повреждений поверхностей трения. Анализ профилограмм изношенных участков в поперечном направлении показал уменьшение размеров борозды на контртеле на фоне снижения шероховатости с Ra=0,49 мкм в базовом варианте до Ra=0,29–0,34 мкм. Оценка потери массы контртел для концентраций наноалмазов 0,5 и 2,5 % показала снижение их величины в 1,3 и 1,9 раза соответственно, для индентора уменьшение этого параметра составило 1,2 и 1,5 раза. Таким образом, использование наноалмазов кавитационного синтеза в качестве присадки может стать перспективным направлением повышения противоизносных свойств смазывающе-охлаждающих жидкостей на водомасляной основе.

cavitational synthesis nanodiamondswater-oil emulsioncooling lubricantboundary frictionwear resistancefriction ratioнаноалмазы кавитационного синтезаводомасляная эмульсиясмазывающе-охлаждающая жидкостьграничное трениеизносостойкостькоэффициент тренияChen Yan, Renner P., Liang Hong. Dispersion of Nanoparticles in Lubricating Oil: A Critical Review. Lubricants, 2019, vol. 7, no. 1, article number 7. DOI: 10.3390/lubricants7010007.Chen Yan, Renner P., Liang Hong. Dispersion of Nanoparticles in Lubricating Oil: A Critical Review // Lubricants. 2019. Vol. 7. № 1. Article number 7. DOI: 10.3390/lubricants7010007.Gulzar M., Masjuki H.H., Kalam M.A., Varman M., Zulkifli N.W.M., Mufti R.A., Zahid R. Tribological performance of nanoparticles as lubricating oil additives. Journal of Nanoparticle Research, 2016, vol. 18, article number 223. DOI: 10.1007/s11051-016-3537-4.Gulzar M., Masjuki H.H., Kalam M.A., Varman M., Zulkifli N.W.M., Mufti R.A., Zahid R. Tribological performance of nanoparticles as lubricating oil additives // Journal of Nanoparticle Research. 2016. Vol. 18. Article number 223. DOI: 10.1007/s11051-016-3537-4.Xia Wenzhen, Zhao Jingwei, Wu Hui et al. Effects of oil-in-water based nanolubricant containing TiO2 nanoparticles in hot rolling of 304 stainless steel. Journal of Materials Processing Technology, 2018, vol. 262, pp. 149–156. DOI: 10.1016/j.jmatprotec.2018.06.020.Wenzhen Xia, Jingwei Zhao, Hui Wu et al. Effects of oil-in-water based nanolubricant containing TiO2 nanoparticles in hot rolling of 304 stainless steel // Journal of Materials Processing Technology. 2018. Vol. 262. P. 149–156. DOI: 10.1016/j.jmatprotec.2018.06.020.Kim Hyun-Joon, Seo Kuk-Jin, Kang Kyeong Hee, Kim Dae-Eun. Nano-lubrication: A review. International Journal of Precision Engineering and Manufacturing, 2016, vol. 17, pp. 829–841. DOI: 10.1007/s12541-016-0102-0.Kim Hyun-Joon, Seo Kuk-Jin, Kang Kyeong Hee, Kim Dae-Eun. Nano-lubrication: A review // International Journal of Precision Engineering and Manufacturing. 2016. Vol. 17. P. 829–841. DOI: 10.1007/s12541-016-0102-0.Ali I., Basheer A.A., Kucherova A. et al. Advances in carbon nanomaterials as lubricants modifiers. Journal of Molecular Liquids, 2019, vol. 279, pp. 251266. DOI: 10.1016/j.molliq.2019.01.113.Ali I., Basheer A.A., Kucherova A. et al. Advances in carbon nanomaterials as lubricants modifiers // Journal of Molecular Liquids. 2019. Vol. 279. P. 251266. DOI: 10.1016/j.molliq.2019.01.113.Zhai Wenzheng, Srikanth N., Kong Ling Bing, Zhou Kun. Carbon nanomaterials in tribology. Carbon, 2017, vol. 119, pp. 150171. DOI: 10.1016/j.carbon.2017.04.027.Zhai Wenzheng, Srikanth N., Kong Ling Bing, Zhou Kun. Carbon nanomaterials in tribology // Carbon. 