Effect of test temperature on low-cycle fatigue of high-chromium steel with high boron and low nitrogen content

Cover Page

Cite item

Abstract

High-boron 9–10 % chromium martensitic steels are an advanced material for manufacturing various components of thermal power units in coal-fired power plants operating under ultra-supercritical steam conditions (up to 650 °C and 35 MPa), enabling an increase in efficiency to 44 % and reduction of harmful environmental emissions. The work studies the influence of various testing conditions on the behaviour of a 10 % Cr martensitic steel with high boron and low nitrogen content, additionally alloyed with cobalt, tungsten, molybdenum, copper, and rhenium, under lowcycle fatigue (LCF). After heat treatment, the steel microstructure consisted of tempered lath troostite with a high dislocation density. The main strengthening phases were identified: grain-boundary M23C6 carbide particles with an average size of 70 nm and uniformly distributed NbX carbonitrides with an average size of 30 nm. Increasing the strain amplitude during low-cycle fatigue significantly reduces the number of cycles to failure regardless of test temperature, due to intensive development of plastic deformation. Microstructural analysis revealed no significant changes in the lath structure after low-cycle fatigue testing at room temperature, while at elevated temperatures, structural recrystallisation initiates and a well-developed subgrain structure with an average subgrain size of about 600±50 nm forms.

About the authors

Ivan S. Brazhnikov

Belgorod State National Research University

Author for correspondence.
Email: brazhnikov@bsuedu.ru
ORCID iD: 0009-0008-8069-7376

engineer of the Joint Research Center of Belgorod State National Research University “Technology and Materials”

Russian Federation, 308015, Russia, Belgorod, Pobedy Street, 85

Alexandra E. Fedoseeva

Belgorod State National Research University

Email: fedoseeva@bsu.edu.ru
ORCID iD: 0000-0003-4031-463X

PhD (Engineering), senior researcher of the Laboratory of Mechanical Properties of Nanostructured Materials and Superalloys