2017. Vol. 119. P. 150171. DOI: 10.1016/j.carbon.2017.04.027.Gong Zhenbin, Shi Jing, Zhang Bin, Zhang Junyan. Graphene nano scrolls responding to superlow friction of amorphous carbon. Carbon, 2017, vol. 116, pp. 310–317. DOI: 10.1016/j.carbon.2017.01.106.Gong Zhenbin, Shi Jing, Zhang Bin, Zhang Junyan. Graphene nano scrolls responding to superlow friction of amorphous carbon // Carbon. 2017. Vol. 116. P. 310–317. DOI: 10.1016/j.carbon.2017.01.106.Morshed A., Wu Hui, Jiang Zhengyi. A Comprehensive Review of Water-Based Nanolubricants. Lubricants, 2021, vol. 9, article number 89. DOI: 10.3390/lubricants9090089.Morshed A., Wu Hui, Jiang Zhengyi. A Comprehensive Review of Water-Based Nanolubricants // Lubricants. 2021. Vol. 9. Article number 89. DOI: 10.3390/lubricants9090089.Ivanov M., Shenderova O. Nanodiamond-based nanolubricants for motor oils. Current Opinion in Solid State and Materials Science, 2017, vol. 21, no. 1, pp. 17–24. DOI: 10.1016/j.cossms.2016.07.003.Ivanov M., Shenderova O. Nanodiamond-based nanolubricants for motor oils // Current Opinion in Solid State and Materials Science. 2017. Vol. 21. № 1. P. 17–24. DOI: 10.1016/j.cossms.2016.07.003.Piya A.K., Yang L., Omar A.A.S., Emami N., Morina A. Synergistic lubrication mechanism of nanodiamonds with organic friction modifier. Carbon, 2024, vol. 218, article number 118742. DOI: 10.1016/j.carbon.2023.118742.Piya A.K., Yang L., Omar A.A.S., Emami N., Morina A. Synergistic lubrication mechanism of nanodiamonds with organic friction modifier // Carbon. 2024. Vol. 218. Article number 118742. DOI: 10.1016/j.carbon.2023.118742.Shirani A., Nunn N., Shenderova O., Osawa E., Berman D. Nanodiamonds for improving lubrication of titanium surfaces in simulated body fluid. Carbon, 2019, vol. 143, pp. 890896. DOI: 10.1016/j.carbon.2018.12.005.Shirani A., Nunn N., Shenderova O., Osawa E., Berman D. Nanodiamonds for improving lubrication of titanium surfaces in simulated body fluid // Carbon. 2019. Vol. 143. P. 890896. DOI: 10.1016/j.carbon.2018.12.005.Mirzaamiri R., Akbarzadeh S., Ziaei-Rad S., Shin Dong-Gap, Kim Dae-Eun. Molecular dynamics simulation and experimental investigation of tribological behavior of nanodiamonds in aqueous suspensions. Tribology International, 2021, vol. 156, article number 106838. DOI: 10.1016/j.triboint.2020.106838.Mirzaamiri R., Akbarzadeh S., Ziaei-Rad S., Shin Dong-Gap, Kim Dae-Eun. Molecular dynamics simulation and experimental investigation of tribological behavior of nanodiamonds in aqueous suspensions // Tribology International. 2021. Vol. 156. Article number 106838. DOI: 10.1016/j.triboint.2020.106838.Alias A.A., Kinoshita H., Fujii M. Tribological properties of diamond nanoparticle additive in water under a lubrication between steel plate and tungsten carbide ball. Journal of Advanced Mechanical Design, Systems, and Manufacturing, 2015, vol. 9, no. 1, article number JAMDSM0006. DOI: 10.1299/jamdsm.2015jamdsm0006.Alias A.A., Kinoshita H., Fujii M. Tribological properties of diamond nanoparticle additive in water under a lubrication between steel plate and tungsten carbide ball // Journal of Advanced Mechanical Design, Systems, and Manufacturing. 2015. Vol. 9. № 1. Article number JAMDSM0006. DOI: 10.1299/jamdsm.2015jamdsm0006.Wu Pu, Chen Xinchun, Zhang Chenhui, Luo Jianbin. Synergistic tribological behaviors of graphene oxide and nanodiamond as lubricating additives in water. Tribology International, 2019, vol. 132, pp. 177184. DOI: 10.1016/j.triboint.2018.12.021.Wu Pu, Chen Xinchun, Zhang Chenhui, Luo Jianbin. Synergistic tribological behaviors of graphene oxide and nanodiamond as lubricating additives in water // Tribology International. 