Russian Federation, 308015, Russia, Belgorod, Pobedy Street, 85

References

  1. Maruyama K., Sekido N., Yoshimi K. Changes in strengthening mechanisms in creep of 9Cr-1.8W-0.5Mo-VNb steel tested over wide ranges of creep conditions. International Journal of Pressure Vessels and Piping, 2021, vol. 190, article number 104312. doi: 10.1016/j.ijpvp.2021.104312.
  2. Dong Z., Chen L., Xiang Z.D. Design of a new 11Cr martensitic steel and evaluation of its long-term creep rupture strengths. Journal of Materials Research and Technology, 2022, vol. 20, pp. 3450–3455. doi: 10.1016/j.jmrt.2022.08.116.
  3. Fedoseeva A.E. Creep Resistance and Structure of 10% Cr–3% Сo–2% W–0.29% Cu–0.17% Re Steel with Low Nitrogen and High Boron Contents for Unit Components of Coal Power Plants. Physical Mesomechanics, 2024, vol. 27, pp. 88–101. doi: 10.1134/S1029959924010090.
  4. Tamura M., Abe F. Analysis of the Degradation in the Creep Strength of High-Cr Martensitic Steels. Journal of Materials Science Research, 2021, vol. 10, pp. 1–70. doi: 10.5539/jmsr.v10n2p1.
  5. Detrois M., Hawk J.A., Jablonski P.D. Creep-Resistant Ferritic-Martensitic Steels for Power Plant Applications. Journal of Materials Engineering and Performance, 2024, vol. 33, pp. 1–42. doi: 10.1007/s11665-023-08566-1.
  6. Hamaguchi T., Kurihara S., Hirata H., Okada H. Creep rupture properties and microstructures of 9Cr–3Co–3W-Nd-B steel welded joints. Materials Science and Engineering: A, 2022, vol. 831, article number 142231. doi: 10.1016/j.msea.2021.142231.
  7. Abe F., Tabuchi M., Tsukamoto S. Alloy Design of MARBN for Boiler and Turbine Applications at 650°C. Materials at High Temperatures, 2021, vol. 38, no. 5, pp. 306–321. doi: 10.1080/09603409.2021.1963393.
  8. Osanai T., Sekido N., Yonemura M., Maruyama K., Takeuchi M., Yoshimi K. Evolution of boron segregation during tempering in B doped 9%Cr ferritic steel. Materials Characterization, 2021, vol. 177, article number 111192. doi: 10.1016/j.matchar.2021.111192.
  9. Dudova N. 9–12% Cr Heat-Resistant Martensitic Steels with Increased Boron and Decreased Nitrogen Contents. Metals, 2022, vol. 12, no. 7, article number 1119. doi: 10.3390/met12071119.
  10. Liu Zhen, Wang Xitao, Dong Chen. Effect of boron on G115 martensitic heat resistant steel during aging at 650°C. Materials Science and Engineering: A, 2020, vol. 787, article number 139529. doi: 10.1016/j.msea.2020.139529.
  11. Golański G., Mroziński S. Low cycle fatigue and cyclic softening behaviour of martensitic cast steel. Engineering Failure Analysis, 2013, vol. 35, pp. 692–702. doi: 10.1016/j.engfailanal.2013.06.019.
  12. Jing Hongyang, Luo Zhenxuan, Xu Lianyong, Zhao Lei, Han Yongdian. Low cycle fatigue behavior and microstructure evolution of a novel 9Cr–3W–3Co tempered martensitic steel at 650 °C. Materials Science and Engineering: A, 2018, vol. 731, pp. 394–402. doi: 10.1016/j.msea.2018.06.071.
  13. Zhang Zhe, Li Xiaofei, Yu Yaohua, Li Bingbing, Zhang Bo, Ma Yushan, Chen Xu. Effects of temperature and strain amplitude on low-cycle fatigue behavior of 12Cr13 martensitic stainless steel. Journal of Materials Research and Technology, 2024, vol. 29, pp. 1414–1427. doi: 10.1016/j.jmrt.2024.01.162.
  14. Chauhan А., Hoffmann J., Litvinov D., Aktaa J. High-temperature low-cycle fatigue behavior of a 9Cr-ODS steel: Part 2 - Hold time influence, microstructural evolution and damage characteristics. Materials Science & Engineering: A, 2018, vol. 730, pp. 197–206. doi: 10.1016/j.msea.2018.05.107.
  15. Hirsch P.B. Direct Observations of moving dislocations: Reflections on the thirtieth anniversary of the first recorded observations of moving dislocations by transmission electron microscopy. Materials Science and Engineering, 1986, vol. 84, pp. 1–10. doi: 10.1016/0025-5416(86)90216-8.
  16. Zhilyaev A.P., Sergeev S.N., Langdon T.G. Electron backscatter diffraction (EBSD) microstructure evolution in HPT copper annealed at a low temperature. Journal of Materials Research and Technology, 2014, vol. 3, no. 4, pp. 338–343. doi: 10.1016/j.jmrt.2014.06.008.