2019. Vol. 132. P. 177184. DOI: 10.1016/j.triboint.2018.12.021.Hu Shuguo, Li Changhe, Zhou Zongming et al. Nanoparticle-enhanced coolants in machining: mechanism, application, and prospects. Frontiers of Mechanical Engineering, 2023, vol. 18, article number 53. DOI: 10.1007/s11465-023-0769-8.Hu Shuguo, Li Changhe, Zhou Zongming et al. Nanoparticle-enhanced coolants in machining: mechanism, application, and prospects // Frontiers of Mechanical Engineering. 2023. Vol. 18. Article number 53. DOI: 10.1007/s11465-023-0769-8.Wang Xiaoming, Song Yuxiang, Lim Changhe et al. Nanofluids application in machining: a comprehensive review. The International Journal of Advanced Manufacturing, 2024, vol. 131, pp. 3113–3164. DOI: 10.1007/s00170-022-10767-2.Wang Xiaoming, Song Yuxiang, Lim Changhe et al. Nanofluids application in machining: a comprehensive review // The International Journal of Advanced Manufacturing. 2024. Vol. 131. P. 3113–3164. DOI: 10.1007/s00170-022-10767-2.Kumar A.S., Deb S., Paul S. Tribological characteristics and micromilling performance of nanoparticle enhanced water based cutting fluids in minimum quantity lubrication. Journal of Manufacturing Processes, 2020, vol. 56, part A, pp. 766–776. DOI: 10.1016/j.jmapro.2020.05.032.Kumar A.S., Deb S., Paul S. Tribological characteristics and micromilling performance of nanoparticle enhanced water based cutting fluids in minimum quantity lubrication // Journal of Manufacturing Processes. 2020. Vol. 56. Part A. P. 766–776. DOI: 10.1016/j.jmapro.2020.05.032.Antipov A.A., Arakelyan S.M., Kutrovskaya S.V., Kucherik A.O., Nogtev D.S., Osipov A.V., Garnov S.V. Laser ablation of carbon targets placed in a liquid. Quantum Electronics, 2015, vol. 45, no. 8, pp. 731–735. DOI: 10.1070/QE2015v045n08ABEH015681.Антипов А.А., Аракелян С.М., Гарнов С.В., Кутровская С.В., Кучерик А.О., Ногтев Д.С., Осипов А.В. Лазерная абляция углеродных мишеней, помещенных в жидкость // Квантовая электроника. 2015. Т. 45. № 8. С. 731735. EDN: UGUZNP.Vityaz P.A. Nanoalmazy detonatsionnogo sinteza: poluchenie i primenenie [Detonation synthesis nanodiamonds: production and application]. Minsk, Belaruskaya navuka Publ., 2013. 381 p.Витязь П.А. Наноалмазы детонационного синтеза: получение и применение. Минск: Беларуская навука, 2013. 381 с.Beskopylny A.N., Stel’makh S.A., Shcherban’ E.M. et al. Performance and mechanism of the structure formation and physical-mechanical properties of concrete by modification with nanodiamonds. Construction and Building Materials, 2024, vol. 452, article number 138994. DOI: 10.1016/j.conbuildmat.2024.138994.Beskopylny A.N., Stel’makh S.A., Shcherban’ E.M. et al. Performance and mechanism of the structure formation and physical-mechanical properties of concrete by modification with nanodiamonds // Construction and Building Materials. 2024. Vol. 452. Article number 138994. DOI: 10.1016/j.conbuildmat.2024.138994.Xia Yue, Lu Yunxiang, Yang Guoyong et al. Application of Nano-Crystalline Diamond in Tribology. Materials, 2023, vol. 16, no. 7, article number 2710. DOI: 10.3390/ma16072710.Xia Yue, Lu Yunxiang, Yang Guoyong et al. Application of Nano-Crystalline Diamond in Tribology // Materials. 2023. Vol. 16. № 7. Article number 2710. DOI: 10.3390/ma16072710.