  17. Hughes D., Hansen N. Microstructure and strength of nickel at large strains. Acta Materialia, 2000, vol. 48, no. 11, pp. 2985–3004. doi: 10.1016/S1359-6454(00)00082-3.
  18. Mishnev R., Dudova N., Kaibyshev R. Low cycle fatigue behavior of a 10Cr–2W–Mo–3Co–NbV steel. International Journal of Fatigue, 2016, vol. 83, part 2, article number 344–355. doi: 10.1016/j.ijfatigue.2015.11.008.
  19. Batista M.N., Marinelli M.C., Herenu S., Alvarez-Armas I. The role of microstructure in fatigue crack initiation of 9–12% Cr reduced activation ferritic–martensitic steel. International Journal of Fatigue, 2015, vol. 72, pp. 75–79. doi: 10.1016/j.ijfatigue.2014.11.006.
  20. Giordana M.F., Alvarez-Armas I., Armas A. Microstructural characterization of EUROFER 97 during low-cycle fatigue. Journal of nuclear materials, 2012, vol. 424, no. 1-3, pp. 247–251. doi: 10.1016/j.jnucmat.2012.03.019.
  21. Guguloth K., Sivaprasad S., Chakrabarti D., Tarafder S. Low-cyclic fatigue behavior of modified 9Cr–1Mo steel at elevated temperature. Materials Science and Engineering: A, 2014, vol. 604, pp. 196–206. doi: 10.1016/j.msea.2014.02.076.
  22. Zhang Zhen, Hu Zhengfei, Schmauder S., Zhang Baosen, Wang Zhangzhong. Low cycle fatigue properties and microstructure of P92 ferritic-martensitic steel at room temperature and 873 K. Materials Characterization, 2019, vol. 157, article number 109923. doi: 10.1016/j.matchar.2019.109923.
  23. Wang Xiaowei, Zhang Wei, Zhang Tianyu, Gong Jianming, Wahab M.A. A new empirical life prediction model for 9–12% Cr steels under low cycle fatigue and creep fatigue interaction loadings. Metals, 2019, vol. 9, no. 2, article number 183. doi: 10.3390/met9020183.
  24. Mroziński S., Golański G. Influence of temperature change on fatigue properties of P91 steel. Materials Research Innovations, 2014, vol. 18, no. 2, pp. S2-504-S2-508. doi: 10.1179/1432891714Z.000000000546.
  25. Wang Xiaowei, Zhang Tianyu, Zhang Wei, Wahab M.A., Gong Jianming. An improved unified viscoplastic model for modelling low cycle fatigue and creep fatigue interaction loadings of 9–12% Cr steel. European Journal of Mechanics-A/Solids, 2021, vol. 85, article number 104123. doi: 10.1016/j.euromechsol.2020.104123.
  26. Zhang Wei, Wang Xiaowei, Li Xiang, Gong Jianming, Wahab M.A. Influence of prior low cycle fatigue on microstructure evolution and subsequent creep behavior. International Journal of Fatigue, 2018, vol. 109, pp. 114–125. doi: 10.1016/j.ijfatigue.2018.01.001.
  27. Li Xin, Zhou Chang-Yu, Pan Xiang-Ming, Chang Le, Lu Lei, Zhang Guo-Dong, Xue Fei, Zhao Yan-Fen. In-phase thermomechanical fatigue studies on P92 steel with different hold time. High Temperature Materials and Processes, 2022, vol. 41, no. 1, pp. 57–68. doi: 10.1515/htmp-2022-0024.
  28. Brazhnikov I.S., Fedoseeva A.E. Microstructure and high-temperature low-cycle fatigue of high-chromium martensitic steel with low nitrogen and high boron. Physical Mesomechanics, 2025, vol. 28, pp. 366–380. doi: 10.1134/S1029959924601568.
  29. Fedoseeva A., Klauz A., Iskandarov N., Boev A., Aksyonov D., Kaibyshev R. Effect of the Cu additives on strain-induced coarsening of the Laves phase in Re-containing 10% Cr-3% Co martensitic steels. Materials Science & Engineering: A, 2024, vol. 897, article number 146306. doi: 10.1016/j.msea.2024.146306.
  30. Wang Xiaowei, Gong Jianming, Zhao Yanping, Wang Yanfei, Yu Minghao. Characterization of low cycle fatigue performance of new ferritic P92 steel at high temperature: effect of strain amplitude. Steel research international, 2015, vol. 86, no. 9, pp. 1046–1055. doi: 10.1002/srin.201400246.
  31. Wang Xiaowei, Zhang Wei, Gong Jianming, Wahab M.A. Low cycle fatigue and creep fatigue interaction behavior of 9Cr-0.5 Mo-1.8 WV-Nb heat-resistant steel at high temperature. Journal of Nuclear Materials, 2018, vol. 505, pp. 73–84. doi: 10.1016/j.jnucmat.2018.03.055.

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2025 Brazhnikov I.S., Fedoseeva A.E.

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.